1.

The best reagent for converting 2-phenylpropanamide to 1-phenylethanamine is ________(a) H2/Ni(b) Na(Hg)/C2H5OH(c) LiAlH4(d) NaOH/Br2I had been asked this question in unit test.This intriguing question originated from Preparation of Amines in division Amines of Chemistry – Class 12

Answer»

Correct option is (d) NaOH/Br2

Easiest EXPLANATION: 2-Phenylpropanamide has 9 carbon atoms while 1-phenylethamine has 8 carbon atoms. This depicts stepping down of carbon from AMIDE to AMINE conversion and this takes place in Hoffmann degradation reaction.



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