1.

The boiling point of benzene is 353.23 K. When 1.80 g of a non - volatile solute was dissolved in 90 g of benzene, the boiling point is raised to 354.11 K. Calculate the molar mass of the solute. K_(b) for benzene is 2.53 K kg mol^(-1).

Answer»

Solution :The elevation `(Delta T_(b))` in the boiling point `= 354.11 K - 353.23 K = 0.88 K`
Sdubstituting these VALUES in expression
`M_(2)=(1000 xx w_(2))xx (K_(b))/(Delta T_(b)xx w_(1))`
we get,
`M_(2)=(2.53"K kg MOL"^(-1)xx1.8 g xx1000 g kg^(-1))/(0.88K xx 90 g)`
`= 58 gmol^(-1)`
Therefore, molar mass of the SOLUTE,
`M_(2)=58 g mol^(-1)`


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