The boiling point of p-nitrophenol is hgiher than that of o-nitropheno – InterviewSolution

1.	The boiling point of p-nitrophenol is hgiher than that of o-nitrophenol because
Answer» `NO_(2)` group at p-position behaves in a DIFFERENT way from that at o- position INTRAMOLECULAR hydrogen bonding exists inp-nitrophenol there is INTERMOLECULAR hydrogen bonding in p-nitrophenol p-nitrophenol has a HIGHER molecular weight than o-nitrophenol. Solution :The b.pt of p-nitrophenol is higher than that of o-nitrophenol because in p-nitrophenol there is intermolecular H-bonding in o-nitrophenol it is intramolecular H=bonding.

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