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The boiling points of isomeric alkyl halides _______ with increase in branching.(a) increase(b) decrease(c) remains same(d) cannot be determinedI have been asked this question in an online quiz.Asked question is from Haloarenes Physical Properties in section Haloalkanes and Haloarenes of Chemistry – Class 12

Answer»

The correct option is (b) decrease

Best explanation: The branching of compounds MAKES it more compact and REDUCES the surface area, which in TURN van der WAALS ATTRACTION forces and thus, decrease the boiling point.



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