The chlorate ion can disproportionate in basic solution according to reaction,2ClO−3⇌ClO−2+ClO−4The concentration of chlorate ion present initially is 0.1 M.The equilibrium concentration of perchlorate ions at 298 K is x. What is the value of 1x?Given : EClO−4|ClO−3=0.36V and E∘ClO−3|ClO−2=0.33.V At 298 KRTF=0.06 V√10=3.16

The chlorate ion can disproportionate in basic solution according to r

1.	The chlorate ion can disproportionate in basic solution according to reaction,2ClO−3⇌ClO−2+ClO−4The concentration of chlorate ion present initially is 0.1 M.The equilibrium concentration of perchlorate ions at 298 K is x. What is the value of 1x?Given : EClO−4\|ClO−3=0.36V and E∘ClO−3\|ClO−2=0.33.V At 298 KRTF=0.06 V√10=3.16
Answer» The chlorate ion can disproportionate in basic solution according to reaction, $2 C l O_{3}^{-} ⇌ C l O_{2}^{-} + C l O_{4}^{-}$ The concentration of chlorate ion present initially is $0.1 M$ . The equilibrium concentration of perchlorate ions at $298$ K is $x$ . What is the value of $\frac{1}{x}$ ? Given : $E_{C l O_{4}^{-} \| C l O_{3}^{-}} = 0.36 V a n d E_{C l O_{3}^{-} \| C l O_{2}^{-}}^{\circ} = 0.33. V A t 298 K \frac{R T}{F} = 0.06 V \sqrt{10} = 3.16$