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The decarboxylation of beta - ketoacids, beta, gamma - unsaturated acid and geminal diacid proceed through the formation of cyclic transition state in presence of heat. CH_(3)-overset(O)overset("||")C-CH_(2)-overset(O)overset("||")C-OHoverset(Delta)rarrCH_(3)-overset(O)overset("||")C-CH_(3) Mechanism: |
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