1.

The enthalpy change for the reaction of 5 litre of ethylene with 5 litre of `H_(2)` gas at 1.5 atm pressure is `Delta H= -0.5 kJ`. The value of `Delta U` will be: `( 1 atm Lt=100 J)`A. `-1.25 kJ`B. `+1.25 kJ`C. `0.25 kJ`D. `-0.25 kJ`

Answer» Correct Answer - C
`CH_(2)H_(2)(g)+H_(2)(g) rarrC_(2)H_(4)(g)`
`Delta H=Delta V+Deltan_(g)RT=Delta U+P Delta V`
`-0.5=Delta U+1.5(-5)xx(100)/(1000)`
`Delta U= -0.5+0.75`
`Delta U= 0.25 kJ`


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