1.

The equilibrium constants of the following areA. `K_1K_(3)^(3)//K_2`B. `K_2K_(3)^(3)//K_1`C. `K_2K_(3)//K_1`D. `K_2^(3)K_(3)//K_1`

Answer» Correct Answer - B
Given, `N_2+3H_2hArr2NH_3,K_1` .....(1)
`N_2+O_2hArr2NO,K_2` .....(ii)
`H_2+(1)/(2)O_2toH_2O,K_2` .......(iii)
To calculate ,
`2NH_3+(5)/(2)O_2overset(K)hArr2NO+3H_2O`
`K=?` .....(iv)
On reversing the equaiton (1) and multiplying the equation (iii) by 3, we get
`2NH_3hArrN_2+3H_2,(1)/(K_1)` ....(v)
`3H_2+(3)/(2)O_2to 3H_2O,K_(3)^(3)` ......(vi)
Now, add equation (ii),(v) and (vi), we get the resultant equation (iv).
`2NH_3+(5)/(2)O_2overset(K)hArr2NO+3H_2O`
`K=(K_2K^2)/(K_1)`


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