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The heat of formation of `C_(2)H_(5)OH(l)` is `-66 " kcal"//"mole"`. The heat of combustion of `CH_(3)OCH_(3)(g)` is `-348 " kcal"//"mole",DeltaH_(f)` for `H_(2)O(l)` and `CO_(2)(g)` are `-68 kcal//"mole"` and `-94 kcal//"mole"` respectively,. Then the `DeltaH` for the isomerisation reaction, `C_(2)H_(5)OH(l)toCH_(3)OCH(g)`, and `DeltaE` for the same are : (Take: `T_("surr")=298 K`)A. `DeltaH=18 kcal//"mole",DeltaE=17.301 kcal//"mole"`B. `DeltaH=22 kcal//"mole",DeltaE=21.404 kcal//"mole"`C. `DeltaH=26 kcal//"mole",DeltaE=25.709 kcal//"mole"`D. `DeltaH=30 kcal//"mole",DeltaE=28.522 kcal//"mole"` |
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Answer» Correct Answer - B |
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