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The ionization energy of a hydrogen like Bohr atom is 4 Rydberg. If the wavelength of radiation emitted when the electron jumps from the first excited state to the ground state is N-m and if the radius of the first orbit of this atom is r-m then the value of (N)/(r )=Pxx10^(2) then, value of P. (Bohr radius of hydrogen =5xx10^(11)m,1 Rydberg =2.2xx10^(16)J)

Answer»


Solution :(a) In energy units, `1` rydberg `=13.6 eV`. The energy NEEDED to detach the ELECTRON is `4xx13.6 eV`. The energy in the ground state is, therefore, `E_(1) = -4xx13.6 eV`. The energy of the first excited state `(n=2)` is `E_(2)=(E_(1))/(4)=13.6 eV. DeltaE=40.8 eV`. The wavelength of the radiation emitted is
`lambda=(hc)/(DeltaE)`
(b) The energy of a hydrogen-like ion in ground state is `E=Z^(2)E_(0)` where `Z=` atomic number and `E_(0) = -13.6 eV`. Thus, `Z=2`. The radius of TH first orbit is `(a_(0))/(Z)` where `a_(0)=5xx10^(-11)m`. Thus,
`r=(a_(0))/(Z)=2.5xx10^(-11)m`


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