The lower stability of ethyl anion compared to methyl anion and the hi

1.	The lower stability of ethyl anion compared to methyl anion and the higher stability of ethyl radical compared to methyl radical, respectively, are due to (A) +I effect of the methyl group in ethyl anion and σ → p-orbital conjugation in ethyl radical (B) –I effect of the methyl group in ethyl anion and σ → σ∗ conjugation in ethyl radical (C) +I effect of the methyl group in both cases (D) +I effect of the methyl group in ethyl anion and σ → σ∗ conjugation in ethyl radical
Answer» Correct option (A) +I effect of the methyl group in ethyl anion and σ → p-orbital conjugation in ethyl radical Explanation: Stability C₂H₂⁻ > CH₃⁻ In ethyl anion, methyl group have +I effect which increases e^– density on carbanion so stability decreases. Stability C₂H₅ > CH₃ Due to σ –p orbital conjugation in ethyl radical, it is more stable.

The lower stability of ethyl anion compared to methyl anion and the higher stability of ethyl radical compared to methyl radical, respectively, are due to (A) +I effect of the methyl group in ethyl anion and σ → p-orbital conjugation in ethyl radical (B) –I effect of the methyl group in ethyl anion and σ → σ∗ conjugation in ethyl radical (C) +I effect of the methyl group in both cases (D) +I effect of the methyl group in ethyl anion and σ → σ∗ conjugation in ethyl radical

Answer»

Correct option (A) +I effect of the methyl group in ethyl anion and σ → p-orbital conjugation in ethyl radical

Explanation:

Stability C₂H₂⁻ > CH₃⁻

In ethyl anion, methyl group have +I effect which increases e^– density on carbanion so stability decreases.

Stability C₂H₅ > CH₃

Due to σ –p orbital conjugation in ethyl radical, it is more stable.

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