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The pH of a solution of AgCI(s) with solubility product `1.6 xx 10^(-10)` in 0.1 M Nacl solution would be :A. `1.26xx10^(-5)M`B. `1.6xx10^(-9)M`C. `1.6xx10^(-11)M`D. zero |
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Answer» Correct Answer - B `{:(,underset((s))(AgCl),hArr,Ag^(+),+,Cl^(-)),("Initial",-,,0,0),(Eq^(m),-,,S^(1),S^(1)):}` `{:(,NaCl,to,Na^(+),+,Cl^(-)),("Initial",C,,0,,0),("Final",0,,C,,C):}` So Ionic product `Q=K_(sp)=[Ag^(+)][Cl^(-)]` `" "K_(sp)=(S^(1))" "(C)` `becalseCl^(-)` ion due to common ion obtained from NaCl `S^(1)=(K_(sp))/(C)=(1.6xx10^(-10))/(0.1)=1.6xx10^(-9)` |
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