1.

The polarimeter readings in an experiment to measure the rate of inversion of cane sugar (1st order reaction) were as follows {:("time(min)",:,0,30,oo),("angle(degree)",:,30,20,-15):} Identify the true statement(s) ? [log2=0.3,log 3=0.48, log 7=0.84, log_e10=2.3]

Answer»

The HALF LIFE of the reaction is 75 min
The solution is optically inactive at 120 min
The equimolar mixture of the product is dextrorotatory
The ANGLE would be `7.5^@` at half time

Solution :`{:(0,30,oo),(30,20,-15):}`
`k=1/30 2.3"log"(30-(-15))/(20-(-15))=1/30"log"45/35`
`:. T_(1//2)75` min
`k=1/t2.3 "log"45/(0-(-15))`
t=120 min
`(30-(-15))/(x-(x-15))=2` at half time
`IMPLIES 45(x+15)=2 implies x+15=45/2implies x=22.5-15=7.5^@`


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