1.

The polarity of the carbon-halogen bond is responsible for the nucleophilic substitution reactions of alkyl halides which mostly occur by S_(N)1 and S_(N)2 mechanisms. The rates of S_(N)2 reactions among other things are governed by steric factors while than of S_(N)1 reactions are governed by the stability of intermediate carbocations. chirality has a profound role in undersetanding the mechanism of S_(N)1 and S_(N)2 reactions. whereas S_(N)2 reactions of chiral alkyl halides are accompanied by inversion of configuration, S_(N)1 reactions are characterised by racemisation. Q. Which of the following is an example of S_(N)2 reaction?

Answer»

`CH_(3)Br+OH^(-)toCH_(3)OH+Br^(-)`
`(CH_(3))_(2)CHBr+OH^(-)(CH_(3))_(2)CHOH+Br^(-)`
`CH_(3)CH_(2)OH OVERSET(-H_(2)O)to CH_(2)=CH_(2)`
`CH_(3)CH_(2)OH overset(-H_(2)O)to CH_(2)=CH_(2)`

Answer :A


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