1.

The pressure of two pure liquid A and B which form an ideal solutions are 400 mm Hg and 800 mm Hg respectively at temperature T.A liquid containing 3:1 molar composition pressure can be varied.The solutions is slowly vapourized at temperature T by decreasing the applied pressure starting with a pressure of 760 mm Hg.A pressure gauge (in mm) Hg is connected which give the reading of pressure applied. The reading of pressure Gauge at bubble point is

Answer»

<P>500
600
700
None

Solution :`X_A=0.75 " " X_B=0.05` above 500 mm HG only liquid phase exists.
`P_("bubble") "POINT"=X_A P_A^@+X_B^@ P_B^@`
`P_("cqycqfyr fcUnq") =X_A P_A^@+X_B^@ P_B^@`
=0.75+400+0.25x800=500 mm
`y_A=0.75 , " " y_B=0.5`
At DEW point
`1/P_T=y_A/P_A^@+y_B/P_B^@implies1/P_T=0.75/400+0.25/800=(1.5+0.25)/800`
`implies P_T=800/1.75=457.14` mm Hg
Below dew point only vapour phase exists


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