1.

The rate of decomposition for methyl nitrite and ethyl nitrite can be given in terms of rate constant ("in" sec^(-1)) k_(1) "and"k_(2) respectively. The energy of activationsfor the two reactions are 152.30 kJ "mol"^(-1) "and" 157.7 kJ "mol"^(-1) as well as frequency factors are 10^(13)"and" 10^(14) respectively for the decomposition of methyl and ethyl nitrite. Calculate the approx. temperature at which rate constant will be same for the two reactions.

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ANSWER :282


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