InterviewSolution
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InterviewSolution
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The reaction `A(g) + 2B(g) rarr C(g) + D(g)` is an elementary process. In an experiment involvig this reaction, the initial partial pressure of `A` and `B` are `p_(A) = 0.60 atm` and `p_(B) = 0.80 atm`, respectively. When `p_(C ) = 0.20 atm`, the rate of reaction relative to the initial rate isA. `(1)/(6)`B. `(1)/(48)`C. `(1)/(4)`D. `(1)/(24)` |
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Answer» Correct Answer - 1 Initial Rate`=k[A][B]^(2)` Rate `1=k[0.60][0.80]^(2)" " ….(i)` Rate `2=k[0.60][0.80]^(2)" "….(ii)` Given `Rxxn` `{:(A(g),+,2B(g),rarr,C(g),+,D(g),),(0.60atm,,0.80atm,,0,,0,t=0),((0.60-0.2),,(0.80-0.40),,0.20,,0.20atm,),(0.40atm,,0.40atm,,0.20atm,,0.20atm,t=1):}` ltBRgt Put value of pressure of `t=t` in rate equation `(II)` Rate `2=k(40][40]^(2)` `("Rate2")/("Rate 1")=(k[40][40]^(2))/(k[60][80]^(2))` `(Rate2)/(Rate1)=(2)/(3)xx(1)/(4)=(1)/(6)` |
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