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The standard state Gibbs free energies of formation of C(graphite) and C(diamond) at T = 298K are Δf G∘ [C(graphite)]=0 kJ mol−1 Δf G∘ [C(diamond)]=2.9KJ mol−1 The standard state means that the pressure should be 1 bar, and substance should be pure at a given temperature. The conversion of graphite [C(graphite)] to diamond [C(diamond)] reduces its volume by 2×10−6m3 mol−1. If C(graphite) is converted to C(diamond) isothermally at T = 298K, the pressure at which C(graphite) is in equilibrium with C(diamond), is [Useful information: 1J=1kg m2 s−2], 1 Pa=1 kgm−1s−2; 1 bar=105 Pa

Answer» The standard state Gibbs free energies of formation of C(graphite) and C(diamond) at T = 298K are
Δf G [C(graphite)]=0 kJ mol1
Δf G [C(diamond)]=2.9KJ mol1
The standard state means that the pressure should be 1 bar, and substance should be pure at a given temperature. The conversion of graphite [C(graphite)] to diamond [C(diamond)] reduces its volume by 2×106m3 mol1. If C(graphite) is converted to C(diamond) isothermally at T = 298K, the pressure at which C(graphite) is in equilibrium with C(diamond), is
[Useful information: 1J=1kg m2 s2],
1 Pa=1 kgm1s2; 1 bar=105 Pa


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