1.

What are vitamins? Name any two diseases caused by deficiency of vitamins A. Write the structures of (a) nucleoside (b) nucleotide. How are I-nitropropane, 2-nitropropane and 2-methy-2 nitropropane are distinguised from each other using nitrous acids?

Answer»

Solution :Vitamins are the organic substance that must be SUPPLIED to permit proportionate growth in living being or for the maintenance of the STRUCTURE.
Diseaes: 1. Night blindness
2. Retardation of growth
3. DRYNESS of hair and skin

Primary nitroalkane reacts with NITROUS acid to form blue COLOURED nitroso-nitro propane which reacts with NaOH to give red colour solution.
`CH_(3) - underset(H)underset(|)overset(H)overset(|)(C )- underset(H)underset(|)overset(H)overset(|)(C ) -overset(O)overset(||)(N) - O + HO - N = O to

When 2-nitropropane is treated withh nitrous acid it gives blue coloured nitro-nitroso propane which do not react with NaOH due to absence of alpha hydrogen.
`CH_(3) - underset(H)underset(|)overset(CH_(3))overset(|)(C ) - overset(O)overset(|)(N) - O + HO - N = O to` CH_(3) - underset(NO)underset(|)overset(CH_(3))overset(|)(C ) - overset(O)overset(||)(N) - O + H_(2) O`
2-methyl 2-nitropropane does not react with nitrous acid due to absence of alpha hydrogen.


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