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What is meant by toral entropy change of a process? Assuming the thermodynamic relationship ΔG = ΔH - TΔS, derive the relationship ΔG = TΔStotal for a system. |
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Answer» Total entropy change of a process if entropy change taking place in universe, i.e. ΔSsystem + ΔSsurrounding = ΔSTotal ΔSTotal = ΔSsys – q/T = ΔSSys – ΔH/T TΔSTotal = TASSys – ΔH [∵ ΔG = ΔH – TΔS] TΔSTotal = -ΔG ΔG = -TΔSTotal |
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