1.

What is meant by toral entropy change of a process? Assuming the thermodynamic relationship ΔG = ΔH - TΔS, derive the relationship ΔG = TΔStotal for a system.

Answer»

Total entropy change of a process if entropy change taking place in universe, i.e. 

ΔSsystem + ΔSsurrounding = ΔSTotal 

ΔSTotal = ΔSsys – q/T = ΔSSys – ΔH/T

TΔSTotal = TASSys – ΔH [∵ ΔG = ΔH – TΔS] 

TΔSTotal = -ΔG 

ΔG = -TΔSTotal



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