1.

What is the major product in the reaction ? CH_(3) - CH = CH_(2) + HBr overset((C_(6)H_(5)CO)_(2)O_(2))rarr

Answer»

`CH_(3) - CH_(2) - CH_(2)BR`
`CH_(3) - underset(Br)underset(|)(CH) - CH_(3)`
`underset(Br)underset(|)(CH_(2))-underset(Br)underset(|)(CH) - CH_(3)`
`underset(Br)underset(|)(CH_(2)) - CH = CH_(2)`

SOLUTION :`CH_(3) - CH = CH_(2) underset("Peroxides")overset(HBr)rarr CH_(3) - underset(H)underset(|)(CH) - CH_(2)Br`
In the presence of peroxides, the reaction PROCEEDS as anti-Markovnikov.s reaction.


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