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What weight of `NaHSO_3` is required to react with 100 " mL of " solution containing 0.33 g of `NaIO_3` according to the following reaction: `IO_3^(ɵ)+HSO_3^(ɵ)toI^(ɵ)+SO_3^(2-)` (a). `0.52g` (b). 5.2 g ltbr) (c). `1.04g` (d). `10.4g` |
Answer» `Mw(NaHSO_3)=23+1+32+3xx16=104g` `Mw(NaIO_3)=23+127+2xx16=198g` `[6e^(-)+IO_3^(ɵ)toI^(ɵ)](n=6)` `[HSO_3^(ɵ)toI^(ɵ)](n=2)` Strength `(gL^(-1))` `=`Normality`xxEw` Normality of `NaIO_3=("Strength")/(Ew)` `=(3.3)/((198)/(6))=(3.3xx6)/(198)=0.100` Strength of `NaIO_3=(0.33g)/(100mL)` `-=(0.33xx1000)/(100)=3.3gL^(-1)` Normality of `NaIO_3=0.1N` m" Eq of "`NaIO_3=NxxV(mL)=0.1xx100=10mEq` `NaHSO_3-=NaIO_3` `mEq-=mEq-=10mEq` `m" Eq of "NaHSO_3=10mEq` `=10xx10^(-3)Eq` `=10xx10^(-3)xxEw(NaHSO_3)` `=10xx10^(-3)xx(104)/(2)g=0.52g` |
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