1.

When an orange coloured crystallccompound [A] was heated withcommon salt and concentrated sulphuricacid , an orange red colouredgas [B] wasevolved. The gas [B] on passingthrough NaOH solution gave a yellow solution [C] . Thesolutionon reactingwith an aqueous solution of lead acetate gave a yellow precipitate. The yellow solution [C] containsmainly

Answer»

Sodium sulphate
Sodium CHROMATE
Sodium dichromate
Potassium chromate.

SOLUTION :(b) The yellow solution (C) contains sodium chromate `(Na_(2)CrO_(4))` which is formed on reacting chromyl chloride with sodium hydroxide (NAOH) solution
`CrO_(2)Cl_(2)+4NaOH to underset("(yellow solution)")(Na_(2)CrO_(4))+2NaCl+2H_(2)O`


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