1.

When para-bromotole istreated withNaNH_(2) in etherthe bromineis lost andmixture of paraandmeta CH_(3)C_(6)H_(4)NH_(2) product is obtained. What is kind of intermediate wouldaccount for this ?

Answer»

ACHARGE delocalised anion formed bynucleophilic addition of`NH_(2)^(ө)` to thebenzene ring .
A charge delocalisedanion formedbyabstractionof methyl proton by thebase `overset(ө) NH_(2)`.
An arylcationfromedby LOSSOF bromide ION .
A benzene SPECIES formedby elimination of HBr.

Answer :D


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