1.

Which of following species does not exert a resonance effect

Answer»

`C_(6)H_(5)OH`
`C_(6)H_(5)CL`
`C_(6)H_(5)NH_(2)`
`C_(6)H_(5)NH_(3)`

Solution :`C_(6)H_(5)NH_(2)+H^(+)rarrunderset("ANILINIUM ion")(C_(6)H_(5)overset(+)(NH_(2))`
Anilinium ion formed by ANILINE on accepting a proton is less resonance stabilised than aniline. Due to absence of lone pair in conjugation of double bond of BENZENE it does not exert a resonance effect.


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