1.

Which of the following complex is heteroleptic ?

Answer»

`[Co(NH_(3))_(6)]Cl_(3)`
`PtCl_(4).4NH_(3)`
`PtCl_(2).4NH_(3)`
`PtCl_(4).3NH_(3)`

Solution :(b) All `Pt^(4+)` COMPLEXES have C.N.=6,`[Pt(NH_(3))_(4)Cl_(2)]Cl_(2)`
(c ) `[Pt(NH_(3))_(2)Cl_(2)].2NH_(3) " or "[Pt(NH_(3))_(4)]Cl_(2)`
(d) `[Pt(NH_(3))_(3).Cl_(3)].Cl "or " [Pt(NH_(3))_(2).Cl_(4)].NH_(3)`


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