1.

Which of the following compounds (s) has Z configuration? I. II. III.

Answer»

Only I
Only II
Only III
I and III

Solution :When the groups with higher priority (i.e. with high atomic number) are present on same side of double bond, then the CONFIGURATION is Z but when present on OPPOSITE side of double bond, the configuration is E.

(Priority : `Cl gt H` and `Br gt F`)
(ii)
(Priority : `Cl gt H` and `Br gt F`)

(Priority : `Br gt Cl` and `CH_(3) gt H)`
HENCE, compounds (i) and (iii) have (Z) configuration.


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