1.

Which of the following easily undergo nucleophilic substitution by S_(N)1 mechanism in butanol?

Answer»

`C_(6)H_(5)CH_(2)Br`
`BrCH_(2)CH=CH_(2)`
`(CH_(3))_(3)CBr`
`(CH_(3))_(3)C CH_(2)Br`

Solution :All form stable carbocations. THEREFORE, all option are correct.
(a) `C_(6)H_(5)overset(+)(C)H_(2)`
(STABILIZED by RESONANCE over the phenyl ring.)


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