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Which of the following factor may be regarded as the main cause of lanthanide contraction?A. Poor shielding of `4f`-electrons in compare to other electrons in the sub-shellB. Effective shielding of one of the `4f`-electrons by another in the sub-shellC. Poorer shielding of `5d` electron by `4f`-electrons.D. Greater shielding of `5d` electrons by `5f-electron. |
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Answer» Correct Answer - A This phienomenon is associated with the intervention of the `4f` orbitals which must be filled before the `5d` series of elements begin The filling of `4f` before `5d` orbital results in a regular decrease in atomic radii called is lanthanoid contraction. This is because of poor shielding of one of the `4f`-electrons by another in the sub-shell. |
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