1.

Which of the following has `d^(1)` configuration and is stable ?A. Cr `( +5)`B. Mn `( +6)`C. both (1) and (2)D. V `( +4)`

Answer» Correct Answer - D
Except `V(+4)`, all other with this configuration are either reducing or undergo disproportionation. For example, disproportionation occurs for `Cr(+5)` and `Mn(+6)` as follows:
`3 CrO_(4)^(3-) + 8H^(+) rarr 2 CrO_(4)^(2-) + Cr^(3+) + 4H_(2)O`
`3MnO_(4)^(2-) + 4H^(+) rarr MnO_(2) + 2H_(2)O`


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