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Which of the following is true regarding non-ideal solutions with negative deviation?(a) The interactions between the components are lesser than in the pure components(b) ΔVmixing = +ve(c) ΔHmixing = +ve(d) They form maximum boiling azeotropesThe question was posed to me in a national level competition.The doubt is from Ideal and Non-Ideal Solutions in chapter Solutions of Chemistry – Class 12

Answer»

Correct CHOICE is (d) They form maximum boiling azeotropes

Easiest explanation: The INTERACTIONS between the components of a non-ideal solution showing negative deviation are GREATER than the pure components. The change in VOLUME and ENTHALPY after mixing is negative, i.e., ΔVmixing = -ve, ΔHmixing = -ve.



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