`K_(2)Cr_(2)O_(7)` solution in acidic medium is ORANGE `K_(2)Cr_(2)O_(7)` solution becomes yellow on increasing the PH beyond 7 on PASSING `H_(2)S` through acidified `K_(2)Cr_(2)O_(7)` solution, a milky colour PREFERRED over `K_(2)Cr_(2)O_(7)` in volmetric analysis
Solution :`Na_(2)Cr_(2)O_(7)` is hydrophilic in nature and hence `K_(2)Cr_(2)O_(7)` is more appropriate in volumetric analysis.