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X-ray crystallography reveals many aspects of the structure of metal halldes. The radius ratio (r_(+)//r_(-)) is a useful parameter to rationalize their structure and stability. A table or radius ratio (r_(+)//r_(-)) for some alkali halide is given below :For a given anion, the graph for NaCl type structure levels off at low r_(+)//r_(-) values because of : |
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Answer» cation - cation CONTACT ALONG the face DIAGONAL |
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