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1.

An organic compound `C_(3)H_(6)O` does not give a precipitate with 2,4-Dintirophenyl hydrazine reagent-A. `CH_(3)CH_(2)CHO`B. `CH_(3)COCH_(3)`C. `CH_(2)=CH-CH_(2)OH`D.

Answer» Correct Answer - C::D
2.

Which of the following will give yellow precipitate with `I_(2)//NaOH`-A. `ICH_(2)COCH_(2)CH_(2)`B. `CH_(2)COOCOCH_(3)`C. `CH_(3)CONH_(2)`D. `CH_(3)CH(OH)CH_(2)CH_(3)`

Answer» Correct Answer - A
3.

`C_(5)H_(10)` represents three isomeric alkenes `A_(1),A_(2)` and `A_(3)`. Each on hydrogeration gives `2-`methylbutane. `A_(1)` and `A_(2)` on oxymercuration-demercuration give the same `3^(o)` alcohol. `A_(2)` and `A_(3)` on hydroboration oxidation give different `1^(o)` alcohol. Assign structures to `A_(1), A_(2)` and `A_(3)` and explain the reactions.

Answer» Correct Answer - `A_(1),A_(2)`orA_(3)overset(H_(2))rarrH_(3)Cunderset(CH_(3))underset(|)CHCH_(2)CH_(3)`
This shows that each of `A_(3),A_(2)` and `A_(3)` have same `C-chain: only position of `(C=C)` is to be decided.
`A_(1),A_(2)`underset("demercuration")overset("oxymercuration")rarr3^(o)` alcohol
hecne `A_(1)` and `A_(2)` have groupings.
`A_(2)` and `A_(3)`overset("hydroboration oxidation")rarr1^(o)` alcohol
This indicates presence of `(CH_(2=)` grouping at the terminal. Hence,
`A_(1)` is `CH_(3)underset(CH_(3))underset(|)C=CHCH_(3)`
`A_(2)` is CH_(3)CH_(2)underset(CH_(3))underset(|)C=CH_(2)`
`A_(3)` is CH_(3)underset(CH_(3))underset(|)CHCH=CH_(2)`
`A_(1)` or `A_(2) underset("demercuration")overset("oxymercuration")rarrCH_(3)underset(CH_(3))underset(|)overset(OH)overset(|)(C)CH_(2)CH_(3) 3^(o)` alcohol `(X)`
`A_(2)underset("oxidation")overset("hydroboration")rarr CH_(3)underset(CH_(3))underset(|)CHCH_(2)CH_(2)OH 1^(o)` alchohol `(Z)`
`Y` and `Z` are different `1^(o)` alcohols.
4.

`2-`Methylbutane on reacting with bromine in the presence of sunlight gives mainlyA. `2-`bremo`-2-`methylbutaneB. `1-`bromo`-2-`methylbutaneC. `1-`bromo`-3-`methylbutaneD. `2-`bromo`-3-`methylbutane

Answer» Correct Answer - A
5.

In the reaction `CH_(2)Br+Mgoverset("dry ether")rarrA+CH_(3)CHOrarr"adduct"overset(H_(3)O^(o+))rarrB`. The product (B) is :A. B. C. D.

Answer» Correct Answer - B
6.

Acetaldehyde reacts with NaoH to form:-A. `CH_(3)-CH_(2)-overset(OH)overset(|)CH-overset(H)overset(|)C=O`B. `CH_(3)-overset(OH)overset(|)CH-CH_(2)-overset(H)overset(|)C=O`C. `CH_(3)-underset(OH)underset(|)CH-underset(O)underset(||)C-CH_(3)`D. `underset(OH)underset(|)CH_(2)-CH_(2)=CH_(2)-underset(H)underset(|)C=O`

Answer» Correct Answer - B
7.

`1-`Methylcyclohexene is allowed to react with `B_(2)H_(6)`. The product is then treated with `H_(2)O_(2)` and `NaOH`. The reaction is - The product formed isA. `1-`methylcyclohexanolB. `2-`methylcyclohexanolC. methylcyclohexaneD. cyclohexanol

Answer» Correct Answer - B
8.

Which one of the following reagents is suitable for the converston of 2-cyclohexansion into 3-methylcyclohexanone ?A. `CH_(3)Mgl`B. `(CH_(3))_(2)CuLi`C. `CH_(3)I_(2)` and `Zn`D. `CH_(3)AlCl_(2)`

Answer» Correct Answer - B
9.

2-Methylcyclohexanone is allowed to react with metachloroperoxobenzoic acid. The major product formed in the reaction isA. B. C. D.

Answer» Correct Answer - C
10.

In the reaction The product (A) is :A. B. C. D.

Answer» Correct Answer - C
11.

Which of the following statement is//are false.A. Aldol condensation is given by all carbonyl compounds.B. Acetaldehyde and acetone can be distinguished by lodoform test.C. `LiAIH_(4)` converts ketones into secondary alcohols.D. Methanol can be distinguished from ethanol by haloform reaction

Answer» Correct Answer - A::B
12.

Assertion : `2, 2-` Dimethylpropanal undergoes Cannizzaro reaction with conc. `NaOH` Reason : Cannizzaro reaction is a disproportionation reactionA. Statement-I is True, Statement-II is True : Statement-II is a correct explanation for Statement-IB. Statement-I is True, Statement-II is True : Statement-II is `NOT` a correct explanation for Statement-IC. Statement-I is True, Statement-II is False.D. Statement-I is False, Statement-II is True.

Answer» Correct Answer - D
13.

`CH_(3)CH_(2)-O-CH_(2)Phunderset(HI)overset("Cold con.")rarrCH_(3)CH_(2)-OH+PhCH_(2)-I`, write mechanism of given reaction.

Answer» Mechanism:-
`CH_(3)CH_(2)underset(..)overset(..)OCH_(2)Phoverset(H^(o+))hArrCH_(3)CH_(2)-underset(H)underset(|)overset(o+)O-CH_(2)PhrarrCH_(3)CH_(2)OH+Phoverset(o+)CH_(2)overset(I^(o+))rarrPhCH_(2)I+CH_(3)CH_(2)-OH`
14.

In iso-pentane, the `H` atom that can be most easily substituated by free radical mechanism is on:- `overset(1)CH_(3)-underset(CH_(3))underset(|)overset(2)CH-overset(3)CH_(2)overset(4)CH_(3)`A. `C-1`B. `C-2`C. `C-3`D. `C-4`

Answer» Correct Answer - B
Ease of subsituation of various types of `H` atoms `3^(@)gt2^(@)gt1^(@)`.
15.

Ozonolysis of benzene in vigorous condition yields :A. GlyoxalB. GlycerineC. GlycolD. Glycerol

Answer» Correct Answer - A
Ozonolysis of benzene yields glyoxal. Benzene adds three molecules of ozone and forms benzene triozonide which of decomposition with water gives three molecules of glyoxal. `underset("benzene")(C_(6)H_(6))+underset("ozone")(3O_(3))rarrunderset("benzene triozonide")(C_(6)H_(6)O_(9))`
`underset("benzene trizonide")(C_(6)H_(6)O_(9))overset(+H_(2)O)rarr3underset("Glyoxal")underset(H-C=O)overset(H-C=O)overset(|)
16.

An organic compound A ( mol wt = 180) is acylated with `CH_3 COCl` to get acylated compound of mol wt. 390. What is the number of amino groups present per molecule of the compound A?A. 2B. 5C. 4D. 6

Answer» Correct Answer - B
Change in molecular mass =42 per `NH_(2)`
180 molecular mass after acylation gives compound of molecular mass 390
Change in molecular mass =390-180=210
so number of `NH_(2)` group `=(210)/(42)=5`
17.

Aldoximes on reduction with `LiAlH_(4)` or `Na//C_(2)H_(5)OH` giveA. `C_(6)H_(5)CH_(2)NH_(2)`B. `C_(6)H_(5)NHCH_(3)`C. D. `C_(6)H_(5)NH_(2)`

Answer» Correct Answer - A
18.

Which of the following reactions can be employed for getting odd carbon alkanes in good yield ?A. Wurtz reactionB. Corey-House reactionC. BothD. None of these

Answer» Correct Answer - B
Wurtz reaction is suitable for symmetrical (even) alkanes
19.

Complete oxidation of ethane yields -A. EthanolB. Ethanoic acidC. Ethanal,D. `CO_(2)` and `H_(2)O`

Answer» Correct Answer - D
`2C_(2)H_(6)+7O_(2)rarr4CO_(2)+6H_(2)O`
20.

How much propanol is required for dehydration to get `2.24` litre of propene at `N.T.P`. If yield is `100%`

Answer» `C_(3)H_(8)O+H_(2)SO_(4)rarrC_(3)H_(6)+H_(2)O+H_(2)SO_(4)`
Molecular weight of propanol `=60`
from the equation given above we can see that from dehydration of `1` mole or `60` gram of propanol we get `1` mole (`22.4`lit) of propene as product.
`because 22.4` litre of `C_(3)H_(6)` can be get from dehydration of `60g` of propanol.
`therefore 1` litre of propene can be get from dehydration of `(60)/(22.4)g` of propanol
21.

The `IUPAC` name of `C_(6)H_(5)COCl` isA. Benzoyl chlorideB. Benzene chloro ketoneC. Benzene carbonyl chlorideD. Chloro phenyl ketone

Answer» Correct Answer - C
22.

How many litre of Oxygen required for complete conbustion of `6.0g` ethane at `NTP` ?

Answer» `2C_(2)H_(6)+7O_(2)rarr4CO_(2)+6H_(2)O`
`60g` ethane required `O_(2)` (at `NTP`) `=7xx22.4` litre
`1g` ethane required `O_(2)` (at `NTP`) `=(7xx22.4)/(2xx30)litre`
`6g` ethane required `O_(2)` (at `NTP`) `=(7xx22.4)/(2xx30)xx6=15.68` litre
23.

Statement-I : Alkyness are more reactive than alkenes towards electrophilic reagents like `H^(+)`. Because Statement-II : The alkyl carbocation formed from alkene is more stable than the uinyl carbocation formed from alkyne.

Answer» Correct Answer - D
24.

Among the compounds the order of decreasing reactivity towards electrophilic substitution isA. `IIgtIgtIIIgtIV`B. `IIIgtIgtIIgtIV`C. `IVgtIgtIIgtIII`D. `IgtIIgtIIIgtIV`

Answer» Correct Answer - B
25.

The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- The observed pattern of electrophilic substitution can be explained by-A. The steric effect of the halogenB. The steric effect of the tert-butyl groupC. The electronic effect of the phenolic groupD. The electronic effect of the turt-butyl group

Answer» Correct Answer - A::B::C
26.

Identify the correct order of reactivity in electrophilic substitution reaction of the following compounds A. `1gt2gt3gt4`B. `4gt3gt2gt1`C. `3gt1gt3gt4`D. `2gt3gt1gt4`

Answer» Correct Answer - A
27.

Statement-I: Phenol is more reactive than benzene towards electrophilic substitution reaction. Because Statement-II: In the case of phenol, the intermediate carbocation is more reasonance stablized.A. Statement-I is True, Statement-II is True : Statement-II is a correct explanation for Statement-IB. Statement-I is True, Statement-II is True : Statement-II is `NOT` a correct explanation for Statement-IC. Statement-I is True, Statement-II is False.D. Statement-I is False, Statement-II is True.

Answer» Correct Answer - A
28.

The correct order of reactivity towards the electrophilic substitution of the compounds anisole (I), benzene (II) and nitrobenzene (III) is :-A. `IIIgtIIgtI`B. `IIgtIIIgtI`C. `IltIIgtIII`D. `IgtIIgtIII`

Answer» Correct Answer - D
29.

Aldehyde and ketones are specially susceptible susceptible to nucleophile addition because carbonyl group (due to electronegatvity different between carbon and oxygen). Positive charge on carbon makes it reactive towards the nucleophile. This addition is catalysed by acid. Reactivity of carbonyl compound towards nucleophilic addition increases in the electron deficience at carbonyl carbon. Thus, (-I.E.) group increase while (+I.E.) groups decrease the reactivity of carbonyl compound Which of the following is most reactve to give nucleophilic addition?A. `FCH_(2)CHO`B. `CICH_(2)CHO`C. `BrCH_(2)CHO`D. `ICH_(2)CHO`

Answer» Correct Answer - A
30.

Which of the following reacts with water to form very stable product ?A. `CH_(3)Cl`B. `C Cl_(4)`C. `C Cl_(3)CHO`D. `CH_(2)ClCH_(2)Cl`

Answer» Correct Answer - C
31.

Statement-I : Of two isomeric alkennes shown, `II` is more stable than `I`. Because Statement-II : The alkene (II) has `sp^(2)-hybridlzed carbons.

Answer» Correct Answer - C
32.

Statement-I: `R-C-=O^(+)` is more stable than `R-C^(+)=O` Because Statement-II: Resonance in carbonyl compound provides A. Statement-I is True, Statement-II is True : Statement-II is a correct explanation for Statement-IB. Statement-I is True, Statement-II is True : Statement-II is `NOT` a correct explanation for Statement-IC. Statement-I is True, Statement-II is False.D. Statement-I is False, Statement-II is True.

Answer» Correct Answer - B
33.

Consider the following reaction. (1R,3S)-cis-Bromo-3-methylcyclohexane ltbr gtThe product formed in the reaction isA. (1R,3S)-cis-3-methylcyclohexanolB. (1S,3R)-cis-3-methylohexanolC. (1S,3S)-trans-3-methylcyclohexanolD. (!R,3R)-trans-3-methylcyclohexanol

Answer» Correct Answer - C
34.

Statement-I : Buta`-1,3-`diene is less stable than Penta`-1,4-`do,eme, ltbr. Because Statement-II : Buta`-1,3-`diene has greater number of reasonating structures and delocallsed electron cloud.

Answer» Correct Answer - D
35.

Statement-I : Iodination of alkanes is carried out in the presence of iodic acid. Because Statement-II : Iodic acid removes `I_(2)` gas from the reaction mixture.

Answer» Correct Answer - C
36.

Statement-I : Propene is more reactive than ethnc with `HCl`. Because Staement-II : Propene is more stable than ethene.

Answer» Correct Answer - B
37.

In the presence of a small amount of phosphorous, aliphatic carboxylic acids react with chlorine or bromine to yield a compound in which `alpha`- hydrogen has been replaced by halogen. This reaction is known as :A. Elard reactionB. Hell-Volhard-Zelinsky reactionC. Wolff-Kischner reactionD. Rosenmund reaction

Answer» Correct Answer - B
`CH_(3)-underset(O)underset(||)C-OHoverset(Red P+Cl_(2))rarrCl-CH_(2)-underset(O)underset(||)C-OH`
38.

The intermediate during the addition of `HCl` to propene in the presence of peroxide is :A. `CH_(3)CHCH_(4)CL`B. `CH_(3)overset(o+)CHCH_(3)`C. `CH_(3)CH_(2)overset(*)CH_(2)`D. `CH_(3)CH_(2)overset(o+)CH_(2)`

Answer» Correct Answer - B
39.

Propyne on reaction with aqueous chlorine gives-A. `1,1,2,2-`TetrachloropropaneB. `1,2-`DichloropropeneC. `1,1-`DichloropropanoneD. `2,2-`Dichloropropanone

Answer» Correct Answer - C
`CH_(3)-C-=CH+2HOClrarr[CH_(3)-underset(OH)underset(|)overset(OH)overset(|)(C)-CHCl_(2)]overset(-H_(2)O)toCH_(3)-overset(O)overset(||)(C)-CHCl_(2)`
40.

Propyne and propene can be distinguished by `:`A. conc. `H_(2)SO_(4)`B. `Br_(2)` in `C Cl_(2)`C. `dil.KMnO_(4)`D. `AgNO_(3)` in ammonia

Answer» Correct Answer - D
41.

Following statements is/are correct about mixture :A. mixture is 3-types of oximesB. mixture is 2-types of oximesC. all are optically activeD. one is optically active

Answer» Correct Answer - A
42.

The product of acid hydrolysis of P and Q can be distinguished by A. 2,4-DNPB. Lucas reagent `(ZnCl_(2)+"conc."HCl)`C. `NaHSO_(3)`D. Fehlings solution

Answer» Correct Answer - D
43.

Any one of the product formed is : A. B. C. D.

Answer» Correct Answer - C::D
44.

Nitrobenzene can be prepared from benzene by using a mixture of conc. `HNO_3` and conc. In the nitrating mixture, `HNO_3` acts as a/anA. BaseB. AcidC. Reducing agentD. Catalyst

Answer» Correct Answer - A
45.

Statement-I : Benzene on heating with conc. `H_(2)SO_(4)` gives benzene sulphonic acid which when heated with superheated steam under pressure gives benzene. Because Statement-II : Sulphonation is a reversible process.A. Statement-I is True, Statement-II is True : Statement-II is a correct explanation for Statement-IB. Statement-I is True, Statement-II is True : Statement-II is `NOT` a correct explanation for Statement-IC. Statement-I is True, Statement-II is False.D. Statement-I is False, Statement-II is True.

Answer» Correct Answer - A
46.

Statement-I : Chlorination of ethyl benzene with Cl_(2)` in prescence of heat and light nearly yield `1-`yield `1-`chloro`-1-`phenyl ethane as major product. Because Statement-II : The reaction oC Curs through intermediate formation of the radical `C_(6)H_(5)CH-CH_(3)`.

Answer» Correct Answer - A
47.

Cyclohexene on ozonolysis followed by reaction with zinc dust and water gives compound E. Compound E on furhter treatment with aqueous KOH yields compound F. Compound F isA. B. C. D.

Answer» Correct Answer - A
48.

The decreasing order of strength of the bases, `OH^(-), NH_(2)^(-), H-C-=C^(-)` and `CH_(3)-CH_(2)^(-)`:A. `CH_(3)-CH_(2)^(-)gtNH_(2)^(-)gtHC-=C^(-)gtOH^(-)`B. `HC-=C^(-)gtCH_(3)-CH_(2)^(-)gtNH_(2)^(-)gtOH^(-)`C. `OH^(-)gtNH_(2)^(-)gtHC-=C^(-)gtCH_(3)-CH_(2)^(-)`D. `NH_(2)^(-)gtHC-=C^(-)gtOH^(-)gtCH_(3)-CH_(2)^(-)`

Answer» Correct Answer - A
49.

Write `IUPAC` names of :

Answer» (a) `1,5-`Dimethylcyclohexene: (b) `1-(2-`butenyl) cyclothex`-1`-`ene
50.

`90 mL` of oxygen is required for complete combustion of unsaturated `20mL` gaseous hydrocarbon, hydrocarbon is ?

Answer» `("Volume of Hydrocarbon")/("Volume of" O_(2))=(2)/(3n)` (for Alkene)
`("Volume of Hydrocarbon")/("Volume of" O_(2))=(2)/(3n-1)` (for alkyne)
By putting the values in above fomulae we can find the hydrocarbon for which `n` is natural number. `
(20)/(90)=(2)/(3n) n=3` So hydrocarbon is Propene `[C_(3)H_(6)]`.