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351.

Strongest base isA. `CH_(2) = CH-CH_(2)-NH_(2)`B. `CH -= C-CH_(2)-NH_(2)`C. `CH_(3)CH_(2)CH_(2)NH_(2)`D.

Answer» Correct Answer - C
352.

Which of these is the strongest base?A. B. C. D.

Answer» Correct Answer - D
353.

For the following compounds, which is the strongest base and which is strongest acid? A. II = Strongest base, I = Strongest acidB. IV=Stronger base, III=Stronger acidC. III = Strongest base, IV = Strongest acidD. II = Strongest base, III = Strongest acid

Answer» Correct Answer - C
354.

Amongst the following, the strongest base in aqueous medium isA. `CH_(3)NH_(2)`B. `(CH_(3))_(3)N`C. `(CH_(3))_(2)NH`D. `C_(6)H_(5)NHCH_(3)`

Answer» Correct Answer - C
355.

Which of the following is the strongest Bronsted base?A. B. C. D.

Answer» Correct Answer - A
356.

Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. `(i)(CH_(3))_(2)CHNH_(2)" "(II)CH_(3)(CH_(2))_(2)NH_(2)" "CH_(3)NHCH(CH_(3))_(2)` `(iv)(CH_(3))_(3)CNH_(2)" "(v)C_(6)H_(5)NHCH_(3)" "(vi)(CH_(3)CH_(2))_(2)NCH_(3)` `(vii) m-Brc_(6)H_(4)NH_(2)`

Answer» 1- Methylethanamine (`1^(@)` amine
Propa-1-amine `(1^(@)"amine")`
(iii) N-Methyl-2-methylethanamine `(2^(@)"amine")`
(iv)2-Methylpropan-2-amine `(1^(@)"amine")`
(v) N-Methylbezamine or N-methylaniline `(2^(@)"amine")`
(vi) N-Ethyl-N-methylethanamine `(3^(@)"amine")`
(vii) 3-Bromobezenamine or 3-bromoniline `(1^(@)"amine")`
357.

When diethylamine is oxidized by `KMnO_(4)` the product is .A. `(CH_(3)CH_(2))_(2)NOH`B. `(C_(2)H_(5))_(2)N-N(C_(2)H_(5))_(2)`C. `(CH_(3)CH_(2))_(2)CO`D. `(CH_(3)CH_(2))CHNO`

Answer» Correct Answer - B
Secondary amines are oxidized `KMnO_(4)` to yield tetra- alkylhydrazine
`(CH_(3)CH)_(2)NHoverset(KMnO_(4))rarr(CH_(3)CH_(2))_(2)N-N(CH_(2)CH_(3))_(2)` .
358.

Which of the following primary amines yields tertiary nitrogen compounds on oxidation with potassium permanganate ?A. `RCN_(2)NH_(2)`B. `R_(2)CHNH_(2)`C. `R_(3)CNH_(2)`D. Both (2) and (3)

Answer» Correct Answer - C
Oxidation of t-alky1 amines with `KMnO_(4)`
`R-underset(R)underset(|)overset(R)overset(|)C-NH_(2)overset(KMnO_(4))rarrR-underset(R)underset(|)overset(R)overset(|)C-NO_(2)`
Here the maine must be primary and -`NH_(2)` group should be bonded to a tertiary carbon atom
`RCH_(2)NH_(2)overset[(O)]rarrRCHunderset(aldi mi n e)(=NH)overset(Ho+)rarrRCHO+NH_(3)`
`R_(2)CHNH_(2)overset(O)rarrunderset(Ketimin e)(R_(2)C=NH)overset (H^(o+))rarrR_(2)CO+NH_(3)` .
359.

Write the IUPAC name of the given compound :

Answer»

2,4,6 - Tribromoaniline or

2,4,6 - Tribromobenzenamine. 

360.

Give the IUPAC name of H2N - CH2 - CH2 - CH = CH2.

Answer»

But-3-en-1-amine.

361.

Give the IUPAC name of H2N - CH3 - CH2 - CH = CH2

Answer»

But-3-en-1-amine.