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2351.

Calculate the number of elctron which will together weigh `1 g `

Answer» Correct Answer - A::B::C
Number of electron
`= (1)/(9.1 xx 10^(-20) g ("electron")^(-1)) = 1.099 xx 10^(27) "electron" g^(-1)`
2352.

Which experiment observation led to the following conclassions ? a. Atom contains a massive positive center Size of the nucleus is very small

Answer» Correct Answer - A
2353.

Energy levels A. B, C. of a certain atom correspoinds to increasing value fo enrgy i.e., E_A lt E_B lt E_C If ` lambda _1, lambda_2`, and ` lambda_3` are the wavelengths of radistions corresponding to the transitions ( C) to ` B, B ` to (A) and ( C) to (A) respectively wich fo the following wstatemnt is correct .A. ` lambda_3 = lambda_1 + lambda_2`B. `lambda_3 ( lambda_2 )/(lambda_1+lambda_2)`C. `lambda+1+ lambda-02 + lambda_3 =0`D. `lambda_3^2 = lambda_1^2+lambda_2^2`

Answer» Correct Answer - B
` E_(3) = E_(1) E_(2) or ( hc)/(lambda_(3)) = (hc)/(lambda_(1)) + (hc)/(lambda_(2))`.
2354.

If the electron enrgy is ` -3 .4` eV, find the principal quantum number fo H-atom .

Answer» Correct Answer - 2
`E_n = E_1/n2 ( :. E_1 "for H-atom" =- 13. 6 eV)`
or ` n^2 = E_1 E_n = ( 13,6)/( -3.4) :. N=2` .
2355.

If the total enrgy fo an electron in a hydrogen linke atom in an ecited state is ` - 3. 4 eV` , the the de-Broglie wavelngth of the electron is :A. `6.6xx10^(-10)`B. ` 3 xx 10^(10)`C. ` 5 xx 10^(-9) `D. ` 9. 3 xx 10 ^(10)`

Answer» Correct Answer - A
Total energy ` = (-e^2)/(2r_n) =- 3 . 4 eV = E_(1) /n^2`
`:. N^(2) = ( -13 . 6)/( -3 . 4) = 4 :. N=2`
The velovity in II orbit
` = u_(1)/2 = ( 2 . 18 xx 10^8 )/2 cm sec ^(-1)`.
` therefore lambda = h/( mu) = (6.6 xx 10^(27)xx 2)/( 9. 108 xx 10^(-23) xx 2 . 18 xx 10^8)`.
` = 6.6. xx 10^(-10) `
` E_(1) =- 13 . 6 eV`.
2356.

For an atom with atomic numner `14` the number of orbits and orbitals in which elrctrons are prresent are respectively :A. ` 3,6`B. ` 6,3`C. ` 7,3`D. 3,8

Answer» Correct Answer - D
Electronic configuration of atomic no. `14 ` is
` 1s^(2)2 . 2s^2 2p^6 . 3s^2 3p^2` ( 3 orbits and (8) orbitals ).
2357.

As an electron is brought form an infinite distance close to the nucleus fo the atom the enrgy of the electron -nucleus system :A. Increased to a grater positive valueB. Decreases to a smaller positiive valueC. Decreases to a smaller positiive valueD. Increased to a grater positive value

Answer» Correct Answer - C
As a result fo attracton some enegy is released.
2358.

Light of wavelength ` 300 xx 10^(-9)` m strikes a metal surface with photoeoctric work function of ` 2. 13 eV`. Find out the kinetic enrgy fo the most energetic photoelectron .

Answer» Energy of photon = Work function + Kinetic enrgy Kinetic energy = Energy of photo -Work function
` = (hc)/(lambda) - "Work function"`
`(therefore "Work function" = 2 . 13 eV = 2 . 13 xx 1. 6 xx 10^(-19) J)`
`=[(6.626 xx 10^(-34) xx 3.0 xx 10^8)/(300 xx 10^(-9))] - 2 . 13 xx 1. 6 xx 10^(-19)`
` 6.626 xx 10^(-19) - 3. 41 xx 10 ^(-19) `
` K.E . = 3 . 216 xx 10^(-19) J`
The is the kinetic energy of most energyetic photoelectron.
2359.

Nucleus of an element contains 9 protons Its valency would be :A. 1B. 3C. 2D. 5

Answer» Correct Answer - A
Since its nucleus contain 9 proton so its. Atomic number is 9 and its electronic configuration is 2,7. So it require one more electron to complete its octet. Hence its valency is 1.
2360.

A single electron system has ionization enrgy ` 1. 118 xx 10^7 J mol^(-1)`. Calculate the numner of protons in the nucleus fo te system .

Answer» Correct Answer - 3
`:.` Ionization enrgy ` = Z^2 /n^2 xx 21. 69. xx 10^(-19) J`
` :. ( 1.118 xx 10^7)/( 6.023 xx 10^(23)) = (Z^2)/((1)^2) xx 2 1. 69 xx 10^(-19)`
` :. Z=3`.
2361.

A single electron system has ionisation energy `11180 KJ "mole"^(-1)`. The number of protons in the nucleus of the system is.......

Answer» Correct Answer - 6
`I.E. = (1312)/(n^(2)) xx Z^(2)`
2362.

The first five ionization energies of an element are `801,2428,3660,25030,32835 "in" "kJ"//"mol"`. Then the element could be.A. a halogenB. a noble gasC. a third group elementD. a second group element

Answer» Correct Answer - C
( c) Energy difference between `3rd` and `4 th IP`s is very high.
2363.

A single electron system has ionization energy 11180 kJ `mol^(-1)`. Find the number of protons in the nucleus of the system.

Answer» Correct Answer - Z=3
`IE=(Z^(2))/(n^(2))xx21.69xx10^(-19)J`
`(11180xx10^(3))/(6.023xx10^(23))=(Z^(2))/(1^(2))xx21.69xx10^(-19)`
`Z~~3`.
2364.

Binding energy per nucleon of three nuclei A, B and C are 5.5, 8.5 and 7.5 respectively. Which one of the following nuclei is most stable?A. AB. BC. CD. Cannot be predicted

Answer» Correct Answer - C
2365.

Which of the following set of quantum numbers is not possible for an electron in the ground state of an atom with atomic number `19`?A. n=2,l=0,m=0B. n=2,l=1,m=0C. n=3,l=1,m=-1D. n=3,l=2,m=`+-2`

Answer» Correct Answer - D
2366.

Helium nucleus is composed of two protons and two neutrons if the atomic mass is `4.00388`, how much energy is released when the nucleus is constituted? (Mass of proton =1.00757, mass of neturon=1.00893)A. 283MeVB. 28.3 mEvC. 2830 MeVD. 2.83 MeV

Answer» Correct Answer - B
2367.

Total number of electrons, protons and neutrons present in the nucleus of `._(92)U^(238) `isA. e=92,p=92,n=146B. e=92,p=92,n=148C. e=0,p=92,n=146D. None of these

Answer» Correct Answer - e=0,p=92,n=146
There is no electron in the nucleus.
`n_(e)=0,n_(p)=92,n_(n)=238-92=146`
2368.

An isotone of `._(32)^(76)Ge` is-(a) `._(32)^(77)Ge`(b)`._(33)^(77)As`(c)`._(34)^(77)Se`(d)`._(34)^(78)Se`A. `._(32)^(77)Ge`B. `._(33)^(78)As`C. `._(34)^(77)Se`D. `._(34)^(78)Se`

Answer» Correct Answer - D
2369.

Electron in a sample of `H-` atoms make transitions from state `n=x` to some lower excited state. The emission spectrum from the sample is found to contain only the lines belonging to a particular series. If one of the photons had an energy of `0.6375 eV`. Then find the value of `x. [" Take " 0.6375eV=(3)/(4)xx0.85eV]`.A. 16B. 24C. 8D. 20

Answer» Correct Answer - 3
We have, `" "DeltaE=(3)/(4)xx0.85eV`
as energy `=0.6375` the photon will belong to brakett series ( as for brackett `0.31 le E le0.85)`
`0.85xx(1-(1)/(4))=13.6((1)/(4^(2))-(1)/(n^(2)))`
`0.85(1-(1)/(4))=(13.5)/(16)[1-((4)/(n))^(2)]" ":. (4)/(n)=(1)/(2)" "rArr" "n=8`
2370.

What a certain was metal was irradiatiobn with light of frequency `1.6 xx 10^(16) Hz` the photoelectron emitted but the kinetic energy as the photoelectron emitted when the same metal was irradiation with light of frequency `1.0 xx 10^(16) Hz` .Calculate the threslold frequency `(v_(0))` for the metal

Answer» `hv = hv_(0) = KE`
`KE_(1) - h(v - v_(0))`
`KE_(2) = h(v_(2) - v_(0)) = (KE_(1))/(2)`
`:. (v_(2) - v_(v_(0)))/(v_(1) - v_(0)) = (1)/(2) rArr (1.0 xx 10^(16) - v_(0))/(1.6 xx 10^(16) - v_(0))m = (1)/(2)`
`rArr v_(0) = 4 xx 10^(15)Hz`
2371.

Gives the values of all the four quantum numbers for `2p` electron in nitrogen `(Z= 7)`

Answer» The electronic configuraqtion of nitrogen atom is `1s^(2)2s^(2)2p_(2)^(1) 2p_(1)^(2) 2p_(4)^(3)`
For the `2p` elementss `n= 2,l = 1, m = -1,o= 1, x = + 1//2 or -1//2`
(All `2p` electron have parallel spin )
2372.

The angular momentum of p electron isA. `sqrt(6). (h)/(2 pi)`B. `sqrt(3) (h)/(2 pi)`C. `sqrt((3)/(2)) (h)/(pi)`D. `(h)/(sqrt(4) pi)`

Answer» Correct Answer - D
(d) Orbital angular momentum `= sqrt(l(l + 1)) xx (h)/(2 pi)`
For `p-"electron" (l = 1)`
=`sqrt(1(l + 1)) xx (h)/(2 pi) = sqrt(2) xx (h)/(2 pi) = (h)/(sqrt(2) pi)`.
2373.

What is the maximum number of elements if the electrons above `n = 4` do not exist in nature ?A. 40B. 40C. 44D. 100

Answer» Since `n = 1,2,3, and 4`
`(1s)/(2),(2s 2p)/(8),(3s 3p 3d)/(18) ,(4s 4p 4d 4f)/(32)`
Thus total number of existent element is `2+8+18+32 = 60`
2374.

Minimum de-Broglie wavelength is associated with.A. ElectronB. ProtonC. `CO_2` moleculeD. `SO_2` molecule

Answer» Correct Answer - D
(d) `lamda = (h)/(mv)`. For same velocity `lamda prop (1)/(m)`.
`SO_2` molecule has least wavelength because their molecular mass is high.
2375.

The sub-shell `2d` is not posible becauseA. `n = 1`B. `l gt n`C. `n lt l`D. None of these

Answer» For sub-shell `2d, n = 2 and l = 2 ` and the value of n and l can never be equal
2376.

What is the maximum number of electron in the posible sub-shell for `n + 1 = 4` ?A. 8B. 6C. 12D. 16

Answer» `{:(n+l=4),(4+0=4s to 2),(3+1=3p to 6),(bar("Total 8")):}` Maximum number of electrons
2377.

if Helium atom and Hydrogen molecule are moving with the same velocity , their wavelength ratio will beA. `4:1`B. `1:2:`C. `2:1`D. `1:4`

Answer» Correct Answer - B
`lambdaprop1/m=lambda_"He"/lambda_(H_2) =m_(H_2)/m_(He) rArr lambda_(He)/lambda_(H_2)=2/4 =1:2`
2378.

Which of the following statement are correct ?A. The electronic configuration of Cr is `[Ar]3d^(5)4s^(1)`(atomic number of Cr is `24)`B. The magnetic quantum number may have a negative valueC. In silver atom `23` electron have spin of one type and `24` of the opposite type (atomic number of `Ag is 47)`D. The oxidation state of nitrogen in `HN_(3)` is `-3`

Answer» Correct Answer - A::B::C
`Cr(Z = 24)`
`[Ar]3d^(6)4s^(1)`
This is because `d^(5)` is a more half -filled configuration Reason for the stablity of half-filled and fallty filled ortained are symmetry and excharge energy
For every value of l m can be fromn -l to + l through 0, `Ag(z = 47)`
The oxidation state of N in `HN_(3)` is not `- 3`but `- 1//3`
2379.

The principal quantum number of an atom is related in theA. Size of the orbitB. Spin angular momentumC. orbital angular momentumD. Orientation of the orbital in space

Answer» Correct Answer - A
The principal quantum number (n) is related to the size to the orbital (n=1,2,3,…)
2380.

The principal quantum number of an atom is related in theA. Size of the orbitalB. Spin angular momentumC. Orbital angular momentumD. Orientation of the orbit in space

Answer» `{:(n + 1 = 7),(7 + 0 = 7s),(6 + 1 = 6p),(5 + 2 = 5d),(4 + 3 = 4f):}`
2381.

A dust particle has mass equal to `10^(-11)g` , diameter equal to `10^(-4)` cm and velocity equal to`10^(-4) cms^(-1)`. The error in the measurment of velocity is `0.1%` . Calculate the uncertiainty in its position. Comment on the result

Answer» ` u = 10 ^(-4) "cm sec"^(-1)`
` :. Delta u = ( 0. 1 xx 10^(-4))/(100) = 1xx 10^(-7) cm sec^(-1)`
Now ,` Delta u . Delta x = h/( 4 pi m)`
` :. Delta x = ( 6.626 xx 10^(-27))/( 4 xx 3. 14 xx 10^(-11) xx 10^(-7))`
`=0.527 xx 10^(-9)` cm
The uncertainty in position as compared to particle
` = (Deltax )/( diameter )`
` = ( 0. 527 xx 10^(-9))/( 10^4) = 0. 527 xx 10^(-5)`
The factor is very small and alost negligible for microscopic particels ,
2382.

Which electronic level would allow the hydrogen atom to absorbe a photon but not to emit a photon ?A. 3sB. 2pC. 2sD. 1s

Answer» Correct Answer - D
The lowest energy state is 1s it is not posible from this state to lost energy
2383.

The principal quantum number of an atom is related in theA. Size of the orbitalB. Spin angular momentumC. Orienitation of the orbital in spaceD. Orbital abgular momebntum

Answer» Correct Answer - A
The large the value of the principle quantum number, large the size of th eshell and hence the orbital
2384.

Point out the followings: (a) How many energy subshells are pssible in ` n=3` level ? (b) How many orbitals of all kinds are possible in ` n=3` level ?

Answer» (a) No. of subshells in a shell = no . Of shells = 3
(b) No. of orbitals = `( "no. of shell")^2 = 3^2 =9`.
2385.

Which of the following sets of quantum number is restrictedA. n=3, l=1, m=+2B. n=3, l=2, m=-2C. n=3, l=1, m=+1D. n=3, l=1, m=-1

Answer» Correct Answer - A
For n=3, l=1, m=-1,0,+1
2386.

For the n=2 energy level, how many orbitals of all kinds are possibleA. 2B. 3C. 4D. 5

Answer» Correct Answer - C
For the n=2, energy level orbitals of all kinds are possible `n^2 , 2^2 =4`
2387.

The velocity of an electron in the first Bohr orbit of hydrogen atom is `2.19 xx 10^(6)ms^(-1)`. Its velocity in the second orbit would beA. `1.10 xx 10^(6)ms^(-1)`B. `4.38 xx 10^(6)ms^(-1)`C. `5.5 xx 10^(5)ms^(-1)`D. `8.76 xx 10^(6)ms^(-1)`

Answer» Correct Answer - A
`v_(n) = (v_(1))/(n)`
2388.

Energy of electron moving in the second orbit of `He^(+)` ion isA. `-13.6ev`B. `-3.4ev`C. `-1.51 ev`D. `-0.84ev`

Answer» Correct Answer - A
`E = (-13.6)/(n^(2)) xx Z^(2)`
2389.

A dispositive ion `16` protons what is the number of el,ectron is its tertpositive ion?A. `16`B. `14`C. `12`D. `10`

Answer» `X^(2+)` has `16` protons then
in `X`, there are `16` protons and `16` electrons
in `X^(2+)`, there are `16` protons and `14` electrons
in `X^(4+)`, there are `16` protons and `12` electrons
2390.

Consider the following nuclear reactions involving X and Y. `X rarr Y + ._(2)^(4)He` `Y rarr ._(8)O^(18) + ._(1)H^(1)` If both neutrons as well as protons in both the sides are conversed in nuclear reaction then moles of neutrons in 4.6 g on X :A. `2.4 N_(A)`B. `2.4`C. `4.6`D. `0.2 N_(A)`

Answer» Correct Answer - B
2391.

Write the complete symbol a. The nucleus with atomic number `16` and mass number `82` b. The nucleus with atomic number `35` and mass number `80` c. The nucleus with atomic number `4` and mass number `9`

Answer» a.`._(16)X^(32)` or `._(16)S^(32)` b. `._(35)X^(80)` or `._(35)Br^(80)`c.`_(4)X^(9)` or `._(4)Be^(9)`
2392.

Consider the following nuclear reactions involving X and Y. `X rarr Y + ._(2)^(4)He` `Y rarr ._(8)O^(18) + ._(1)H^(1)` If both neutrons as well as protons in both the sides are conversed in nuclear reaction then moles of neutrons in 4.6 g on X :A. `3,2.4N_(A)`B. `3,2.4`C. `2,4.6`D. `3,0.2N_(A)`

Answer» Correct Answer - B
`E = (hc)/(lambda) implies (1240)/(lambda_(nm))ev " "E=(1240)/(31)implies 40 eV`
`40=12.8 +K.E.`
`K.E. = 10-12.8=27.2eV`
`K.E. = 27.2 xx1.6xx10^(-19)`
`27.2 xx1.6xx10^(-19)=(1)/(2)xx9.1xx10^(-31)xxv^(2)`
`v = 2.18 xx sqrt(2) xx 10^(6) m//s`
2393.

Energy of atomic orbitals in a particular shell is in the orderA. s lt p lt dlt fB. s gt p gt d gt fC. p lt d lt flt sD. f gt dgt s gt p

Answer» Correct Answer - A
In particular shell, the energy of atomic orbital increases with the value of l
2394.

The quantum numbers n=2, l=1 representA. 1s orbitalB. 2s orbitalC. 2p orbitalD. 3d orbital

Answer» Correct Answer - C
l=1 is for p orbital
2395.

Calculate ratio of wavelenght of limiting line of Blamer and pashcen series for an atom.

Answer» Correct Answer - `4//9`
2396.

If the atomic weight of `Zn` in `70` and its atomic number in `30`, Then what be the atomic weight of `Zn^(2+)`?

Answer» In the formation of `Zn^(2+)` from Zn ,two electrons are removed .The number of proton and neutrons remain unchanged hence , the atomic weight of `Zn^(2+)` will be `70`
2397.

Statement-1: K.E. of photoelectrons increases with increases in frequency of incident ligh `(VgtV_(0)).` Statement -2: Whenever intensity of light is increases the magnitude of photocurrent always increases.

Answer» Correct Answer - c
2398.

The mass numbers of three istopes of an element are `10,12 and 14` units .Their precentage abundance is `80,15 and 5` respectively .What is the atomic weight of the element ?

Answer» The precentage abundences of isotopes are `80,15, and 5` .This is `16:3:1`
Total of the ratio `= 16 + 3 + 1 = 20`
`"Average weight" = (% "abundance" xx" atomic weight")/("Total of ratio" )`
`"Average weight" = (10 xx 16 + 12 xx 3 + 14 xx 1)/(20) = 10.5`
Thus the average atomic weight is `10.5` unit.
2399.

Electronmagnetic radiations having `lambda=310Å`are subjected to a metal sheet having work function `=12.8eV`. What will be the velocity of photoelectrons with maximum Kinetic Energy….A. `0`, no emmision will occurB. `2.18xx10^(6)m//s`C. `2.18sqrt(2)xx10^(6)m//s`D. `8.72xx10^(6)m//s`

Answer» Correct Answer - C
Frequency `=(1)/(T) prop (v)/(T) prop (ƶ//n)/(n^(2)//ƶ)`
Frequency `=(1)/(T) prop (ƶ^(2))/(n^(3))" "Tprop(n^(3))/(ƶ^(2))=(1//4)/(8//1) =(1)/(32)`
2400.

The species which has its fifth ionization potential equal to 340 V is :A. `B^(+)`B. `C^(+)`C. `B `D. `C `

Answer» Correct Answer - C