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101.

In alkaline medium, glycine predominantly exists as/in a/an:

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In alkaline medium, glycine predominantly exists as/in a/an:



102.

Antifertity drug is

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Antifertity drug is



103.

Predict the pinacol-pinacolone rearrangement product of:

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Predict the pinacol-pinacolone rearrangement product of:


104.

The silicate anion given above in a mineral has K+,Ca2+ and Al3+ cations in 2:1:2. Number of moles of Al3+ ions per 4 moles of mineral is

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The silicate anion given above in a mineral has K+,Ca2+ and Al3+ cations in 2:1:2. Number of moles of Al3+ ions per 4 moles of mineral is
105.

By which reagent alkyne converts to cis-alkene?i.e. C6H11−C≡C−CH3R⟶cis-alkene:

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By which reagent alkyne converts to cis-alkene?

i.e. C6H11CCCH3Rcis-alkene:

106.

If Ka=1.8×10−5, calculate the degree of hydrolysis of 0.1 M solution of sodium acetate at 25∘C:

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If Ka=1.8×105, calculate the degree of hydrolysis of 0.1 M solution of sodium acetate at 25C:

107.

The product of the reaction sequence that follows is:

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The product of the reaction sequence that follows is:


108.

Which of the following is an example of condensation polymer?

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Which of the following is an example of condensation polymer?



109.

What volume of 6 M HCl and 2 M HCl should be mixed to get two litre of 3 M HCl?

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What volume of 6 M HCl and 2 M HCl should be mixed to get two litre of 3 M HCl?

110.

If we treat a solution of Sodium dichromate with KCl, the orange crystals that crystallize out is:

Answer» If we treat a solution of Sodium dichromate with KCl, the orange crystals that crystallize out is:
111.

What is the compressibility factor for H2 which behaves as a real gas?

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What is the compressibility factor for H2 which behaves as a real gas?



112.

Which one of the following statement(s) is incorrect about order of reaction?

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Which one of the following statement(s) is incorrect about order of reaction?



113.

Which of the following is/are correct for group 14 elements?

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Which of the following is/are correct for group 14 elements?



114.

Identify the wrong statements in the following

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Identify the wrong statements in the following



115.

In a F.C.C. arrangement of A and B atoms whose A atoms are at the corner of the unit cell and B atoms at the face centres. One of the A atom is missing from one corner in unit cell. The simplest formula of compound is

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In a F.C.C. arrangement of A and B atoms whose A atoms are at the corner of the unit cell and B atoms at the face centres. One of the A atom is missing from one corner in unit cell. The simplest formula of compound is



116.

What volume of 0.50 M CaCl2 solution is needed to prepare 250 mL of solution that has a chloride concentration of 0.100 M?

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What volume of 0.50 M CaCl2 solution is needed to prepare 250 mL of solution that has a chloride concentration of 0.100 M?

117.

Which of the following sequences represents the increasing order of the polarizing power of the cationic species?

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Which of the following sequences represents the increasing order of the polarizing power of the cationic species?

118.

Which of the following are homocyclic aromatic compounds?

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Which of the following are homocyclic aromatic compounds?

119.

In the following, the most stable conformation of n-butane is:

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In the following, the most stable conformation of n-butane is:

120.

One mole of an ideal monoatomic gas expands reversibly and adiabatically from a volume of x litre to 14 litre at 27∘ C. Then the value of x will be:[Final temperature =189 K and Cv=32 R ]

Answer» One mole of an ideal monoatomic gas expands reversibly and adiabatically from a volume of x litre to 14 litre at 27 C. Then the value of x will be:[Final temperature =189 K and Cv=32 R ]


121.

The correct sequence of reagents for the following conversion will be:

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The correct sequence of reagents for the following conversion will be:


122.

Let, the average molar mass of air is 24.9 g. An open vessel at 27 oC is heated upto t oC until 1/3rd of the air measured at final temperature excapes out. The rms velocity of air molecules at t oC is: (Take R=8.3 JK−1mol−1)

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Let, the average molar mass of air is 24.9 g. An open vessel at 27 oC is heated upto t oC until 1/3rd of the air measured at final temperature excapes out. The rms velocity of air molecules at t oC is: (Take R=8.3 JK1mol1)

123.

The solubility product of a salt having general formula MX2, in water is 4×10−12. The concentration (mol L−1) of M2+ ions in the aqueous solution of the salt is:

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The solubility product of a salt having general formula MX2, in water is 4×1012. The concentration (mol L1) of M2+ ions in the aqueous solution of the salt is:

124.

The pressure of H2 required to make the potential of H2 electrode zero in pure water at 298 K is

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The pressure of H2 required to make the potential of H2 electrode zero in pure water at 298 K is

125.

Gauche Conformation of butane is:

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Gauche Conformation of butane is:



126.

The B—F bond length is the shortest in which of the following species?

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The BF bond length is the shortest in which of the following species?

127.

Cracking of Ethane gives a mixture of

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Cracking of Ethane gives a mixture of



128.

The correct order regarding the electronegativity of hybrid orbitals of carbon is?

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The correct order regarding the electronegativity of hybrid orbitals of carbon is?



129.

Incorrect order of stability is:

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Incorrect order of stability is:

130.

What is the chemical composition of 'slag' formed during smelting in the extraction of copper?

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What is the chemical composition of 'slag' formed during smelting in the extraction of copper?

131.

On heating strongly, Lead (II) nitrate yields:

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On heating strongly, Lead (II) nitrate yields:



132.

The cell reaction for the given cell is spontaneous if Pt,Cl2(P1)(g)|Cl−(1.0M)||Cl−(2M)|Cl2(P2)(g),Pt

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The cell reaction for the given cell is spontaneous if Pt,Cl2(P1)(g)|Cl(1.0M)||Cl(2M)|Cl2(P2)(g),Pt

133.

Compounds A, B and C, respectively are:

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Compounds A, B and C, respectively are:
134.

How many layers are adsorbed in chemical adsorption?

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How many layers are adsorbed in chemical adsorption?



135.

Consider the following reaction and choose the possible product(s):

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Consider the following reaction and choose the possible product(s):




136.

The second order Bragg diffraction of X-rays with l =1.0 A0 froma set of parallel planes in a metal occurs at an angle of 600.The distance between the scattering planes in the crystal is

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The second order Bragg diffraction of X-rays with l =1.0 A0 froma set of parallel planes in a metal occurs at an angle of 600.The distance between the scattering planes in the crystal is



137.

2 moles of acetaldehyde are catalyzed by aluminium ethoxide to yield one mole of ethyl acetate. This is:

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2 moles of acetaldehyde are catalyzed by aluminium ethoxide to yield one mole of ethyl acetate. This is:



138.

Two glass bulbs A and B are connected by a very small tube of negligible volume having a stop cock. Volume of bulb A is 100 cm3 and it contains some gas. Bulb B is empty on opening the stop cock, the pressure dropped by 60%. The volume of Bulb B must be____.

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Two glass bulbs A and B are connected by a very small tube of negligible volume having a stop cock. Volume of bulb A is 100 cm3 and it contains some gas. Bulb B is empty on opening the stop cock, the pressure dropped by 60%. The volume of Bulb B must be____.



139.

Colour of dipositive Lanthanum (II) cation is due to:

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Colour of dipositive Lanthanum (II) cation is due to:

140.

The electronic configuration of a dipositive metal M2+ is 2, 8, 14 and its atomic weight is 56 a.m.u. The number of neutrons in its nuclei would be

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The electronic configuration of a dipositive metal M2+ is 2, 8, 14 and its atomic weight is 56 a.m.u. The number of neutrons in its nuclei would be



141.

0.02 M solution of H2A has pH=4. If Ka1 for the acid is 5×10−7 M, the concentration of HA− ion in the solution would be :

Answer» 0.02 M solution of H2A has pH=4. If Ka1 for the acid is 5×107 M, the concentration of HA ion in the solution would be :
142.

The radii of F,F−,O and O2− are in the order of

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The radii of F,F,O and O2 are in the order of



143.

The correct order of increasing C−O bond length in CO,CO2−3,CO2 and CO+ is:

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The correct order of increasing CO bond length in CO,CO23,CO2 and CO+ is:

144.

A solution of sodium sulphate in water is electrolysed using inert electrodes. The products at the cathode and anode are respectively(IIT-JEE, 1987)

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A solution of sodium sulphate in water is electrolysed using inert electrodes. The products at the cathode and anode are respectively

(IIT-JEE, 1987)

145.

Match the polymers given in Column I with the preferred mode of polymerisation followed by their monomers.Column IColumn II(i) Nylon-6(a) free radical polymerisation(ii) PVC(b) Ziegler-Natta plymerisation or coordination polymerisation(iii) HDP(c) Anionic polymerisation(d) Condensation polymerisation

Answer»

Match the polymers given in Column I with the preferred mode of polymerisation followed by their monomers.

Column IColumn II(i) Nylon-6(a) free radical polymerisation(ii) PVC(b) Ziegler-Natta plymerisation or coordination polymerisation(iii) HDP(c) Anionic polymerisation(d) Condensation polymerisation



146.

In which of the following coordination entities, the magnitude of Δ∘ [CFSE in octahedral field] will be maximum?

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In which of the following coordination entities, the magnitude of Δ [CFSE in octahedral field] will be maximum?



147.

Nitric acid is the most important oxi-acid formed by nitrogen. It is one of the major industrial chemicals and is widely used. Nitric acid is manufactured by the catalytic oxidation of ammonia that is known as Ostwald Process which can be represented by sequence of reactions shown below4NH3+5O2(g)Catalyst−−−−−→Pt/Rh4NO(g)+6H2O(g) ...(i)2NO(g)+O2(g)1120 K−−−−→2NO2(g) ...(ii) 3NO2(g)+H2O(l)→2HNO3(aq)+NO(g) ...(iii)The aqueous nitric acid obtained by this method can be concenteated by distillation to 68.5% by weight. Further concentration to 98% acid can be achieved by dehydration with concentrated sulphuric acid.If 180 L of water completely reacts with NO2 produced to form nitric acid according to the above reactions, then the volume of air required at STP containing 20% of NO2 is:(density of water is 1 g/mL)

Answer»

Nitric acid is the most important oxi-acid formed by nitrogen. It is one of the major industrial chemicals and is widely used. Nitric acid is manufactured by the catalytic oxidation of ammonia that is known as Ostwald Process which can be represented by sequence of reactions shown below

4NH3+5O2(g)Catalyst−−−−Pt/Rh4NO(g)+6H2O(g) ...(i)

2NO(g)+O2(g)1120 K−−−2NO2(g) ...(ii)

3NO2(g)+H2O(l)2HNO3(aq)+NO(g) ...(iii)

The aqueous nitric acid obtained by this method can be concenteated by distillation to 68.5% by weight. Further concentration to 98% acid can be achieved by dehydration with concentrated sulphuric acid.



If 180 L of water completely reacts with NO2 produced to form nitric acid according to the above reactions, then the volume of air required at STP containing 20% of NO2 is:

(density of water is 1 g/mL)

148.

Which of the following is not an antibiotic

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Which of the following is not an antibiotic

149.

In a kingdom there was an excellent archer. The ruler was jealous of his archery skills, so he decided to put his skills to test. The archer was asked to shoot an apple which was placed on his son's head or else his son will be killed. The archer always used his trusted bow.Case 1: In practice shots he always hits the apple. In this case the archer is:

Answer»

In a kingdom there was an excellent archer. The ruler was jealous of his archery skills, so he decided to put his skills to test. The archer was asked to shoot an apple which was placed on his son's head or else his son will be killed. The archer always used his trusted bow.


Case 1: In practice shots he always hits the apple. In this case the archer is:



150.

Which compound would give 5-keto-2-methyl hexanal upon ozonolysis?

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Which compound would give 5-keto-2-methyl hexanal upon ozonolysis?