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451.

Which of the following represents Claisen - Schmidt reaction

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Which of the following represents Claisen - Schmidt reaction



452.

Select the correct curve(s).If v = velocity of electron in Bohr's orbitr = Radius of electron n Bohr's orbitP.E = Potential energy of electron in Bohr's orbitK.E = Kinetic energy of electron in Bohr's orbit

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Select the correct curve(s).

If v = velocity of electron in Bohr's orbit

r = Radius of electron n Bohr's orbit

P.E = Potential energy of electron in Bohr's orbit

K.E = Kinetic energy of electron in Bohr's orbit

453.

Ethanol and dimethyl ether are examples of:

Answer»

Ethanol and dimethyl ether are examples of:



454.

Primary and secondary valency of Pt in [Pt(en)2Cl2] are

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Primary and secondary valency of Pt in [Pt(en)2Cl2] are



455.

Which is the strongest base that can exist in water?

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Which is the strongest base that can exist in water?

456.

Benzyl bromide, on treatment with a nucleophile - triphenylphosphine, is then made to react with b-Butyl lithium - a strong base to give a yhosphorus ylid.Which of the following would yield the hydrocarbon:

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Benzyl bromide, on treatment with a nucleophile - triphenylphosphine, is then made to react with b-Butyl lithium - a strong base to give a yhosphorus ylid.

Which of the following would yield the hydrocarbon:



457.

Alkynes could be synthesized by:

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Alkynes could be synthesized by:



458.

An inorganic compound (A) is made of two most occuring elements in the Earth's crust and has a polymeric tetrahedral network structure. With carbon, compound (A) produces a poisonous gas (B) which is the most stable diatomic molecule. Compounds (A) and (B) will be

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An inorganic compound (A) is made of two most occuring elements in the Earth's crust and has a polymeric tetrahedral network structure. With carbon, compound (A) produces a poisonous gas (B) which is the most stable diatomic molecule. Compounds (A) and (B) will be



459.

The ratio of number of atoms present in a simple cubic, body centered cubic and face centered cubic structure, respectively, are :

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The ratio of number of atoms present in a simple cubic, body centered cubic and face centered cubic structure, respectively, are :


460.

Which of the following is the Fischer projection of L – threonine (also known as 2S, 3R-2-amino- 3-hydroxy butanoic acid)?

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Which of the following is the Fischer projection of L – threonine (also known as 2S, 3R-2-amino- 3-hydroxy butanoic acid)?

461.

Which of the following is the weakest acid, in the following compounds?

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Which of the following is the weakest acid, in the following compounds?

462.

Inversion of sucrose (C12H22O11) is a first order reaction and is studied by measuring angle of rotation at different intervals of time C12H22O11d-Sucrose+H2O H+−−→C6H12O6d -Glucose+C6H12O6l -Fructoser0 = angle of rotation at the start, rt = angle of rotation at time ti, and r∞ = angle of rotation at the complete reaction, if 50% of sucrose undergoes inversion, then

Answer»

Inversion of sucrose (C12H22O11) is a first order reaction and is studied by measuring angle of rotation at different intervals of time C12H22O11d-Sucrose+H2O H+C6H12O6d -Glucose+C6H12O6l -Fructose

r0 = angle of rotation at the start, rt = angle of rotation at time ti, and r = angle of rotation at the complete reaction, if 50% of sucrose undergoes inversion, then

463.

Mark the oxide which is amphoteric in character

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Mark the oxide which is amphoteric in character

464.

Which of the following free radical is most stable?

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Which of the following free radical is most stable?

465.

For the reaction CO(g)+12O2(g)→CO2(g),ΔH and ΔS are −283 kJ and −87 J K−1 mol−1 respectively. It was intended to carry out this reaction at 1000,1500,3000 and 3500 K. At which of these temperatures would this reaction be thermodynamically spontaneous?

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For the reaction CO(g)+12O2(g)CO2(g),ΔH and ΔS are 283 kJ and 87 J K1 mol1 respectively. It was intended to carry out this reaction at 1000,1500,3000 and 3500 K. At which of these temperatures would this reaction be thermodynamically spontaneous?

466.

Melting point is maximum for:

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Melting point is maximum for:




467.

A mineral consists of an equimolar mixture of the carbonates of two bivalent metals. One metal is present to the extent of 12.5 by weight. 2.8 g of the mineral on heating lost 1.32 g of CO2. What is the % by weight of the other metal?

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A mineral consists of an equimolar mixture of the carbonates of two bivalent metals. One metal is present to the extent of 12.5 by weight. 2.8 g of the mineral on heating lost 1.32 g of CO2. What is the % by weight of the other metal?

468.

An atom with high electron affinity generally has

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An atom with high electron affinity generally has



469.

The number of tripeptides formed by 3 different amino acids is:

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The number of tripeptides formed by 3 different amino acids is:



470.

When water is cooled to ice, its entropy

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When water is cooled to ice, its entropy



471.

A green ball weighs 80 g and comes travelling towards you at 900 m/s. A photon of light emitted from green ball has a wavelength of 6×10−7 m. Assuming that the error in the position of ball is the same as the wavelength of its photon, calculate error in the momentum (kgm/s) of the green ball.

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A green ball weighs 80 g and comes travelling towards you at 900 m/s. A photon of light emitted from green ball has a wavelength of 6×107 m. Assuming that the error in the position of ball is the same as the wavelength of its photon, calculate error in the momentum (kgm/s) of the green ball.



472.

The complex ion that has the minimum wavelength of absorption in the visible region is:

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The complex ion that has the minimum wavelength of absorption in the visible region is:

473.

The prefix and suffix used for -OH are respectively

Answer»

The prefix and suffix used for -OH are respectively



474.

The radial wave function for an orbital in a hydrogen atom is:ψ=116√3(1a0)32[(x−1)(x2−8x+12)]e−x2where, x=2ra0; a0= radius of first Bohr's orbit. The minimum and maximum position of radial nodes from the nucleus are:

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The radial wave function for an orbital in a hydrogen atom is:

ψ=1163(1a0)32[(x1)(x28x+12)]ex2

where, x=2ra0; a0= radius of first Bohr's orbit. The minimum and maximum position of radial nodes from the nucleus are:

475.

Which of the following sequence converts benzaldehyde into phenylacetaldehyde?1: PBr32: Mg in THF3: NaBH4 followed by H3O+4: HCHO followed by H3O+5: PCC

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Which of the following sequence converts benzaldehyde into phenylacetaldehyde?



1: PBr3

2: Mg in THF

3: NaBH4 followed by H3O+

4: HCHO followed by H3O+

5: PCC



476.

From the following which is the least conducting in solution

Answer» From the following which is the least conducting in solution
477.

Electron gain enthalpy depends on:

Answer»

Electron gain enthalpy depends on:



478.

What is the hybridization of Xe in the product formed on reaction of XeF4 with SbF5?SbF5 के साथ XeF4 की अभिक्रिया पर बने उत्पाद में Xe का संकरण क्या है?

Answer»

What is the hybridization of Xe in the product formed on reaction of XeF4 with SbF5?



SbF5 के साथ XeF4 की अभिक्रिया पर बने उत्पाद में Xe का संकरण क्या है?

479.

The average osmotic pressure of human blood is 7.8 bar at 370C. What is the concentration of an aqueous NaCl solution that could be used in the blood stream

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The average osmotic pressure of human blood is 7.8 bar at 370C. What is the concentration of an aqueous NaCl solution that could be used in the blood stream



480.

A sample of chloroform before being used as an anaesthetic agent is tested by

Answer»

A sample of chloroform before being used as an anaesthetic agent is tested by



481.

The correct statement(s) for orthoboric acid is(are)

Answer»

The correct statement(s) for orthoboric acid is(are)



482.

Calculate the solubility of A2X3 in pure water, assuming that neither kind of ion reacts with water. The solubility product of A2X3, Ksp=1.1×10−23.

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Calculate the solubility of A2X3 in pure water, assuming that neither kind of ion reacts with water. The solubility product of A2X3, Ksp=1.1×1023.

483.

The degree of hydrolysis and pH of 0.1 M sodium acetate solution are:Hydrolysis constant of sodium acetate is 5.6 × 10−10.

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The degree of hydrolysis and pH of 0.1 M sodium acetate solution are:

Hydrolysis constant of sodium acetate is 5.6 × 1010.



484.

A 0.6% solution of urea (molar mass = 60) would be isotonic with

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A 0.6% solution of urea (molar mass = 60) would be isotonic with



485.

Which one of the following is not a member of 3d-transition series?

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Which one of the following is not a member of 3d-transition series?



486.

In a living organism, the C-14 concentration

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In a living organism, the C-14 concentration



487.

Which of the following behaves as both oxidising and reducing agents

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Which of the following behaves as both oxidising and reducing agents


488.

The order of the oxidation state of the phosphorous atom in H3PO2,H3PO4,H3PO3 and H4P2O6 is:

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The order of the oxidation state of the phosphorous atom in H3PO2,H3PO4,H3PO3 and H4P2O6 is:

489.

The following reaction is performed at 298K2NO(g)+O2(g)⇌2NO2(g)The standard free energy of formation of NO(g) is 86.6kJ/mol at 298K. What is the standard free energy of formation of NO2(g) at 298 K? Kp=1.6×1012

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The following reaction is performed at 298K

2NO(g)+O2(g)2NO2(g)

The standard free energy of formation of NO(g) is 86.6kJ/mol at 298K. What is the standard free energy of formation of NO2(g) at 298 K? Kp=1.6×1012

490.

The spin magnetic momentum of electrons in an ion is 4.84 BM. Its total electronic spin will be

Answer»

The spin magnetic momentum of electrons in an ion is 4.84 BM. Its total electronic spin will be



491.

Then the formula of C3H9N is

Answer»


Then the formula of C3H9N is



492.

\(N_2 ~+ ~O_2 ~\rightleftharpoons~ 2NO ~+~ (-Q cals)\)In the above reaction which is the essential condition for the higher production of NO

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\(N_2 ~+ ~O_2 ~\rightleftharpoons~ 2NO ~+~ (-Q cals)\)


In the above reaction which is the essential condition for the higher production of NO



493.

Hybridisation of carbon atom in CO2−3 is

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Hybridisation of carbon atom in CO23 is



494.

A pure sample of N2O5 gas contains 0.01 moles. Find the volume occupied by the gas sample at standard temperature and pressure conditions (STP).

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A pure sample of N2O5 gas contains 0.01 moles. Find the volume occupied by the gas sample at standard temperature and pressure conditions (STP).

495.

While denoting an organic compound in the form , which type of representation is used?

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While denoting an organic compound in the form , which type of representation is used?



496.

The average velocity of a gas is 400 ms−1.Find the rms velocity of the gas.

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The average velocity of a gas is 400 ms1.Find the rms velocity of the gas.



497.

How many C-atoms are present in 2.6 micromoles of C6H12O6?

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How many C-atoms are present in 2.6 micromoles of C6H12O6?

498.

The reaction between ethylene and bromine is an example of:

Answer»

The reaction between ethylene and bromine is an example of:



499.

Diethylether may be regarded as an anhydride of:

Answer»

Diethylether may be regarded as an anhydride of:



500.

During the process of electrolytic refining of copper, some metals present as impurity settle as anode mud. These are-

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During the process of electrolytic refining of copper, some metals present as impurity settle as anode mud. These are-