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1851.

Po(A) = 60 mm of Hg and Po(B) = 45mm of Hg. If 1 mol of A and 2 mol of B are mixed, the solution forms an azeotropic mixture with a minimum boiling point, then mole fraction of A in its vapour phase above the solution will be

Answer» Po(A) = 60 mm of Hg and Po(B) = 45mm of Hg. If 1 mol of A and 2 mol of B are mixed, the solution forms an azeotropic mixture with a minimum boiling point, then mole fraction of A in its vapour phase above the solution will be
1852.

How many oxygen atoms are present in 2 gram-atoms of O?

Answer»

How many oxygen atoms are present in 2 gram-atoms of O?

1853.

100 ml mixture of Co and CO2 is mixed with 30 ml of oxygen and sparked in a eudiometer tube. The residual gas after treatment with aqueous KOH has a volume of 10 ml which remains unchanged when treated with alkaline pyrogallol. If all the volumes are under the same conditions, point out the correct option(s).

Answer»

100 ml mixture of Co and CO2 is mixed with 30 ml of oxygen and sparked in a eudiometer tube. The residual gas after treatment with aqueous KOH has a volume of 10 ml which remains unchanged when treated with alkaline pyrogallol. If all the volumes are under the same conditions, point out the correct option(s).



1854.

An acidified solution of KMnO4 oxidizes

Answer» An acidified solution of KMnO4 oxidizes
1855.

Pressure cooker reduces cooking time for food because:

Answer»

Pressure cooker reduces cooking time for food because:



1856.

The reciprocal of compressibility factor of a real gas in the critical state is ?

Answer»

The reciprocal of compressibility factor of a real gas in the critical state is ?



1857.

Which of the following is/are ambident nucleophiles?

Answer»

Which of the following is/are ambident nucleophiles?



1858.

A gaseous mixture containing CO, CH4 and N2 gas has total volume of 40 mL. This mixture is exploded with excess of oxygen, on cooling 30 mL of contraction is observed and when this mixture is treated with aqueous KOH a further contraction of 30 mL is observed. Find the composition of the mixture in mL.

Answer»

A gaseous mixture containing CO, CH4 and N2 gas has total volume of 40 mL. This mixture is exploded with excess of oxygen, on cooling 30 mL of contraction is observed and when this mixture is treated with aqueous KOH a further contraction of 30 mL is observed. Find the composition of the mixture in mL.

1859.

The fraction of total molecules which is ionised in a solution of an electrolyte is known as

Answer»

The fraction of total molecules which is ionised in a solution of an electrolyte is known as



1860.

Which of the following pair of metals is purified by van Arkel method?

Answer»

Which of the following pair of metals is purified by van Arkel method?



1861.

Which of the following compounds will evolve hydrogen on treatment with metal

Answer» Which of the following compounds will evolve hydrogen on treatment with metal


1862.

ZnSO4.7H2OAbove 39∘C−−−−−−−→Below 70∘CAAbove 70∘C−−−−−−−→BAbove 280∘C−−−−−−−→O2+SO2+ZnO. A and B respectively are:

Answer» ZnSO4.7H2OAbove 39C−−−−−−Below 70CAAbove 70C−−−−−−BAbove 280C−−−−−−O2+SO2+ZnO. A and B respectively are:


1863.

Which of the following sets has all the species that do not follow octet rule?

Answer»

Which of the following sets has all the species that do not follow octet rule?

1864.

Alkene R−C−H=CH2 reacts readily with B2H6 and the product on oxidation with alkaline hydrogen peroxides produces

Answer» Alkene RCH=CH2 reacts readily with B2H6 and the product on oxidation with alkaline hydrogen peroxides produces
1865.

The work done by 2 mole of an ideal gas at 300 K in a reversible isothermal expansion from 10 litres to 20 litres is

Answer»

The work done by 2 mole of an ideal gas at 300 K in a reversible isothermal expansion from 10 litres to 20 litres is

1866.

When strongly heated, Sodium thiosulphate disproportionates into compounds having ___ different oxidation states.

Answer»

When strongly heated, Sodium thiosulphate disproportionates into compounds having ___ different oxidation states.


1867.

The yellow colored solution of chromate salt changes to orange colour on acidification due to the formation of

Answer» The yellow colored solution of chromate salt changes to orange colour on acidification due to the formation of
1868.

Which will show maximum non-metallic character?

Answer»

Which will show maximum non-metallic character?




1869.

For the reaction, at 1000oCCaCO3(s)⇌CaO(s)+CO2(g)△Go=−24 kJ mol−1,pCO2=0.0030 atmHence, △G at this temperature is :

Answer»

For the reaction, at 1000oC

CaCO3(s)CaO(s)+CO2(g)

Go=24 kJ mol1,pCO2=0.0030 atm

Hence, G at this temperature is :

1870.

Half life of a first-order reaction is 1386 seconds. The specific rate constant of the reaction is :

Answer»

Half life of a first-order reaction is 1386 seconds. The specific rate constant of the reaction is :

1871.

Which one is strongest acid

Answer» Which one is strongest acid


1872.

Propionic acid is subjected to reduction with hydroiodic acid in the presence of a little P, the product formed is

Answer»

Propionic acid is subjected to reduction with hydroiodic acid in the presence of a little P, the product formed is



1873.

Which of the following orders regarding relative stability of free radicals is correct?

Answer»

Which of the following orders regarding relative stability of free radicals is correct?



1874.

The oxidation numbers of C - 1 and C - 2 in propene CH32CH=1CH2 are respectively

Answer»

The oxidation numbers of C - 1 and C - 2 in propene CH32CH=1CH2 are respectively



1875.

A crystallizes in HCP close packing and B occupied 12 of octahedral voids.Calculate the formula of the compound?What if 2 ions of A are removed from the corner of each unit cell?What is the new crystal formula?

Answer»

A crystallizes in HCP close packing and B occupied 12 of octahedral voids.


Calculate the formula of the compound?


What if 2 ions of A are removed from the corner of each unit cell?


What is the new crystal formula?



1876.

Which of the following compounds will not react with methyl magnesium bromide?

Answer»

Which of the following compounds will not react with methyl magnesium bromide?



1877.

Be2+ is isoelectronic with which of the following ions?

Answer» Be2+ is isoelectronic with which of the following ions?
1878.

Structure of A can be:

Answer» Structure of A can be:
1879.

If λ0 and λ be the threshold wavelength and the wavelength of incident light, the velocity of photo-electrons ejected from metal surface is:

Answer»

If λ0 and λ be the threshold wavelength and the wavelength of incident light, the velocity of photo-electrons ejected from metal surface is:

1880.

Which one of the following can be used as a monomer in a polymerization reaction?

Answer»

Which one of the following can be used as a monomer in a polymerization reaction?



1881.

Equal volumes of two gases A and B diffuse through a porous pot in 20s and 10s, respectively .If the molar mass of A be 80gmol−1,Find the molar mass of B.

Answer»

Equal volumes of two gases A and B diffuse through a porous pot in 20s and 10s, respectively .If the molar mass of A be 80gmol1,Find the molar mass of B.



1882.

If Pt is used as catalyst in the decomposition of H2O2, then it is an example of

Answer»

If Pt is used as catalyst in the decomposition of H2O2, then it is an example of



1883.

What is the general formula for oxide of element M with atomic number 87?

Answer»

What is the general formula for oxide of element M with atomic number 87?

1884.

Which of the following is/are TRUE about electromeric effect ?

Answer»

Which of the following is/are TRUE about electromeric effect ?



1885.

SCN is

Answer» SCN is
1886.

The vapour density of a mixture containing NO2 and N2O4 is 27.6. Mole fraction of NO2 in the mixture is:

Answer»

The vapour density of a mixture containing NO2 and N2O4 is 27.6. Mole fraction of NO2 in the mixture is:



1887.

A piece of wood was burned and 7.32 g of CO2 was collected. The total radioactivity in CO2 was 7.6 dpm. How old was the wood sample ? Given t12 of C - 14 = 5730 years, specific activity of carbon obtained from a fresh wood sample is 15.2 dpm.

Answer»

A piece of wood was burned and 7.32 g of CO2 was collected. The total radioactivity in CO2 was 7.6 dpm. How old was the wood sample ? Given t12 of C - 14 = 5730 years, specific activity of carbon obtained from a fresh wood sample is 15.2 dpm.



1888.

What is the minimum possible atomic number of the element containing four electrons in the ground state with magnetic quantum number ml=+1 ?

Answer»

What is the minimum possible atomic number of the element containing four electrons in the ground state with magnetic quantum number ml=+1 ?

1889.

C(s)+O2(g)→CO2(g), ΔrH=−94.3 kcal/molCO(g)+12O2(g)→CO2(g), ΔrH=−67.4kcal/molO2(g)→2O(g), ΔrH=117.4Kcal/molCO(g)→C(g)+O(g), ΔrH=230.6Kcal/molCalculate: ΔrH for C(s)→C(g) in Kcal/mol

Answer»

C(s)+O2(g)CO2(g), ΔrH=94.3 kcal/mol


CO(g)+12O2(g)CO2(g), ΔrH=67.4kcal/mol


O2(g)2O(g), ΔrH=117.4Kcal/mol


CO(g)C(g)+O(g), ΔrH=230.6Kcal/mol


Calculate: ΔrH for C(s)C(g) in Kcal/mol





1890.

Which of the following does not react with sodium bisulphite ?

Answer»

Which of the following does not react with sodium bisulphite ?



1891.

The volume (in mL) of 0.1 M AgNO3 required for the complete precipitation of chloride ions present in 30 mL of 0.01 M solution of [Cr(H2O)5Cl]Cl2, as silver chloride is close to:

Answer»

The volume (in mL) of 0.1 M AgNO3 required for the complete precipitation of chloride ions present in 30 mL of 0.01 M solution of [Cr(H2O)5Cl]Cl2, as silver chloride is close to:

1892.

An ideal solution is that which:

Answer»

An ideal solution is that which:



1893.

The normality of a solution of sulphuric acid is 0.1 N. Its molarity will be:

Answer»

The normality of a solution of sulphuric acid is 0.1 N. Its molarity will be:



1894.

Equilibrium constant of a reversible reaction:

Answer» Equilibrium constant of a reversible reaction:
1895.

Oxygen gas weighing 64 g is expanded from 1 atm to 0.1 atm at 30 oC. Calculate entropy change, assuming the gas to be ideal

Answer»

Oxygen gas weighing 64 g is expanded from 1 atm to 0.1 atm at 30 oC. Calculate entropy change, assuming the gas to be ideal

1896.

A black compound ‘A’ in its solid state is fused with KOH and KClO3. The aqueous extract of the fused mass is a green coloured solution ‘B’. On passing CO2 gas through it, pink colour of ‘C’ is noticed along with some black insoluble mass of ‘A’. The pink coloured solution is decolourised by Fe2+ in acidic medium. The oxidation state of the central metal in ‘C’ is?

Answer»

A black compound ‘A’ in its solid state is fused with KOH and KClO3. The aqueous extract of the fused mass is a green coloured solution ‘B’. On passing CO2 gas through it, pink colour of ‘C’ is noticed along with some black insoluble mass of ‘A’. The pink coloured solution is decolourised by Fe2+ in acidic medium. The oxidation state of the central metal in ‘C’ is?

1897.

Correct statements regarding 'D' is

Answer»

Correct statements regarding 'D' is



1898.

The correct order for the acidic character of the following carboxylic acid is ?

Answer»

The correct order for the acidic character of the following carboxylic acid is ?



1899.

Which of the following compound has the highest dipole moment?

Answer»

Which of the following compound has the highest dipole moment?

1900.

In the purification of NaCl, an impure solution is saturated with HCl gas. The principle involved is:

Answer»

In the purification of NaCl, an impure solution is saturated with HCl gas. The principle involved is: