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6651.

When chloroform is treated with amine and KOH, we get

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ROSE LIKE odor.
bitter ALMOND like smell
offensive odor.
sour oil of winter green like smell

Answer :C
6652.

Which of the following reaction take place at a faster rate

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`2Na_((s))+I_(2(s))rarr2NaI_((s))`
`2Na_((s))+I_(2(g))rarr2NaI_((s))`
`PbNO_3(s)+KI_((s))rarrPbI_((s))+KNO_3`
`underset("MARBLE")(CaCO_3)+OVERSET(dil)(HCl)rarrCaCl_2+H_2O+CO_2uarr`

Answer :B
6653.

What is the effect of catalyst on activation energy?

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SOLUTION :Catalyst lowers down the activation energy .Because it PROVIDES altemate PATH to the REACTION .It forms unstable intermediate which readily CHANGES into products.
6654.

Which statements are correct regarding copper sulphate?

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It reacts with `NAOH` and GLUCOSE to give `Cu_(2)O`
It reacts with KCl to give `Cu_(2)O`
It gives CuO on heating in air
It reacts with KI to give brown colouration

Answer :A::C::D
6655.

Which of the following is correct match?

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A-i-II
B-iv-I
C-iii-I
D-ii-I

Answer :B
6656.

Which is the correct order of boiling point of halomethane ?

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`CH_(3)F gt CH_(3)Cl gt CH_(3)Br gt CH_(3)I`
`CH_(3)Br gt CH_(3)I gt CH_(3)Cl gt CH_(3)F`
`CH_(3)I gt CH_(3)Br gt CH_(3)Cl gt CH_(3)F`
`CH_(3)F gt CH_(3)Br gt CH_(3)I gt CH_(3)Cl`

Solution :When the MASS and volume of the HALOGEN ATOM increases, then there will be an increase in repulsion FORCES of van der Waals.
6657.

Which of the following indicates to 'regions of ordered structure within a protein'.

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PRIMARY structure
Secondary structure
Tertiary structure
Quaternary structure

Answer :B
6658.

What is the action of concentrated nitric acid on copper? Give equation.

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Solution :Copper REACTS with concentrated `HNO_3`, reddish brown vapours of NITROGEN DIOXIDE is PRODUCED.
6659.

Total charge on 1 mole of a monovalent metal ion is equal to

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`9.65xx10^(4)` coulomb
`6.28xx10^(18)` coulomb
`1.6xx10^(-19)` coulomb
None of these

Solution :One MOLE of monovalent metal ION means charge of N ELECTRON i.e., 96500 C or 1 faraday.
6660.

When 1000 ml of a 1M solution of sulphuric acid is neutralised by a strong base in dilute solution, the standard enthalpy of neutralisation is

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`-57.1 KJ`
`-114.2 kJ`
`-28.55 kJ`
`+57.1 kJ`

Solution :1 M solution of `H_(2)SO_(4)` GIVES 2 equivalents of `H^(+)` IONS.
6661.

To what extent do the electronic configurations decided the stability of oxidation states in the first series of the transition elements?

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SOLUTION :If an element has `d^(0), d^(5) or d^(10)` configuration in a PARTICULAR oxidation state, then they are STABLE EX:
(i) `Sc^(3+)` is stable because of `d^(0)` configuration. It is more stable than `Sc^(+)`.
(II) `V^(5+)` is more stable than `V^(3+)` because of `d^(0)` configuration.
(iii) `Mn^(2+)` is more stable than `Mn^(3+)` due to `d^(5)` configuration.
(iv) `Fe^(3+)` is more stable than `Fe^(2+)` due to `d^(5)` configuration.
(v) `Zn^(2+)` is more stable than `Zn^(+)` due to `d^(10)` configuration.
6662.

Which of the following is a Lewis base

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`CH_(4)`
`C_(2)H_(5)OH`
Acetone
Secondary amine

Solution :Presence of lone PAIR of electron and they donate two electron pairs.
6663.

What weight of AgCl will be precipated when a solution containing 4.77g of NaCl is added to a solution of 5.77g of AgNO_(3)

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ANSWER :`AgNO_(3)` is a limiting REAGENT in this PROBLEM
AgCl=4.87g
6664.

Which one of the following is not an antibiotic?

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amoxicillin
cefixime
AMLODIPINE
ampicillin

Solution : amlodipine
6665.

Which of the following compounds has ionicbond. pi-bond, co-ordinate bond and covalent bond:-

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`HNO_(2)`
`NaNO_(3)`
`KNO_(2)`
`MgCl_(2)`

Answer :B
6666.

Which tow sets of reactants best represents the amphoteric character of Zn(OH)_(2) ? I. Zn(OH_(2))(S) and OH^(-)(aq) set 2. : Zn(OH)_(2)(s) and H_(2)O(1) Set 3 : Zn(OH)_2(s) and NH_(3)(aq)

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1 and 2
1 and 3
2 and 4
3 and 4

Solution :`{:(Zn(OH)_(2) + 2OH^(-) RARR ZnO_(2)^(2) + 2H_(2)O),("Acid ""Acid ""SALT "" Water" ):}`
`UNDERSET("BASE")(Zn(OH)_2) + underset("Acid")(2H^+)rarr underset("Salt")(Zn^(2+))+underset("Water")(2H_(2)O)`
6667.

Write two differences between order of a reaction and molecularity of a reaction.

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SOLUTION :
6668.

Which among the following alkane of formula (C_6H_14) gives five types of of C_6H_(13) (excluding stereoisomer) ?

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Solution :All five CARBONS in the main CHAIN are DIFFERENT HENCE will give five isomers in mono-substitution.
6669.

Write the formula of nitric anhydride.

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SOLUTION :
6670.

Which among the following is called fruit sugar?

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GLUCOSE
FRUCTOSE
SUCROSE
MALTOSE

SOLUTION :Fructose
6671.

Which is/are correct about emulsions?

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Demulsification can take PLACE by chemical
methods only
Small amount of water cannot be mixed in
water-in-oil EMULSION
Sodium OLEATE is used to PREPARE oil-in-water
emulsion
Calcium oleate is used to prepare water-in-oil
emulsion

Answer :B::C::D
6672.

Which of the following metals are used in alloy like deltametal?

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MG 
ZN 
CO 
CU 

ANSWER :D
6673.

What do you mean by Enantiomers ?

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ANSWER :Non-superimposable MIRROR IMAGES are CALLED ENANTIOMERS.
6674.

What are analgesics? Give one example for non-narcotic analgesie.

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Solution :The DRUGS which RELIEVE PAIN are called ANALGESICS, e.g. Aspirin, morphine.
6675.

Which of the esters shown, after reduction with LiAlH_(4) and aqueous work up, will yield two molecules of only a single alcohol?

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`C_(6)H_(5)COOC_(6)H_(5)`
`CH_(3)CH_(2)COOCH_(2)CH_(3)`
`C_(6)H_(5)COOCH_(2)C_(6)H_(5)`
`CH_(3)COOCH_(3)`

Solution :Esters in which acyl and alkyl/aralkyl groups contain the same number of carbon atoms would GIVE two molecules of the same alcohol, i.e.,
`C_(6)H_(5)CO OCH_(2)C_(6)H_(5) underset((ii)" "H_(3)O^(+))overset((i)" "LiAlH_(4)//ether)to underset("Benzyl alcohol")(2C_(6)H_(5)CH_(2)OH)`
6676.

Write the equations of anodic and cathodic reactions occur during rusting of iron.

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Solution :(i) At Anode : `2FE to 2Fe^(2+) + 4e^(-)`
(II)At CATHODE : `O_2 + 4H^(+) +4e^(-) to 2H_2O`
6677.

Which of the following is true about photochemical smog ?

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It is reducing in nature
It is formed in water
It is a MIXTURE of SMOKE and fog
It CAUSES irritation in eyes.

Answer :D
6678.

What is meant by unidentate, didentate and ambidentate ligands ? Give two examples for each.

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SOLUTION :A molecule or an ion having only one donor atom and FORMING one coordinate BOND with the central metal atom is called unidentate ligand. For example, `CL^(-)` and `NH_(3)`.
A molecule or an ion having two donor atoms and hence forming two coordinate bonds with the central metal atom is called a didentate ligand. For example,
A molecule or an ion which contains two donor atoms but only one of them forms a coordinate bond at a time with the central metal atom is called ambidentate ligand. For example, `CN^(-)` : or : `NC^(-)`:
6679.

Which substances are used in aerosol mixtures of insectiside substance ?

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Feron - 22
`C ClF_(3)`
`C Cl_(2)F_(2)`
All of these

Answer :D
6680.

Whichof the followingis wrongwithrespectto lanthanidecontraction ?

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DECREASE in IONICRADII
INCREASEIN tendencyto ACTAS reducingagents
Decreases in basiccharacter
Resemblessecondsand thirrowof d- BLOCKELEMENTS

Answer :D
6681.

Which of the following compound can be used as artireeze in automobilie radiators ?

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METHANOL
ETHANOL
NEOPENTYL alcohol
ethan-1,2- DIOL

Solution :ethan-1,2- diol
6682.

Which of the following reaction shows metal corrosion reaction in presence of H_(3)O^(+) ?

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`2H_(2)O_((l)) to O_(2(g)) +4H_((aq))^(+)+4e^(-)`
`2H_(2)O_((l))+2e^(-) to H_(2(g))+2OH_((aq))^(-)`
`O_(2(g))+4H_((aq))^(+)+4e^(-) to 2H_(2)O_((l))`
`O_(2(g))+2H_(2)O_((l))+4e^(-) to 4OH_((aq))^(-)`

Solution :REDUCTION REACTION is carried out on cathode. Only reaction of (C) SHOWS reduction reaction in presence of `H^(+)(H_(3)O^(+))`.
6683.

Which of the following compound will give yellow precipitate with I_(2)//Na_(2)CO_(3)(aq) but does not respond to Cannizzaro reaction ?

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`(C_2H_5)_2CO`
` CH_3CHO`
` CH_2O`
`C_2H_5CH_2OH`

ANSWER :B
6684.

Why are reactions of higher order less in number?

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SOLUTION :A reaction takes place DUE to collide of molecules. The chances for a LARGE number of molecules or ions to collide SIMULTANEOUSLY are LESS. Hence, the reactions of higher order are less.
6685.

Which of the following phenomenon does not support the particle nature of electromagnetic radiation?

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PHOTOELECTRIC effect
Line SPECTRUM of hydrogen
Interference
Blackbody radiation

Answer :C
6686.

Which among the following is not a borane

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`B_(2)H_(6)`
`B_(3)H_(6)`
`B_(4)H_(10)`
None of these

Solution :Borances fall into TWO categories
`(a) B_(n) H_((n+4))` (CALLED nido-boranes), `B_(2)H_(6)`
`(b) B_(n)H_((n+6))` (called archno-boranes) , `B_(4)H_(10)`
`B_(3)H_(6)` does NOTFALL into any of the above categories
6687.

Which of the following compound has peroxide linkage ?

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`Pb_(2)O_(3)`
`SiO_(2)`
`PbO_(2)`
`CO_(2)`

Solution :It has peroxide linkage `O_(2)^(2-)`.
6688.

Which of the following is used in manufacture of paints ?

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GLYPTAL
Dynel
THIOKOL
KEVLAR

ANSWER :A
6689.

Total numberof CN^(-) ion that are present in ICN(liq.)

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Solution :`ICN(l) RARR(I_(2)(CN)^(+))+(I(CN)_(2))^(-)`
6690.

What is the action of 2, 4-dinitrophenyl hydrazine on acetone ?

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SOLUTION :ACETONE on reaction with 2, 4-Dinitrophenyl hydrazine forms 2, 4-dinitrophenyl HYDRAZONE.
6691.

Unit cells can be broadly classified into 2 categories primitive and centred unit cells.The unit cell dimension of a particular crystal system isa = b = c and alpha = beta = gamma = 90°. Identify the crystal system.

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SOLUTION :CUBIC CRYSTAL SYSTEM.
6692.

The reason for double helical structure of DNA is operation of

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dipole-dipole interaction
HYDROGEN BONDING
electrostatic attractions
van DER WAALS' forces

Solution :Hydrogen bonding
6693.

What happens when : (i) Ethanol is mixed with conc. H_(2)SO_(4) at 273K.

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Solution :Due to the presence of two lone pairs of electrons on the oxygen atom, alcohol acts as a Lewis BASE.
THEREFORE, at 273K, ethanol reacts with `H_(2)SO_(4)` to form oxonium salts (protonated alcohols).

(ii) Excess of ETHYL alcohol is heated with conc. `H_(2)SO_(4)` at 413K.
(iii) Ethanol is heated with excess of conc. `H_(2)SO_(4)` at 443K.
6694.

Various phenol derivatives, tincture of iodine (2 - 3% I_(2) in water/alcohol) and some dyes like methylene blue are

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Antiseptic
Analgesics
Disinfectants
Antipyretics

Solution :Antiseptic drugs cause destruction of micro-organism that PRODUCE septic disease e.g., DETTOL, Savlon, Boric acid, PHENOL, Iodoform `KMnO_(4)` and some dye such as CHLORAMINE T METHYLENE blue, genation violet.
6695.

Which of the following statement is incorrect for XeF_(6) ?

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Its PARTIAL hydrolysis gives `XeOF_(4)` and `XeO_(2)F_(2)` which is non-redox hydrolysis.
Its reaction with silica gives `XeOF_(4)`.
It is prepared by reaction of `XeF_(4)` and `O_(2)F_(2)`.
It disproportionates under water.

SOLUTION :`DeltaS=nF((dF)/(dT))=2xx96500xx2xx10^(-4)=38.6J`
at equilibrium `DeltaG=DeltaH-TDeltaS=0`
`DeltaH=TDeltaS=300xx38.6=11580J`
6696.

What is the hybridization of nitrogen in NH_3 ?

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SP
`sp^2`
`sp^3`
`dsp^2`

ANSWER :C
6697.

The shapes of SF_(4) and XeF_(2) respectively are

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TRIGONAL bipyramidal and trigonal bipyramidal
see-saw and LINEAR
T-shape and linear
square planar and trigonal bipyramidal

Solution :`SF_(4)` (`sp^(3)`d, see-saw) and `XeF_(2)` (`sp^(3)`d, linear).
6698.

Which among the following elements of group -2 exhibits anomalous properties?

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Be
Mg
Ca
Ba

Solution :Be
6699.

Write the cell reaction for the half cell Cl_((aq))^-)//AgCl_((s))Ag.

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SOLUTION :`AgCl_((s))+E^(-)rarr Ag_((s))+Cl^(-)`
6700.

The standard reduction potentials of metal electrodes A,B,C and D are +0.14V,+0.34V,-0.74 V and -0.4V respectively, Which is the best reducing agent :

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A
B
C
D

Answer :C