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7951.

Which statement if wrong regarding osmotic pressure (P), volume (V) and temperature (T)

Answer»

<P>`P prop (1)/(V)` ID T is constant
`F prop T` is V is constant
`P prop V` is T is constant
PV is constant if T is constant

Answer :C
7952.

Which of the following reactions goes almost all the way to completion, and which proceeds hardly at all ? 2NO(g) + O_(2)(g)hArr2NO_(2) (g) , K_(c) = 6.0 x× 10^(13)

Answer»


ANSWER :ALMOST COMPLETE
7953.

Which is most stable compound among the following

Answer»




All the COMPOUNDS have same stability

Answer :C
7954.

When an aqueous solution of lithium chloride is electrolysed using graphite electrodes

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`Cl_2` is LIBERATED at the anode.
Li is DEPOSITED at the cathode
as the current FLOWS,pH of the solution around the cathode REMAINS constant
as the current flows,pH of the solution around the cathode decreases

Answer :A
7955.

Which one of the following is not used as fertlizer ?

Answer»

Ammonium nitrate
Ammonium sulphate
Ammonium phosphate
potassium sulphate

Solution :Ammonium sulfide solutions are USED occasionally in photographic developing, to apply patina to bronze, and in textile MANUFACTURING . Also, due to offensive smell, it is the ACTIVE ingredient in a veriety of pranks including the common STINK BOMB.
7956.

When acetone undergoes reduction in presence of Zn-HCl/Hg, it is known as

Answer»

WOLF Kishner's reduction
Rosenmund's reduction
Cleammenson's reaction
Gatterman's reaction

Answer :C
7957.

Thermal decomposition of KC10, in the presence of ........... follows ........... theory.

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SOLUTION :`MnO_2` , intermeidatecompoundformation THEORY .
7958.

Which of the following strategy is not useful for global warming

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Use of FOSSIL fuel in limit
Increase in forest
Increasing use of NITROGEN fertilizers
Use of other OPTIONS in PLACE of CFC

Answer :C
7959.

Which of the following is the correct order for strength of C - X bond.

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`CH_(3)F gt CH_(3)CL gt CH_(3)Br gt CH_(3)L`
`CH_(3)F lt CH_(3)Cl lt CH_(3)Br lt CH_(3)l`
`CH_(3)l gt CH_(3)F gt CH_(3)Cl gt CH_(3)Br`
`CH_(3)Cl gt CH_(3)Br gt CH_(3)F gt CH_(3)l`

ANSWER :A
7960.

Which of the following is an example of liquid dishwashing detergent?

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`CH_3(CH_2)_(10)-CH_2C_6H_4OSO_3^(-) Na^(+)` <BR>

`[CH_3(CH_2)_(15)-UNDERSET(CH_3)underset(|)overset(CH_3)overset(|)N-CH_3]^(+)Br^(-)`

Solution : Non-ionic detergents are used an LIQUID dish WASHING detergents.
7961.

The compound formed on heating chlorobenzene with chloral in the presence of concentrated sulphuric acid, is:

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FREON
HEXACHLOROETHANE
Gammexene
DDT

Answer :D
7962.

What is meant by degree of polymerization ?

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Solution :The number of REPEATING units of MONOMERS in a CHAIN of a polymer is called its DEGREE of polymerization.
7963.

Welding of magnesium can be done in an atmosphere of:

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`O_2`
He
`N_2`
All

Answer :B
7964.

What is the minimum energy of photons which causes photoelectric effect with platinum metal? The threshold frequency of the metal platinum is 1.3xx1015s^(-1).

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SOLUTION :`8.3xx10^(-19)J`
7965.

Which hydrocarbon will be most stable

Answer»

Methane
Ethane
Propane
Butane

Answer :D
7966.

Which of the following result the chemist must have observed about his studies with KCl solution ?

Answer»

Dilute KCL SOLUTION shows no adsorption whereas CONCENTRATED KCl shows adsorption.
Concentrated KCl solution shows no adsorption whereas dilute KCl solution adsorption.
Dilute KCl solution shows positive adsorption whereas concentrated KCl solution shows negative adsorption.
Concentrated KCl solution shows positive adsorption whereas dilute KCl solution shows negative adsorption.

Solution :Soolute is adorbed from concentrated KCl solution whereas SOLVENT (WATER) is adsorbed from dilute KCl solution.
7967.

While testing borate, green edged flame is due so formation of (a) _____.

Answer»


Answer :a.`(C_(2)H_(2)O)_(3)B`
7968.

When a hydrocarbon (A) is treated with Br_(2) gives (B). The compound (B) is treated with Na metal in ether gives 2,3- dimethyl butane. The compound (A) is

Answer»

`CH_(3)-CH_(3)`
`CH_(4)`
`CHH_(3)CH_(2)CH_(3)`
`CH_(3)CH(CH_(3))CH_(3)`

SOLUTION :`CH_(3) CH_(2)CH_(2) +Br_(2) overset(AlBr_(3)) to CH_(3) CHClCH_(3)`
`2CH_(3)Br+2Na overset("dry ether") to C_(2)H_(6)+2NaBr`
ETHANE is thehydrocarbon which contain less than foun carbon atoms.
7969.

Unlike phenol , 2,4-dinitrophenol is soluble in sodium carbonate solution in water because

Answer»

presence of two- `NO_(2)` GROUPS in the ring makes 2,4- dinitrophenol a stronger ACID than PHENOL
presence of two - `NO_(2)` groups in the ring makes 2,4-dinitrophenol a weaker acid than phenol
presence of two - `NO_(2)` groups make the hydrogen bonding easier , making 2,4-dinitrophenol soluble
nitro group reacts with `Na_(2)CO_(3)` while `-OH` group does not .

Answer :A
7970.

The real vapour pressure for non ideal solution is …….. Than by Raoult's law.

Answer»

more
LESS
EQUAL
(A) and (B) both

ANSWER :D
7971.

underset (("solid"))(HgI_(2))+underset((aq))(2KI)rarrK_(2)underset((aq))([Hg_(4)])(100%) yield) If exactly sufficient HgI_(2) solid is dissoved in an aqueous potassium iodide solution , which of the following may be observed ? (allsubstances are completely ionised)

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The elivation BOILING POINT of water in THESOLUTION drops by `25%`
Freezing point of the solution increased by `25%`
`'DeltaT_(f)'` of KI solution decreases by `25%`
Freezing point of solution decreases by `25%`

Answer :A::B::C
7972.

Which of the following has both Schottky and Frenkel defects.

Answer»

AGBR
ZNO
NACI
KCI

ANSWER :A
7973.

What are the applications of colloids.

Answer»

Solution :Collodion is used to reduced pore SIZE of filter paper to get ultra-filters.
(ii) Alum is added to coagulate suspended impurities so as to purify drinking WATER.
(iii) Colloidal antimony is used in curing kalazar (disease caused by mosquito bite).
(IV) Argyrol is used as eye lotion.
(v) Milk of MAGNESIUM is used as antacid.
(vi) Animal hides are colloidal in nature and are positively charged. When it is soaked in tannin which contains negatively charged colloidal particles, mutual takes place. This result in turning of leather or hardening of leather. `K_2Cr_2O_7` is used for tanning of leather asitis and oxdizing agent.
7974.

When an aqueous solution of lithium chloride is electrolysesd using graphite electrodes :

Answer»

pH of the RESULTING solution increases
pH of the resulting solution decreases
As the current FLOWS, pH of the solution around the CATHODE increases
None of these

Answer :A
7975.

The total number of alkyl groups having the molecular formula (c) C_(3)H_(7) (b) C_(4)H_(9) (c) C_(5)H_(11) are.

Answer»


ANSWER :a-2, b-4, c-8
7976.

The surface tension of water at 21°C is 72.75 xx 10^(3) Nm^(-1). A 33.24% (vol./vol.) solution of ethanol has y = 33.24 xx 10^(-3) Nm^(-1)at the same temperature. Given density (solution) = 0.9614 xx 10^3 kg m^(-3)and density (water) = 0.9982 xx 10^3 kg m^(-3). How much less will the alcohol solution rise in the same capillary? Angle of contact, theta = 0^(@)

Answer»

Solution :We have,
`gamma = (hdrg)/2`
As the same capillary is used for both ETHANOL and water, r and g are the same in both.
`THEREFORE h_(1)/h_(2) = (gamma_(1).d_(2))/(gamma_(2).d_(1))`
.1. and .2. stand for ethanol and water RESPECTIVELY.
`h_(1)/h_(2) = ((33.24 xx 10^(-3)) xx 0.9982 xx 10^(3))/((72.75 xx 10^(-3)) xx 0.9614 xx 10^(3)) = 0.474`
Thus, ethanol will rise only 47.4% as FAR as pure water.
7977.

The specific optical rotations of pure a- and b-D-mannopyranose are + 29.3° and -17.0, respectively. When either form is dissolved in water, specific optical rotation of the equilibrium mixture is found to be + 14.2°. Calculate the percentage of a anomer at equilibrium.

Answer»


Solution :LET FRACTION of a corner=X
`THEREFORE` Fraction of b-anomer =(1-x)
Hence, `x(+29.3^(@)) + (1-x)(-17.0^(@))=+14.2^(@)`
`29.3^(@)x + 17^(@)x = 14.2^(@) + 17^(@)`
x=0.67
`therefore` Fraction of a-anomer = 0.67 or 67%
7978.

Which of the following element possess highest metallic properties ?

Answer»

P
As
Sb
Bi

Answer :D
7979.

Which is the reagent whose reaction with glucose indicates the presence of Carbonyl group in it ?

Answer»

`NH_(2)OH`
Conc. `HNO_(3)`
`(CH_(3)CO)_(2)O`
HI

Solution :`NH_(2)OH`
7980.

When NH_(4)Cl is added to a solution of NH_(4)OH,

Answer»

The dissociation of `NH_(4)OH` INCREASES
The CONCENTRATION of `OH^(-)` ions increases
Dissociation of `NH_(4)Cl` decreases
The concentration of `OH^(-)` ions decreases

ANSWER :D
7981.

Using Raoult's law, explain how the total vapour pressure over the solution is related to molefraction of components in the following solutions :(i) CHCl_3 (l) " and " CH_2Cl_2(l)(ii) NaCl (s) " and " H_2O (l)

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Solution : (i) For a binary solution having both components as volatile liquids, the total PRESSURE will be
`p = x_1p_1^0 + x_2p_2^0`
`= x_1p_1^0 + (1-x)p_2^0`
`= (p_1^0 - p_2^0) x_1 + p_2^0`
p=total vapour pressure
`p_1` = partial vapour pressure of COMPONENT 1 (SAY `CHCl_3`)
` P_2` = partial vapour pressure of component 2 (say `CH_2Cl_2`)
`x_2` = mole FRACTION of `CHCl_3`
(ii)For a solution containing non-volatile SOLUTE, the Raoult.s law is applicable only to vaporisable component (1) and total vapour pressure is written as
`p = x_1p_1^0`
7982.

Which is more stable PCl_(5) or PCl_(3) ? Or What happens when PCl_(5) is heated ?

Answer»

Solution :`PCl_(3)` is more stable than `PCl_(5)` because on heating `PCl_(5)` decomposes to form `PCl_(3) and Cl_(2)`
`PCl_(5) OVERSET(Delta)rarr PCl_(3) + Cl_(2)`
7983.

Which of the following atoms has miniumum covalent radius

Answer»

B
C
N
Si

ANSWER :C
7984.

Which of the following is a composition of bleaching powder ?

Answer»

`CA(OCL)_(2).CaCl_(2) .Ca(OH)_(2).2H_(2)O`
`Ca(Ocl)_(2).Ca(OH)_(2)`
`CaOCl.CaCl_(2).Ca(OH)_(2)`
`CaOCl.CaCl_(2).2H_(2)O`

Answer :A
7985.

Which compound in each of the following pairs will react faster in S_(N)2 reaction with OH^(-)? (a) CH_(3)Br or CH_(3)I (b) CH_(2)=CHBr or CH_(2)=CHCH_(2)Br.

Answer»

Solution :(a) Since `I^(-)` ion is a better leaving group than `Br^(-)` ion, therefore, iodidies are more reactive than bromides. In other words, `CH_(3)I` is more reactive than `CH_(3)Br`.
(b) Reactiviity in `S_(N)2` reactions among other things DEPENDS upon the magnitude of the +ve charge on the carbon atom carrying the halogen. now the `sp^(2)`-carbon atom of the `CH_(2)` group carrrying the Br atom in `CH_(2)=CHCH_(2)Br` carries more +ve charge due to -I-effect of the Br atom and the `CH_(2)=CH`- group as COMPARED to `sp^(2)`-carbon atom of `CH` group in `CH_(2)=CHBr` due to electron-donating RESONANCE effect.

As a result, `CH_(2)=CHCH_(2)Br` will react faster than `CH_(2)=CHBr` with `OH^(-)` ions.
7986.

Why a drug should not be taken without consulting a doctor ? Give two reasons.

Answer»

SOLUTION :(i) To avoid side effects CAUSED by drug.
(II) To have the ADVICE for proper DOSE of drug.
7987.

Which of the following is not the true about crystalline solids

Answer»

they are RIGID and hard
theypossess plane SURFACES
they are obtained by rapid COOLING of motten substances
they have definete geometricconfiguration

Answer :C
7988.

Z is:

Answer»




SOLUTION :
7989.

Which of the following is not a cellulose product,

Answer»

GUN COTTON
CELLULOID
RAYON
Dacron

Answer :D
7990.

Which of the following is polymide?

Answer»

TEFLON
TERYLENE
NYLON 6,6
Bakelite

ANSWER :C
7991.

The structure of a basic amino acid, lysine, is given below: (HOOC-underset(.^(o+)NH_(3))underset(|)(C)H-(CH_(2))_(3)-CH_(2)overset(o+)(N)H_(3))(A) The pK_(a_1),pK_(a_2), and PK_(a_3) of (A), respectively, are: 2.18,8.95, and 10.53. What is the pH at isoelectric points (pI)?

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`(pK_(a_(1))+pK_(a_(2)))/(2)`
`(pK_(a_(1))+pK_(a_(3)))/(2)`
`(pK_(a_(2))+pK_(a_(3)))/(2)`
`(pK_(a_(1))+pK_(a_(2))+pK_(a_(3)))/(3)`

ANSWER :C
7992.

Which of the following statement is/are correct for gas (D) ? (I)it has the state of hydridisation sp^(3) (II)Gas can be identified by CaCI_(2) solution (III)Gas can be identified by Pb(OAc)_(2) solution (IV)Gas can be identified by passingthrough solution

Answer»

I,IV
I,III
III only
I,II,IV

Answer :C
7993.

What happens whenD-glucoseis treatedwith thefollowingreagents ? (i) HI (ii) Brominewater (iii) HNO_(3)

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SOLUTION :(i)` UNDERSET("D - Glucose")underset(CH_(2)OH)underset(|)overset(CHO)overset(|)((CHOH)_(4))+ HI to CH_(3) - CH_(2) - CH_(2) - CH_(2) - CH_(3)`
7994.

Which of the following have maximum electronegativity

Answer»

Al
S
Si
P

Solution :ELECTRONEGATIVITY INCREASES ACROSS a PERIOD.
7995.

Which of the following are polar protic solvents

Answer»

Water
Dimethyl sulphoxide
Dimethyl formamide (DMF)
Fromic acid

SOLUTION :A,D but not BC DMSO, and DMF is POLAR aprotic solvents
7996.

The solubility of a solid in H_(2)O at different temperatures is indicated in the accompying diagram. What mass of the solid will crystallize when 40mL of a solution that is saturated at 80^(@)C is cooled to 20^(@)C?

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12g
24g
30g
36g

Answer :A
7997.

Write the role of (a) Dilute NaCN in the extraction of gold. (b) CO in the extraction of Iron.

Answer»

SOLUTION :Dilute NACN is used as a leaching agent.
(b) CO is used as a REDUCING agent
7998.

Which of the following statements about the assembly of nucleotides in a molecule of deoxyribonucleic acid is correct?

Answer»

A PENTOSE of one unit CONNECTS to a pentose of another
A pentose of one unit connects to the base of another
A PHOSPHATE of one unit connects to a pentose of another
A phosphate of one unit connects to the base of another

Answer :C
7999.

What is the primary structural feature necessary for a molecule to make it useful in a condensation polymerization reaction ?

Answer»

Solution :The MONOMER molecule must be bifunctional, i.e., it must have two FUNCTIONAL GROUPS , For example , CAPROLACTAM.
8000.

Which of the following statements about the interstitial compounds is incorrect?

Answer»

They are much harder than the PURE metal
They have HIGHER melting points then the pure metal
They RETAIN METALLIC conductivity
They are chemically very reactive

Answer :D