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88251.

(A) Number of moles of H_(2) in 0.224 L of H_(2) is 0.001 mol. (R) 22.4 litres of H_(2) at STP contains 6.023xx10^(23) mol.

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If both (A) and (R) are CORRECT and (R) is the correct EXPLANATION of (A).
If both (A) and (R) are correct but (R) is not the correct explanation of (A).
If (A) is correct but (R) is WRONG.
If (A) is wrong but (R) is correct.

Answer :C
88252.

A number of ionic compounds are insoluble in water. This is because

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Ionic COMPOUNDS do not dissolve in water
Water has a high dielectric CONSTANT
Water is not a good ionizing SOLVENT
These molecules have high lattice energy

ANSWER :D
88253.

A number of factors such as temperature, concentration of reactants, ____________, affect the rate of reaction.

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SOLUTION :CATALYST
88254.

A number of elements are available in earth's crust but most abundant elements are

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`AL and FE`
`Al and CU`
`Fe and Cu`
`Cu and AG`

ANSWER :A
88255.

A number ofelecments areavailablein earth'scrustbut mostabundantelementsare

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AL ANDFE
Al andCu
FeandCu
CU andAg

ANSWER :A
88256.

A number of elements are available in earth's crust but most abundant elements are……….

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AL and Fe
Al and Cu
Fe and Cu
Cu and Ag

Answer :A
88257.

A number of elements are available in earth's crust but most abundant elements are :

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Al and Fe
Al and Cu
Fe and Cu
Cu and Ag

Solution :ALUMINIUM (8.3%) and IRON (5.1%) are most abundant ELEMENTS in earth's CRUST.
88258.

A nuclide of an alkaline earth metal undergoes radioactive decay by emissio of the alpha-particles in succession. The group of the periodic table to which the resulting daughter element would belong is

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`Gr.14`
`Gr.16`
`Gr.4`
`Gr.6`

Solution :`UNDERSET(Gr.2)(._(Z)A^(M)) overset(-alpha)rarr underset(Gr.18)(._(Z -2)B^(M-4)) overset(-alpha)rarr underset(Gr.16)(._(Z-4)C^(M -8))`
88259.

A nuclide has mass number (A) and atomic number (Z). During a radioactive process if: (A) both A and Z decrease, the process is called alpha-decay (B)A remains unchanged and Z decreases by one, the process is called beta^(+) or positron decay of K-electron capture (C ) both A and Z remain unchanged the process is called gamma-decay (D)both A and Z increase, the process is called nuclear isomerism. The correct answer is:

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1,2 and 3
2,3, and 4
1,3, and 4
1,2, and 4

Answer :a
88260.

A nucleotide consists of three parts : a phosphate unit, a sugar and a..............or ...............

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SOLUTION :PURINE , PYRIMIDINE
88261.

A nucleotide consist of …….. .

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baseand SUGARE
baseand phosphate
SUGAR and phosphate
base , sugar andphosphate

ANSWER :D
88262.

A nucleoside on hydrolysis gives

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an aldopentose and a NITROGENOUS BASE
an aldopentose and PHOSPHORIC acid
an aldopentose, a nitrogenous base and phosphoric acid
a nitrogenous base and phosphoric acid

Answer :A
88263.

A nucleophilic reagent would readily attack:

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CARBONIUM ion
Carbanion
ethane
`CH_4`

ANSWER :C
88264.

A nucleophile is:

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LEWIS ACID
Lewis acid and ALSO a Lewis base
Lewisbase
NEITHER a Lewis acid nor a Lewis base

Answer :C
88265.

A nucleophile should possess_________.

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an overall negative charge
an overall positive charge
a LONE PAIR of electrons
an UNPAIRED electron

Answer :C
88266.

A nucleophile is a :

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LEWIS ACID
Lewis BASE
Both Lewis acid and Lewix base
Neither a Lewis acid nor a Lewis base.

ANSWER :B
88267.

A nucleide of an alkaline earth metal undergoes radioactive decay by emission of three a-particles in succession. The group of the periodic table to which the resulting daughter element would belong is:

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GROUP 4
Group 6
Group 14
Group 16

Solution :When II A group element (Ra) emits ONE `alpha`- particle its group no. decreases by two units i.e. goes into zero group (group 18). But it is alsoradioactive and DUE to successtion emission, last product is Pb i.e. (Group 14).
88268.

A nuclear reaction is accompanied by loss of mass equivalent to 0.01864 amu. Energy liberated is:

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931 MEV
`186.6` MeV
17.36 MeV
460 MeV

Solution :Energy liberated = LOSS of MASS `XX 931`
`= 0.01864 xx 931 = 17.36 MeV`
88269.

A nuclear reaction is accompanied by a loss of mass equivalent to 0.01864 amu. The energy liberated is

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17.34 MeV
186.2 MeV
4.655 MeV
9321.1 MeV

Answer :A
88270.

(A) Nuclear isomers have same atomic number and same mass number but with different radioactive properties. U_((A)) and U_((Z)) are nuclear isomers.

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If both (A) and (R ) are CORRECT and (R ) is the correct EXPLANATION for (A).
If both (A) and (R ) are correct but (R ) is not the correct explanation for (A )
If both (A) and (R ) are incorrect.
If both (A) and (R ) are incorrect.

Answer :A
88271.

A non-volatile solute (A) is dissolved in a volatile solvent (B). The vapour pressure of the resultant solution is P_(s^(*)). The vapour pressure of pure solvent is P_(B)^(@). If X_(B) is the mole fraction of the solvent, which of the following is correct?

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`P_(S)=P_(B)^(0).X_(A)`
`P_(B)^(0)=P_(S)X_(B)`
`P_(S)=P_(B)^(0)`
`P_(B)^(0)=P_(S)X_(A)`

Answer :C
88272.

A non -volatile solute.'A' tetramerises in water to the extent of 80% .2.5 g of 'A' in 100 g of water .lower the freezing point by 0.3 ""^(@)C.The molar mass of Å in mol 4^(-1) is (K_(T)For water =1.86 K kg mol^(-1))

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62
221
155
354

Solution :(a): As non-volatile SOLUTE ‘A’ tetramerises,
`:. ALPHA =(l=i) (n)/(n-1) alpha = 80%` (given)
0.8 = (l-i) `4/3 rArr i=0.4`
`Delta T_(f) = iK_(f)m`
`0.3=0.4xx1.86xx (2.5)/("Molar mass") xx (1000)/(100)`
Molar mass `= (0.4xx1.86xx2.5xx10)/(0.3)` = 62 g/mol
Note: Read mole `L^(-1)` as g `mol^(-1)` in question.
88273.

A non-volatile hydrocarbon has 5.6% hydrogen. Determine the molecular formula of the non-volatile hydrocarbon (Molecular mass of benzene is 78 a.m.u.)

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SOLUTION :Step I. Calculation of empitical fromula of the hydrocarbon.
in hydrocarbon, H=5.6% , C=100-5.6= 94.4 %

Empirical formula of hydrocarbon `=C_(7)H_(5)`
`"Empirical formula mass of hydrocarbon"=7xx12+5xx1=89" amu"=89 g`
Step II. Calculation of molecular mass of the hydrocarbon.
According to Raoult's law,
`(P_(A)^(@)-P_(S))/(P_(A)^(@))=X_(B)=n_(B)/n_(A)`
`(P_(A)^(@)-P_(S))/(P_(A)^(@))=1.306xx10^(-2),W_(B)=3g, W_(A)=100g, M_(A)=78" amu"=78" g mol"^(-1)`
`1.306xx10^(-2)=(W_(B)//M_(B))/(W_(A)//M_(A))=((3g)//M_(B))/((100g)//(78" g mol"^(-1)))=(3xx78(g//mol^(-1)))/(100xx(M_(B)))`
`M_(B)=(378(g//mol^(-1)))/(100xx(1.306xx10^(-2)))=179.17("GMOL"^(-1)).`
Step III. Calculation of molecular formula of the hydrocarbon.
`n=("Molecular mass of hydrocarbon")/("Empirical formula mass of hydrocarbon")=(179.17)/(89.0)~~2.
`"Molecular formula"=nxx"Empirical formula"=2C_(7)H_(5)=C_(14)H_(10).`
88274.

A non-reacting gaseous mixture contains SO_2 and SO_3 in the mass ratio of 1 : 5. Find the ratio of the number of molecules

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` 1 : 1`
`4 : 5`
` 1 : 4`
` 1 : 5`

ANSWER :`C`
88275.

(A) Non-competitive inhibitors occupy allosteric site so that the substrate cannot attach at active site. (R) Non-competitive inhibitors change the shape of active site of enzyme after binding at allosteric site.

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Both (A) and (R) are TRUE and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :A
88276.

(A): Noble gases are springly soluble in water (R): Neon has high positive electron gain enthalpy.

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Both (A) and (R) are true and (R) is the correct EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :B
88277.

(A) Noble gases have very high ionization enthalpies in periodic table (R) All noble gases have stable octet configuration in their valence shell

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Both (A) and (R) are TRUE and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :C
88278.

A noble gas has the property to diffuse through rubber. Name the noble gas.

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SOLUTION :HELIUM has PROPERTY to DIFFUSE through RUBBER.
88279.

A noble gas which is not adsorbed by coconut charcoal is

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He
Ne
Ar
Ra

Solution :He, due to small SIZE and WEAK VANDERWAAL forces
88280.

(A): Noble gases are lower melting points and boiling points (R): Noble gases posses weak dispersion forces.

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Both (A) and (R) are true and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :A
88281.

(A) Noble gas elements have very low melting and boiling points(R) The interatomic attractions in noble gas elements are weak dispersion forces.

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Both (A) and (R) are TRUE and (R) is the correct EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :A
88282.

(A): NO_(3)^(-) and CO_(3)^(-2) ions are isoelectronic. (R): Nitrate ion is planar

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Both (A) and (R ) are TRUE and (R ) is the correct EXPLANATION of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

Answer :2
88283.

(a) NO_(2)^(-) interface in the Ring Test of NO_(3)^(-) Suggest a chemical method for removal of NO_(2)^(-).(b)I interface in the Ring of NO_(3)^(-). Suggested chemical reagent that can remove I

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Solution :By bolling the mixture with `NH_(4)CL,NO_(2)^(-)` is decomposed as `N_(2)`
`NaNO_(2)+NH_(4)OVERSET(Delta)toNaCl+N_(2)uarr+2H_(2)O`
`HgCl_(2)`removes l as Hg`l_(2)`
`Hgl_(2)toHgl_(2)darr+2Cl`
88284.

(A): Nitrous oxide is called laughing gas. (R): Nitrous oxide is a linear molecule.

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Both (A) and (R ) are TRUE and (R ) is the correct EXPLANATION of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

Answer :2
88285.

A nitrogen containing compound on heating with CHCl_3 and alcoholic KOH evolved an unpleasant smelling vapour. The compound could be

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NITROBENZENE
ANILINE
BENZAMIDE
N, N-dimethyl aniline

Answer :B
88286.

(A) Nitromethane can give aldol condensation. (R) alpha hydrogen of nitromethane is acidic.

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If both (A) and (R) are CORRECT and (R) is the CORECT explanation of (A)
If both (A) and (R) are correct but (R) is not correct explanation of (A)
If (A) is correct but (R) is incorrect.
If (A) is incorrect but (R) is correct

ANSWER :A
88287.

A nitrogenous substance X is treated with HNO_(2) and the product so formed is further treated with NaOH solution, which produces blue colouration. Which of the following can X be ?

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`CH_(3)CH_(2)NH_(2)`
`CH_(3)CH_(2)NO_(2)`
`CH_(3)CH_(2)ONO`
`CH_(3)UNDERSET(CH_(3))underset(|)(CH)NO_(2)`

Solution :`{:(""CH_(3)""CH_(3)),("|""|"),(H_(3)C-CH-NO_(2) underset(-H_(2)O)overset(HO-N=O)(rarr) H_(3)C-C-NO_(2)),(" "2^(@)" Nitroalkane""|"),(""X""N=O),("Pseudonitrole"),(""darr NAOH),("Blue COLOURATION"):}`
88288.

A nitrogenous subsatnce X is treated with HNO_2 and the product so formed is further treated with NaOH solution , which produces blue colouration X can be :

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`CH_3CH_2NH_2`
`CH_3CH_2NO_2`
`CH_2CH_2ONO`
`(CH_3)_2CHNO_2`

ANSWER :D
88289.

A nitrogenous substamnce (X ) is treated withHNO_2 and the product so formed is further treate withNaOH solution , which produces blue coloruation . Whichof the following can (X ) be ?

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`CH_3CH_2NH_2`
`CH_3CH_2NO_2`
`CH_3CH_2ONO`
`(CH_(3))_(2)CHNO_(2)`

Solution :The reaction is a TEST for ` 2^@` nitro compound .
.
88290.

A nitrogenouscompoundis treatedwithnitrousacidand the prodructsofromedinfurthertreatedwith NaOHsoluitonwhichproduces bluecolouration . The nitrogenouscompoudis

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`CH_(3) - CH_(2) - CH_(2) - NH_(2)`
`CH_(3)-CH_(2) - NO_(2)`
`CH_(3) - CH_(2) - O-N = O`
`CH_(3)- UNDERSET(NO_(2))underset(|)(CH) - CH_(3)`

Solution :Secondary nitroalkane givenblue colouredpseudonitrol, whichdo notundergo TAUTOMERISATION . Hencebluecolouris retainedwhen TREATEDWITH `NaOH`.
88291.

A nitrogenous compound is treated with HNO_(2) and the product so formed is further treated with NaOH solutoin which produces blue colouration. The nitrogenous compound is:

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`CH_(3)CH_(2)NH_(2)`
`CH_(3)CH_(2)NO_(2)`
`CH_(3)CHONO`
`CH_(3)UNDERSET(CH_(3))underset(|)(CH)NO_(2)`

ANSWER :D
88292.

(A): Nitrogen is unable to show a valency more than three. (R): Nitrogen does not have vacant d-orbitals in its valence shell.

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Both (A) and (R ) are true and (R ) is the CORRECT explanation of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is false
Both (A) and (R ) are false

ANSWER :1
88293.

(A) :Nitrogen is a non metal where as Bismuth is a typical metal (R ) Oxides of Nitrogen are acidic where as Bi_(2)O_(3) is a basic oxide

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Both (A) and (R ) are true and (R ) is the CORRECT EXPLANATION of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is false
Both (A) and (R ) are false

Answer :2
88294.

(A)Nitrogen is a gas, where as phosphorus is a solid (R ) Nitrogen can form (P-P) pi bonds in effective manner when compared to phosphorus

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Both (A) and (R ) are TRUE and (R ) is the CORRECT EXPLANATION of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is false
Both (A) and (R ) are false

Answer :1
88295.

(A) : Nitrogen has higher ionization energy than that of oxygen. (R ) : Nitrogen atom has smaller atomic size than that of oxygen.

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Both (A) and (R ) are true and (R ) is the CORRECT explanation of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

ANSWER :3
88296.

a) Nitrogen dioxide (NO_(2)) dissociates into nitric oxide (NO) and oxygen (O_(2)) as follows: Write the rate of reaction in terms of (i) rate of disappearance of NO_(2) ii) rate of formation of NO and iii) rate of formation of O_(2). Equate the three rates of reaction. b) If the rate of decreases of concentration of NO_(2) is 6.0 xx 10^(-12) mol L^(-1)s^(-1), calculate the rate of increase of concentration of NO and O_(2)

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Solution :a) SELF explanatory
B) Solved in the text PORTION
88297.

A nitrogen containing organic compound gave an oily liquid on heating with bromine and potassium hydroxide solution. On shaking the product with acetic anhydride, an antipyretic drug was obtained. The reactions indicate that the starting compound is

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 ANILINE
 BENZAMIDE
 acctamide
nitrobenzene.

SOLUTION :Acetanilide has been used in medicine as anti fibrin for lowering body temperature (antipyretic) and to relieve HEADACHE. On account of its toxic nature, its use as a drug is not finding favour and is replaced by more effective and LESS toxic drugs.
88298.

A nitrogen -containing aromatic compound A reacts with Sn/HCl, followed by HNO_(2) to give an unstable compound B. B on treatment with phenol, forms a beautiful coloured compound C with the molecular formula C_(12)H_(10)N_(2)O. The structure of compound A-

Answer»




ANSWER :C
88299.

A nitrogen containing compound dissolves in 10% aq. sulfuric acid. The Hinsberg test (C_(6)H_(5)SO_(2)Cl in base) gives a solid product that is not soluble in 10% aq. NaOH. Which of the following would best fit these facts?

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N,N-Dimethylaniline, `C_(6)H_(5)N(CH_(3))_(2)`.
N-Methylbenzamide, `C_(6)H_(5)CONHCH_(3)`.
N-Methylaniline, `C_(6)H_(5)NHCH_(3)`.
Benzylamine, `C_(6)H_(5)CH_(2)NH_(2)`.

SOLUTION :`2^(@)` AMINE
88300.

(A): Nitrogen can form pentahalides (R): Nitrogen does not possess vacant d-orbitals in the valance shell

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Both (A) and (R ) are TRUE and (R ) is the correct EXPLANATION of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

Answer :1