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16251.

When iron nail is placed in CuSO4 solution then....

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oxidation of Fe is not possible. 
BLUE color of solution BECOME FAINT
reduction of `Cu^(2+)` is not possible. 
reduction of `Fe` is possible. 

Answer :B
16252.

Which has minimum osmotic pressure

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200 mL of 2 M NaCl pressure
200 mL of 1 M GLUCOSE solution
200 mL of 2 M urea solution
All have same osmotic pressure

Solution :Osmotic pressure is a colligative property. Particles in NaCl solution `= 2xx2 = 4M` . Particles in glucose solution `= 1xx1 =1M`. Particles in urea solution `= 2xx1=2 M`. LEAST particles are in glucose solution, hence its osmotic pressure is the MINIMUM.
16253.

Write the structure of the product expected to be formed when CH_2=CH-overset("*")CH_3(overset("*")C=""^(14)C) is subjected to free radical chlorination.

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SOLUTION :
16254.

Which one of the following statements regarding the population of different conformers butane -2, 3 - diol is true?

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The most populated CONFORMER with have the hydroxyl GROUPS of the GAUCHE position.
The most populated conformer will have the hydroxyl groups at the anti position.
All staggered conformations will be equally populated.
Relative POPULATIONS of different conformers is not predictable

Answer :A
16255.

What is the bond angle in NH_4^+ion ?

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SOLUTION :`109.5@0`
16256.

The relative lowering of vapour pressure of an aqueous solution containing non-volatile solute is 0.0125. The molality of the solution is

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0.7
0.5
0.6
0.8

Solution :Relative lowering of VAPOUR pressure
= mole fraction of the SOLUTE in the solution,
i.e., `(n_(2))/(n_(1)+n_(2))=0.0125`
Molality `=n_(2)" when "n_(1)=1000/18 " mole"`
= 55.55 mole
`(n_(1)+n_(2))/(n_(2))=(1)/(0.0125)=80or(n_(1))/(n_(2))+1=80`
`"or"(n_(1))/(n_(2))=79 or n_(2)=(n_(1))/(79)=(55.55)/(79)=0.70`
16257.

Which of the following cation maybe present in white ppt ?

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`Pb^(2+)`
`Hg^(2+)`
`AG^(o+)`
`Bi^(3+)`

Answer :a,B,c
16258.

What LDP and HDP signify ? How are they prepared ?

Answer»
16259.

Thermodynamically, the most stable allotrope of C is

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DIAMOND
GRAPHITE
anthractice
all of these

SOLUTION :Graphite is thermodymically more STABLE than diamond.
16260.

Which of the following undergoes sublimation ?

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`AlCl_3`
`NH_4Cl`
DRY ice
All of these

Answer :D
16261.

Write the structural formual and IUPAC name of the following compunds. (i) Methyl cyanide (ii) Propionitrile (iii) Butyro nirile

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Solution :(i) `CH_(3)CN""` Ethane nitrile
(II) `CH_(3)-CH_(2)CN""` Propane nitrile
(iii) `CH_(3)-CH_(2)-CH_(2)CN""` Butane nitrile
16262.

Vanishing cream and cold cream both are emulsions. Then, what is the difference between the two?

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Solution :Vanishing CREAM is an emulsion of oil-in-water WHEREAS cold cream is an emulsion of water-in oil. The latter is used for day skin as the base (dispersion MEDIUM) in this cream is oil.
16263.

What are non-essential amino acids ? Give two examples.

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Solution :Out of the 20 amino acids required for PROTEIN synthesis, human body can synthesize only 10. These 10 amino acids which, the body can synthesize are called non-ESSENTIAL amino acids e.g. valine and phenylalanine while the remaining ten which the human body cannot synthesize are called essential amino acids. These essential amino acids are required for the growth of the body and they must be supplied from outside in the human diet, e.g. glycine and CYSTEINE.
16264.

What is the unit of rate constant for a second order reaction ?

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SOLUTION :`MOL^(-1)` LITRE `SEC^(-1)`
16265.

When diliute sulphuric acid and hydrogen perioxide are added to a solution of chromate ions, an intense blue colour is produced which is stable in ether. This is due to the formation of :

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`Cr_(2)O_(3)`
`Cr_(2)O_(7)^(2-)`
`CrO_(3)`
`Cr_(2)O_(5)`

ANSWER :D
16266.

Which of the following is a semisyntheticpolymer ?

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silk
WOOL
Acetate rayon
cotton

ANSWER :C
16267.

Which of the following species is not expected to be a ligand?

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NO
`NH_(4)^(+)`
`NH_(2)CH_(2)CH_(2)NH_(2)`
CO

Solution :`NH_(4)^(+)` doesn't have LONE PAIR
16268.

Which of the following amines gives yellow oily liquid with HNO_(2)?

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Ethyl METHYL AMINE
Aniline
3-methyl benzyl amine
Methyl amine

Solution :Secondary amines , (containing -NH- group) when TREATED with `HNO_(2)` give nitrosamines which separate as yellow OILY liquids. The structures of the given compound are

Among the given compounds , only ethyl methyl amine is a secondary amine , thus it gives a yellow oily liquid with `HNO_(2)`.
16269.

Which of the following is a conjugated protein ?

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PHOSPHOPROTEIN
GLYCOPROTEIN
CHROMOPROTEIN
All of these

ANSWER :D
16270.

Which melts in boiling water ?

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GUN metal
Wood's metal
Monel metal
Bell metal

Answer :B
16271.

What volume of ammonia gas at S.T.P. will be required to be passed into 30 mL of 1 N H_(2)SO_(4) solution to bring down the acid normality to 0.2 N?

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Solution :Normality is the number of milliequivalents (MEQ) per mL
`"meq of 0.2 N "H_(2)SO_(4)" in 30 mL "=30xx0.2=6`
`therefore" meq of "H_(2)SO_(4)" REQUIRED to be beutralized by "NH_(3)=30-6=24`
`"But 1 mole of "NH_(3)="1 g eq, i.e. 1000 meq of "NH_(3)="22400 mL at S.T.P."`
`therefore"24 meq of "NH_(3)=(22400)/(1000)xx"24 mL =537.6 mL"`
16272.

Write the IUPAC name ofthe following coordination compound:[Mn(H_2O)_6]^(2+)

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SOLUTION :Hexa-aqua MANGANESE (II) ION
16273.

Which neuro messenger changes the mood of person?

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Isopronizide 
NORADRENALINE 
PHENELZIN 
LUMINAL 

SOLUTION :Noradrenaline
16274.

Which o,f the followingis used to increse pH?

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Ibuprofen
penicillin
`AI(OH)_(3)`
Veronal

Answer :C
16275.

whatvolumeof methane (NTP) is formedfrom16.4g ofsodiumacetanebyfucioonwithsodalime ?

Answer»


Solution :`{:(""CH_(3)COONa),([12+3+12+32+23]),(""82G):} +NaOHunderset("heat")overset(CaO)tounderset(22.4L )(CH_(4))+Na_(2)CO_(3)`
16276.

Which is correct about fuel cells :

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Cells continuously RUN as long as FUELS are supplied
These are more EFFICIENT and free from pollution
These are USED to provide power and drinking WATER to astronauts in space programme
All

Answer :D
16277.

Which of the following processes is used for the separation of colloidal particles from particles of molecular dimensions ?

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DIALYSIS
COAGULATION
PLASMOLYSIS
NONE of these

ANSWER :A
16278.

The valency of mercuric ion is:

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One
Two
Four
All

Answer :B
16279.

Which of the following acids doesnot exists in the free form?

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`H_2SO_2`
`H_2S_2O_3`
`H_2SO_3`
`H_2SO_4`

ANSWER :A
16280.

TiO_(2) is well known example of

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TRICLINIC SYSTEM
Tetragonal system
Monoclinic system
None

Answer :B
16281.

When phenol is treated with Conc. HNO_3 and conc. H_2SO_4,the product fornmed is …………………….. .

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SOLUTION :2, 4, 6 - trinitro phenol (or) PICRIC acid
16282.

The volume occupied by 0.25 mol of an ideal gas at S.T.P. is :

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89.6L
11.2L
5.6L
22.4L

Solution :Volume occupied by 1 MOL of gas at S.T.P. = 22.4 L
Volume occupied by 0.25 mol of gas at S.T.P.
`= 224. XX 0.25 = 5.6 L`
16283.

When a crystal of caustic soda is exposed to air, a liquid layer is deposited because:

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CRYSTAL melts
Crystal LOSS water
Crystal ABSORBS MOISTURE and `CO_2`
Crystal sublimes

Answer :C
16284.

What do we obtain when starch is boiled with dilute H_(2)SO_(4) at 393 K under pressure ?

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SOLUTION :GLUCOSE
16285.

Which does not acts as Bronsted acid

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`HSO_(3)^(-)`
`CH_(3)COO^(-)`
`HCO_(3)^(-)`
`NH_(4)^(+)`

ANSWER :B
16286.

Which correctly represents the physical significance of free energy change:

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`triangleG=W_expansion`
`triangleG=W_nonexpansion`
`triangleG=-W_Compression`
`triangleG=W_compression`

ANSWER :C
16287.

Vapour pressure of pure acetone and acetone and chlorofrom at 328 K are 632.8 mm Hg and 741.8 mm Hg respectively. Assuming that they from ideal solution over the entire renge of composition, plot_("Plotal, Pchloroform, and Pcetone") as a function of x_(acetone). The experimental date observed for diffiereant compositin of mixture is:

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Solution :Form the acailable infrmation:

The NATUE of the based upon the above DATE is as FOLLOWS:

Since the plot or GRAPH dips downward, the solution shows nagative DIVIATION form Raouot's Law.
16288.

Which of the following pairs of alcohols are distinguished by oxidation test, Lucas test and haloform test ?

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METHANOL and ethanol
Ethanol and 3-pentanol
Ethanol and 2-propanol
1-propanol and 3-pentanol

Answer :B
16289.

Which of the following compound is trisaccharide ?

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CELLOBIOSE
RAFFINOSE
Stachyose
Lactose

SOLUTION :Raffinose
16290.

Which of the following combination of orbitals is correct

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SOLUTION :It is a CORRECT COMBINATION
16291.

Which of the following chemical species is tetrahedral, diamagnetic as well as coloured ?

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`CrO_(4)^(2-)`
`MnO_(4)^(2-)`
`[NiCl_(4)]^(2-)`
`[NI(CN)_(4)]^(2-)`

ANSWER :A
16292.

Toluene on oxidation with acidified KMnO_(4) gives _______ .

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BENZOIC acid
salicylic acid
o-toluic acid
anthranilic acid

Answer :A
16293.

Which of these do not underg Wurtz reaction

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`C_(2)H_(5)F`
`C_(2)H_(5)Br`
`C_(2)H_(5)Cl`
`C_(2)H_(5)I`

SOLUTION :`C_(2)H_(5)F+2Na+FC_(2)H_(5) UNDERSET(ether)overset(dry)to`No reaction.
16294.

Which of the following represents the correct order?

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STABILITY : `overset+CH_3 lt CH_3 - overset+CH_2 lt CH_3 - overset+CHCH_3 lt (CH_3)_3overset+C`
Stability : `dotCH_3 lt CH_3-dotCH_2 lt CH_3 - DOT CH-CH_3 lt (CH_3)_3dotC`
Hyperconjugation : `CH_3 - lt CH_3 - CH_2- lt (CH_3)_2CH - lt (CH_3)_3C-`
Basic NATURE: `barCH_3 GT barNH_2 gt barOH gt barF`

ANSWER :A::B::C::D
16295.

Write the names of the monomers of the following polymers: [CF_2 - CF_2 ]_n

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SOLUTION :TETRAFLUOROETHENE `(CF_2=CF_2)`
16296.

Which of the following compound(s) decolourises Bromine water and also gives positive test with neutral FeCl_(3) solution?

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`CH_(2)=CH-OH`<BR>`CH_(2)=CH-CH_(2)OH`
`CH_(3)-CH=CH-OH`

Solution :`-CH_(2) = CH - OH` groups decolourise `Br_(2)` water. No reaction with NEUTRAL `FeCl_(3)`
16297.

Write IUPAC names of the following componds : (i) CH_(3)- underset(CH_(3))underset(|)overset(Cl)overset(|)C-CH_(3)"" (ii) CH_(3)- underset(Cl)underset(|)CH-CH_(3)

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SOLUTION :(1) 2-chloro-2-methylpropane.
(II) 2-chloropropane.
16298.

Zr and Hf have almost equal atomic size because….

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Of CHARACTERISTIC configuration
Of LANTHANOID contraction
Lattice enthalpy is high
Of ACTINOID contraction

Answer :B
16299.

Which transiton element shows the highest oxidation state:

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Fe
Mn
V
Cr

Answer :B
16300.

Which of the following is not an antipyretic?

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PARACETAMOL
Aspirin
Chloramphenicol
Phenacetin.

ANSWER :C