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23851.

Write the mechanism of the reaction of HI with methoxybenzene.

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SOLUTION :.
23852.

Which colloidal sol is not prepared by bredig's arc method ?

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Gold
Silver
IRON
Platinum 

SOLUTION :Iron
23853.

When an excess electrolyte is added to a colloidal sol it

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GETS COAGULATED
Is ionised
BECOMES stable
Gets PURIFIED

ANSWER :A
23854.

X mole of KCl and Y mole of BaCl_(2) are dissolved in 1kg of water. Given (x+y)=0.1 and K_(f)=1.85 "kmolal^(-1), what is the observed range of Delta T_(f) If the ratio of x to y is varied

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`0.37 to 0.55`
`0.185 to 0.93`
`0.56 to 0.93`
`0.37 to 0.93`

ANSWER :A
23855.

Which of the following has highest b.p.t ?

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`C_2H_5OH`
`CH_3COOH`
`CH_3COCH_3`
`HCOOCH_3`

ANSWER :B
23856.

Which of the following properties would you not expect copper to exhibit:

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Malleability
LOW THERMAL conductivity
Low electrical conductivity
Ductility

Solution :CU is GOOD conduction of HEAT and electricity due to metallic nature
23857.

Which of the following processes is accompanied by decrease in entropy ?

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EVAPORATION of water
Sublimation of DRY ice
Melting of ice
Condensing steam

Answer :D
23858.

Which bond is expected to be the least polar?

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`O-F`
`P-F`
`Si-N`
`B-F`

Solution :Bond POLARITY is directly related to difference of ELECTRONEGATIVITY of BONDED ATOMS.
23859.

Write IUPAC name ofproduct expected from reaction of sodium methoxide andiosbutyl bromide.

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2-Methoxybutane
2-Methoxy pentane
2-Methoxy propane
2-Methoxy hexane

Answer :A::B
23860.

Whichof the followingamineis mostbasicin nature ?

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2,4-dichloro ANILINE
2,4-dimethyl aniline
2,4-dinitro aniline
2,4- DIBROMO aniline

ANSWER :B
23861.

Which of the following solutions has the highest equivalent conductance at infinite dilution ?

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HCOOH
`CH_(3)COOH`
ph-COOH
HCl

Solution :Complete DISSOCIATION
23862.

What is the formula of chocolate coloured ppt ?

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`Fe_(4)[Fe(CN)_(6)]`
`Cu_(2)[Fe(CN)_(6)]`
`Cu_(4)[Fe(CN)_(6)]`
`Cu(CN)_(2)`

Solution :i`CuSO_(4) + BaCI_(2) rarr BaSO_(4) DARR + 2HCI`
`ii 2CuSO_(4)+4KI to 2K_(2)SO_(4)+underset("white ppt.")(CuI_(2)+I_(2)darr`
`I_(2)+2Na_(2)S_(2)O_(3)to 2NaI+Na_(2)S_(4)O_(6)`
`(iii) 2CU^(2+)+K_(4)[Fe(CN)_(6)]to underset("ppt.")underset("(chocolate)")underset("Red-brown")`
23863.

Which of the following cannot exist as Zwitter ion ?

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Glycine
Sulphanilic acid
p - AMINO BENZOIC acid
Alanine

SOLUTION :p - amino benzoic acid
23864.

Which one is the most reactive towards S_(N^(1)) reaction?

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`C_(6)H_(5)CH(C_(6)H_(5))BR`
`C_(6)H_(5)CH(Br)CH_(3)`
`C_(6)H_(5)C(CH_(3))(C_(6)H_(5))Br`
`C_(6)H_(5)CH_(2)Br`.

Solution :The compound is a tertiary alkyl HALIDE. It will form a tertiary carbocation which is most stable out of the three carbocations. No other compound WOULD yield a tertiary carbocation.
23865.

Which among the following is a acidic flux

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`SiO_(2)`
`MgCO_(3)`
`CaO_(3)`
`Fe_(2)O_(3)`

ANSWER :1
23866.

Which compound does not undergo hydrolysis?

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`SF_(6)`
`SF_(4)`
`SOCl_(2)`
`SO_(2)Cl_(2)`

Solution :`SF_(6)+H_(2)Orarrx`
DUE to steric FACTOR
23867.

Which of the following isomeric pairs shows ionisation isomerism ?

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`[Co(NH_(3))_(6)][Cr(CN)_(6)]` and `[Cr(NH_(3))_(6)][Co(CN)_(6)]`
`[Cr(H_(2)O)_(6)]Cl_(3) and [Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O`
`[Pt(NH_(3))_(2)Cl_(2)] and [Pt(NH_(3))_(4)] [PtCl_(4)]`
`[Co(NH_(3))_(5) Br] SO_(4) and [Co(NH_(3))_(5)SO_(4)]Br.`

Answer :D
23868.

Which out of the followingis//are transition elements //s and why ? Zn,Ag,Cd,Au.

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SOLUTION :Agand AU are TRANSITION elementsbecause they have INCOMPLETELY FILLED d-subshell.
23869.

Which one of the following plots is correct for a first order reaction?

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Solution :For a first ORDER REACTION, the graph between "LOG"(a - x) VS timw (t) gives a slope of `(-K)/2.3.3`
23870.

What is the difference when a concentrated solution of KCl is shaken with blood charcoal in one case and a dilute solution of KCl in the second case ?

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SOLUTION :With CONCENTRATED solution, there is POSITIVE ADSORPTION but with DILUTE solution, there is negative adsorption.
23871.

Which of thefollowingspeciesshowsthe maximummagneticmoment ?

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` MN^(6 +) `
` Ni^(2 +) `
`Fe^( 3+) `
` AG^(+) `

SOLUTION :
THUS,` Fe^ (3+ ) `will showmaximum magneticmoment.
23872.

When O_(2) is adsorbed on a metallic surface, electron transfer electron transfer occurs from the metal to O_(2). The TRUE statement (s) regarding this adsorption is (are)

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`O_(2)` is physisorbed
heat is released
occupancy of `pi_(2p)` of `O_(2)` is increased
bong LENGTH of `O_(2)` is increased

Answer :B::C::D
23873.

What happens when KMnO_4 is heated ?

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Solution :It CHANGES into `K_(2)MnO_(4),MnO_(2) and O_(2)`
`UNDERSET("DARK pink")(2KMnO_4) OVERSET(Delta)rarr underset("Green")(K_2MnO_4) + MnO_2 + O_2`
23874.

Which of the following is soluble in water ?(C Cl_4,C_6H_6,CH_3OH_,C_2H_6)

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SOLUTION :`CH_3OH`
23875.

Which has a giant covalent structure ?

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`PbO_2`
`SiO_2`
NACL
`AlCl_3`

ANSWER :B
23876.

Two centre three electron (2e, -3e^(-)), Bond is present in is present in :-

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NITRIC OXIDE
SUPEROXIDE
`CLO^(2)`
All of these

Solution :`N//A`
23877.

When vapours of an alcohol are passed over hot reduced copper, alcohol is converted into alkene, the alcohol is

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Primary
Secondary
Tertiary
None

Answer :C
23878.

The reactivity order of haildes for dehydro halogenation is:

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`RF gt RCL gt RBr gt RI`
`RI gt RBr gt RCl gt RF`
`RI gt RCl gt RBr gt RF`
`RF gt RI gt RBr gt RCl`

ANSWER :B
23879.

The reactivity of xenon is attributed to

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small atomic size of xenon
highest heat of vapourisation
lower ionisation POTENTIAL
higher RATIO of molar heat CAPACITIES

ANSWER :C
23880.

The reactivity order of alkyl halides depends upon :

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Nature of alkyl GROUP only
Nature of HALOGEN ATOM only
Nature of both alkyl group and halogen ATOMS
None

Answer :C
23881.

The reactivity of the compounds (i) MeBr (ii) PhCH_2Br (iii) MeCl (iv) p-MeOC_6H_4 Br decreases as

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(i)gt(II)gt(III)gt(IV)
(iv)gt(ii)gt(i)gt(iii)
(iv)gt(iii)gt(i)gt(ii)
(ii)gt(i)gt(iii)gt(iv)

Solution :Reactivity of HALO compounds.
23882.

The reactivityof hydrogenatomsattachedtocarbon atominan alkane hasthe order.

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TERTIARY GT PRIMARY gtsecondary
secondry gt primary gt tertiary
tertiary ?SECONDARY gt tertiary
primary gtsecodary gt tertiary

Answer :C
23883.

The reactivity of following compound in electrophilic substitution reaction is in the order of {:(1., C_(6)H_(5)-CH_(3), 3.,C_(6)H_(5)-Cl),(2.,C_(6)H_(5)-Br,4.,C_(6)H_(5)-NO_(2)):}

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`1 gt 2 gt 3 gt 4`
`4 gt 3 gt 2 gt 1`
`1 gt 4 gt 3 gt 2`
`1 gt 3 gt 2 gt 4`

ANSWER :D
23884.

The reactivity of hydrogen atom in an alkane towards substitution by bromine atom is

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`1^@H GT 2^@H gt 3^@H`
`1^@H lt 2^@H lt 3^@H`
`1^@H gt 2^@H lt 3^@H`
`1^@H lt 2^@H gt 3^@H`

Answer :B
23885.

The reactivity of halogen atom is minimum in

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PROPYL chloride
Propyl iodide
Isopropyl chloride
Isopropyl bromide

Answer :C
23886.

The reactivity of ethyl chloride is :

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More or less equal to that of BENZYL CHLORIDE
More than that of benzyl chloride
More or less equal to that of chlorobenzene
Less than that of chlorobenzene

ANSWER :2
23887.

The reactivity of compound Z with different hologebs under apppropriate conditions is give below: The observed pattern of electrophilic substitution cannot by explained by

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The steric effect of the halogen
The steric effect of the tert-butey`1` group
The electronic effect of the PHENOLIC group
The electronic effect of the tert-buty`1 group

Solution :
(I),(II) and (III) are probable positions as per electronic effect of `OH` group WHER electrophile can attack and due to steric HINDRANCE at (II) and (III) positions bulky electrophiles are not PREFERRED like I only preferred at position I, Bromine at positions `II`and `I` is while chlorine at all three positions.
23888.

The reactivity of copper is low because of its

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HIGH enthalphy of SUBLIMATION and LOW IONIZATION ENERGY
High enthalphy of sublimation and high ionization energy
Low enthalphy of sublimation and high ionization energy
Low enthalphy of sublimation and low ionization energy

Solution :Due to high sublimation and high ionization energy
23889.

The reactivity of carboxylic acid derivatives from highest reactivity to lowest reactivity is

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ACID anhydride `gt` acid CHLORIDE `gt` ESTER `gt` amide
acid chloride `gt` acid anhydride `gt` ester `gt` amide
acid anhydride `gt` ester `gt` amide `gt` acid chloride
amide `gt` ester `gt` acid anhydride `gt` acid chloride

Answer :B
23890.

The reactivity of alcohols with respect to oxidation decreases with

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INCREASE in `ALPHA`- H
decreases in `alpha`-H
increase in `BETA`- H
decrease in `beta` -H

Answer :B
23891.

The reactivity of acid derivatives in general follows the order: The above order of reactivity can be explained in terms of the: (i) Basicity of leaving group (ii) Resonance effect (iii) Inductive effect Weaker is the basic character of leaving group, more is the reactivity of acid derivative. In general, all the acid derivatives show resonance as follows: More is the stabilization, lesser is the reactivity and vice -versa. Acid derivatives although contain -Coverset(O)overset(||)C- group yet do not undergo the usual properties of carbonyl group. It is due to :

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INDUCTIVE EFFECT
resonance
ELECTROMERIC effect
all of these

ANSWER :B
23892.

The reactivity of acid derivatives in general follows the order: The above order of reactivity can be explained in terms of the: (i) Basicity of leaving group (ii) Resonance effect (iii) Inductive effect Weaker is the basic character of leaving group, more is the reactivity of acid derivative. In general, all the acid derivatives show resonance as follows: More is the stabilization, lesser is the reactivity and vice -versa. Which is the most reactive acid derivative?

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R-COCl
`(RCO)_(2)O`
RCOOR
`RCONH_(2)`

ANSWER :A
23893.

The reactivity of acid derivatives in general follows the order: The above order of reactivity can be explained in terms of the: (i) Basicity of leaving group (ii) Resonance effect (iii) Inductive effect Weaker is the basic character of leaving group, more is the reactivity of acid derivative. In general, all the acid derivatives show resonance as follows: More is the stabilization, lesser is the reactivity and vice -versa. Which among the following anions is the most basic ?

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`NH_(2)`
`barOR`
`R-CObarO`
`CL^(-)`

ANSWER :A
23894.

The reactivity of acid derivatives in general follows the order : The above order of reactivity can be explained in terms of the : (i) Basicity of leaving group (ii) Resonance effect (iii) Inductive effect Weaker is the basic character of leaving group, more is the reactivity of acid derivative. In general, all the acid derivatives show resonance as follows: More is the stablization, lesser is the reactivity and vice-versa. Acid derivatives although contain -overset(O)overset(||)C- group, yet do not undergo the usual properties of carbonyl group. It is due to

Answer»

INDUCTIVE effect
resonance
elemenric effect
all of these

ANSWER :B
23895.

The reactivity of acid derivatives in general follows the order : The above order of reactivity can be explained in terms of the : (i) Basicity of leaving group (ii) Resonance effect (iii) Inductive effect Weaker is the basic character of leaving group, more is the reactivity of acid derivative. In general, all the acid derivatives show resonance as follows: More is the stablization, lesser is the reactivity and vice-versa. Which of the following compounds will be most easily hydrolysed ?

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ACID HALIDE
Acid amide
Ester are non-volatile
Acid anhydride

Answer :A
23896.

The reactivity of acid derivatives in general follows the order : The above order of reactivity can be explained in terms of the : (i) Basicity of leaving group (ii) Resonance effect (iii) Inductive effect Weaker is the basic character of leaving group, more is the reactivity of acid derivative. In general, all the acid derivatives show resonance as follows: More is the stablization, lesser is the reactivity and vice-versa. Which of the most reactive acid derivative ?

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R-COCl
`(RCO)_(2)O`
RCOOR
`RCONH_(2)`

ANSWER :A
23897.

The reactivity of acid derivatives in general follows the order : The above order of reactivity can be explained in terms of the : (i) Basicity of leaving group (ii) Resonance effect (iii) Inductive effect Weaker is the basic character of leaving group, more is the reactivity of acid derivative. In general, all the acid derivatives show resonance as follows: More is the stablization, lesser is the reactivity and vice-versa. Which among the following anions is the most basic ?

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`vecNH_(2)`
`vecOR`
`R-COvecO`
`CL^(-)`

ANSWER :A
23898.

The reactivities of methyl chloride (A) propyl chloride (B) and chlorobenzene © are inthe order :

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`A GT B gt C`
`C gt B gt A`
`A gt C gt B`
`B gt A gt C`

ANSWER :A
23899.

The reactivities of acid halides (I), anhydrides (II),esters(III) and amides (IV) with nucleophilic reagents follow the order

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`IgtIIgtIIIgtIV`
`IVgtIIIgtIIgtI`
`IgtIIIgtIIgtIV`
`IIIgtIIgtIgtIV`

ANSWER :A
23900.

The reactive species in the nitration of benzene is

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`NO_(3)`
`NHO_(3)`
`NO_(2)^(+)`
`NO_(2)^(-)`

ANSWER :3