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6901.

What is corrosion? Give mechanism of rusting of iron.

Answer»

In the process of the rusting of iron:

The iron is the anode and is oxidized:

Fe → Fe2+ + 2e-

The reduction of oxygen occurs at the cathode:

O2 + 2H2O + 4e- → 4OH-

Electrons move from the anode to the cathode through the iron.

The anode and the cathode may be separated by some distance.

Insoluble iron (II) hydroxide is formed and the iron (II) ions are further oxidized to produce hydrated iron (III) oxide, or rust.

Corrosion is a natural process, which converts a refined metal to a more chemically-stable form, such as its oxide, hydroxide, or sulfide. It is the gradual destruction of materials by chemical and/or electrochemical reaction with their environment.

6902.

Give mechanism of cationic polymerization.

Answer»

MECHANISM OF CATIONIC POLYMERIZATION

Cationic polymerization is a type of chain growth polymerization in which a cationic initiator transfers a charge to a vinyl monomer which then becomes reactive. This reactive monomer goes on to react with other monomers to form a polymer. Let A be the catalyst, RH the co-catalyst and M the monomer, then the individual steps can be represented as follows:

A + RH ⇔ H+AR-

H+AR-+ M → HM+AR-

HMn+AR-+ M → HMn+1+AR-

HMn+AR-→ Mn+ H+AR-

HMn+AR-+ M → Mn+ HM+AR-

Both the initiation and termination reaction involves the transfer of a proton. Other cations may of course be transferred in some other cases.

In a homogenous system, the rate of initiation is usually proportional to the concentration of the catalyst complex and also to the concentration of the monomer. Its concentration is usually below one percent of that of the monomer. Often the chemical nature of the initiating catalyst and its concentration is unknown. For this reason, the rate of initiation is usually expressed in terms of the total concentration of either the catalyst or the co-catalyst, whichever is present in stoichioemetric deficiency. Calling this concentration [C], the rate of initiation can be written as ki[C] or ki[C] [M] depending on whether the initiation complex H+AR-is mostly converted to a reactive chain-growth monomer HM+AR-or not. The rate of initiation Riis then given by

Ri= ki[H+AR-] [M] = kiK [A] [RH] [M]

Herein is K the rate constant of the catalyst-cocatalyst complex formation and kiis the rate constant of the initiation step.

The termination rate should be of second order, that is, it should be proportional to the anion concentration [AR-] and the concentration of growing chains [M+]. However, it is of first order since the anion remains always in the vicinity of the growing chain center:

Rt= kt[M+]

Assuming steady state conditions, Ri= Rt, the rate of polymerization can be written as

Rp= kp[M+] [M] = (K ki/ kt) [A] [RH] [M]2

where [M+] is the concentration of all chain carriers ∑nHMn+AR-.

6903.

150or to prevent the spoilage of potato chips, they are packed in plastic bags inxosphere of4. O3. No2. Hz

Answer»

tq

They are packed in an atmosphere of N2 as it is an inert gas.

(3) nitrogen because it is unreactive

6904.

Why does styrene undergo anionic polymerization easily?

Answer»

These polymerizations are initiated by nucleophilic addition to the double bond of the monomer. This nucleophile can be an ion such as hydroxide, alkoxide, cyanide or a carbanion. The carbanion can originate from an organo-metallic species such as an alkyl lithium or Grignard reagent

6905.

why copper rod cannot be charged easily by friction

Answer»

The materials which are non-conducting in nature can be charged by friction easily. Copper which is a highly conducting material cannot be charged that easily.

6906.

what is type of charge on a glass rod and a silk cloth when they are rubbed with each other.

Answer»

a glass rod when rubbed against a silk cloth acquires a positive charge and silk cloth acquires negative charge

6907.

How many grams of Ag (atomic mass- 108) would beelectroplated on a spoon by electrolysis of AgNO3solution by passing one ampere current for 10 minutes?Ans. : 0.6715 gl12.

Answer»
6908.

Define a) diamagnetism b) space lattic

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a) Diamagnetic substances are those which have a tendency to move from stronger part to the weaker part of the externalmagnetic field. We can also say that the diamagnetic substances get repelled by a magnet.

b) The position of atoms, molecules, or ions in a solid crystal, relative to one other in space, is usually designated by points. Such a representation is calledspace lattice.Thus, we define thespace lattice as an array of points showing how molecules, atoms or ions are arranged at different sites in three-dimensional spaces

6909.

define vector

Answer»

In mathematics, physics, and engineering, a Euclidean vector is a geometric object that has magnitude and direction. Vectors can be added to other vectors according to vector algebra.

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6910.

(a) Hau36. For a reaction, Ag 20(s) 2Ags)+ O(g), the value of:ΔΗ 132 .6 kJ,AS-66 JK-1 mol-1The free energy change for the reaction will be zero atwhich of the temperature:(a) 2000K(c) 2023 K(BHU 1998)(b) 2009 K(d) 2029 K

Answer»

Hence, 132.6 * 10^3 / 66 = 2009

option (b)

6911.

aldol reaction

Answer»

Aldol' is an abbreviation ofaldehyde and alcohol. When the enolate of an aldehyde or a ketone reacts at the α-carbon with the carbonyl of another molecule under basic or acidic conditions to obtain β-hydroxy aldehyde or ketone, this reaction is called Aldol Reaction.

two acetaldehyde form enol form and after that form a mixture of aldehyde and alcohol so known as aldol condensation

6912.

L (CH),C-CHO does not undergo aldol condensation. Commentrinened grapes are crushed so tha

Answer»
6913.

4.DiluteNaOHLiAlH4300°CIn the above reaction Z is(1) aldol(3) acetol[KCET 2009(2) ketol(4) butanol

Answer»

Z is aldol

6914.

shot not of aldol condenstio

Answer»
6915.

moles of pds crse taken in a elosedcontoinez cohich dioviaes io ps + clzAccorcing to reaction derive one expresslommemain of roole in pels dliceodate in team-to eactiOn

Answer»
6916.

Total number of electrons in any energy level is-(Α) Σ2(21 + 1) (B) Σ2(2/+1) (c)Σ2(21+1)(D)Σ2(21 +1)-0

Answer»

option d is correct

see while calculating the value of l we go from 0 to n-1 and no. of orbitals in an subshell is given by(2l+1). and we know each orbital has 2 electons so 2(2l+1) and putting value of l between 0 to n-1

For a certain Value of n, L is always from 0 to n-1

and for each l , the number of electrons = 2(2l+1)

so, total is summation of 2(2l+1) for all L

option D

6917.

C,the expression forFor the system 3A +28-equilibrium constant is01.3A][2B](b)3A12B[CT(d) [d]3[B]2LA [B]c) [C

Answer»

Equilibrium for the expression would be: [C]/([A]³[B]³)

6918.

pe of element X has 12 neutrons and 11 protons which of the following shows the83. An isotocorect symbol of theion formed by x?23 +(D) x3.42 g of sucrose are dissolved in 18 g of water in a beaker. The number of oxygen atoms inthe solution are-(A) 668y1023(B) 6.09x10(C) 6.022 x 1023(D) 6.022x1021

Answer»

Molecular mass of sucrose=342 umolar mass = 342 ggiven mass =3.42 ggiven mass in terms of molar mass = 1/100 of molar massNo. of molecules in 1 mole =6.022*10^23No. of molecules in given mass = 1/100 * 6.022*10^23=6.022*10^21No.of oxygen atoms in 1 molecule of sucrose =11No.of oxygen atoms in 6.022*10^21 molecules =11*6.022*10^21=6.6242*10^22atomsNow,given water 18gmolecular mass of water = 18 ugiven water = 18g = 1 moleno.of oxygen atoms in 1 molecule of water = 1 No. of oxygen atoms in 6.022*10^23 molecules =1*6.022*10^23=6.022*10^23 atoms Total no. of oxygen atoms inthe solution =6.022*10^23+0.66242*10^23=6.68442*10^23 atoms

6919.

1 Explain the important aspect of resonance with reference to theCOğ ion.

Answer»
6920.

Name the two components of starch. How do they differ froally ?

Answer»

Starch is made up of 2 components that are:

Amylaseandamylopectin.

Amyloseandamylopectin.

6921.

१. म रा स त है? उदाहरण के साथ लिखें।16. स्तनपायी वर्ग के मुख्य लक्षणों को लिखें।17a2m2

Answer»

यह प्राणी जगत का एक समूह है, जो अपने नवजात को दूध पिलाते हैं जो इनकी (मादाओं के) स्तन ग्रंथियों से निकलता है। यह कशेरुकी होते हैं और इनकी विशेषताओं में इनके शरीर में बाल, कान के मध्य भाग में तीन हड्डियाँ तथा यह नियततापी प्राणी हैं। स्तनधारियों का आकार २९-३३ से.मी.

6922.

C Dancoho is Actor in The Movie(a) Sek

Answer»

The film was remade in 2006 as Don starring Shah Rukh Khan in the lead role of Don.

what about Mr.Bachchan

6923.

byWhat is galvanisation? What purpose is served by it?

Answer»

Galvanization or galvanizing is the process of applying a protective zinc coating to steel or iron, to prevent rusting. The most common method is hot-dip galvanizing, in which the parts are submerged in a bath of molten zinc.

what is purpose of it?

6924.

What is OS? Mention its purpose

Answer»

An operating system isthelevel of programming that lets you do things withyourcomputer.Theoperating system interacts withacomputer's hardware onabasic level, transmittingyourcommands into languagethehardware can interpret.The OSacts asaplatform for all other applications onyourmachine.

6925.

6. What is colloidal solution? Write any two properties of it

Answer»

A colloid is a mixture in which one substance of microscopically dispersed insoluble particles is suspended throughout another substance. Stability: Colloids are relatively stable in nature. The particles of the dispersed phase are in a state of continuous motion and remain suspended in the solution.

Filterability: Colloids require specialized filters known as ultrafilters for filtration. They readily pass through ordinary filter papers without yieldingany residue.

Heterogenous nature:Since colloids consist of two phases, the dispersed phase as well as the dispersion medium, they are known as heterogeneous in nature.

6926.

Write the two properties of carbon which lead to huge numberof Carbon Compounds.

Answer»

Thetwofeatures ofcarbonthat give rise to alarge numberofcompoundsare as follows: (i) Catenation − It is the ability to form bonds with other atoms ofcarbon. (ii) Tetravalency − With the valency of four,carbonis capable of bonding with four other atoms.

Great dude!

6927.

Why does carbon forms a huge number of compounds?

Answer»

Carbon forms huge number of compounds because of most important property of carbon that is catenation which means it has the capability to form large no. of bonds. which is further possible due to only 4 valence electrons and it's small size which avoid steric hindrance.

6928.

22. Give reasons.c (i) Aliquid flows, easily.un) Ice at 0°C appearsthan water at 0°CC appears colder in the mouth(i) Doctors advis a tothe forehead of aliv) We perspire monW) A wooden tablevisa to put strips of wet cloth onCad of a person having high feverspire more during summer.on table should be called a solid. (3)

Answer»

1.liquid can move easily because their particles can move over each other2. the latent heat absorbed by ice is more than water.3. because the water evaporates and absorb the heat of body4.due to effect of temperature in our body5.wooden table can be called as solid because it as a fixed shape and have strong force of attraction

6929.

10. Outline youu rolc as an active citizen in relation to sanitation.

Answer»
6930.

3. A gaseous mixture contains CHs and CHs in equimolecular proportion. The weight of 224 litres of this mitureNIP isA)46gB) 1.6gC)23 gD) 23 g

Answer»
6931.

(3) Say whether the following statements are True or False:The red colour used during Rang Panchami contains high proportionof lead.

Answer»

True Using the chemical-mixed colorsfor Holi andRang Panchamican cause and they contains solvents such as tetrathyline as well aslead.

6932.

41. IfAg and 位 be the threshold wavelength and the wavelength of incident light , the velocity of photoelectrons ejectedwill be:2hA) /(Ao-A)

Answer»
6933.

and terdary aiconoExplain why propanol has higher boiling point than that of the hybutane?luble in water than hydro

Answer»

Boiling pointis directly proportional to the intermolecular forces existing in a compound. Althoughbutaneandpropanol have comparable molecular masses (58 and 60 respectively) but, inpropanol, polar OH group is present, due to which strong intermolecular hydrogen bonding exists between its molecules.

thank u

6934.

s points. wvnyAmmonia has higher boiling point than phosphene. Why?3: Cu is colourless whereas Cu is blu

Answer»

AlthoughPH3is alargermolecule with greater dispersion forcesthanammonia,NH3 hasvery polar N-H bonds leading to strong hydrogen bonding. This the dominant intermolecular force and results ina greaterattraction betweenNH3moleculesthanthere is betweenPH3molecules..

reason is Hydrogen bonding.

6935.

: Noble gases have low boiling points, why?

Answer»

Being monoatomic is a crucial point to understand the melting and boiling points of noble gases. If the gas is monoatomic, that means the intermolecular forces will be extremely weak. So there is weak interaction between atoms of the noble gases, leaving a low boiling point for them.

6936.

1. Write the total number of periods in modern periodictable

Answer»

Periods. Horizontal rows of the periodic table of elements are the periods. There are seven such periods in the table, each numbered from 1 to 7.

6937.

15. Elements Z is in third period and group 17 of the Periodic Table.(i) It is a metal of non-metal ?(i) What is the number of valence electrons in its atom?(ii) What is its valency ?(iv) What is the name of the element ?

Answer»

i) Non-metalii) seven valence electrons, iii)valency = 1iv)Halogens

6938.

89. The elements A, B, C, D and E have atomic numbers 9, 11.17, 12 and 13 respectively.The pair of elements which belongs to the same group of the periodic table isi1. A and B 2. B and D3.A andC 4 . D and E

Answer»
6939.

eDatePagewhich Sodium Compound i'sused in soda- acid tiveextinguishers .ca Name the com(6) write one use which isnot in thisquestion.

Answer»

(a) Sodium bicarbonate(b) Sodium bicarbonate, also known as baking soda, is used to relieve heartburn, sour stomach, or acid indigestion.

6940.

Calculate the boiling point of a solution prepared by adding 15.0 g of NacI to 250,.0 gof water. (Kb for water -0.512 K kg mol-1, Molar mass of NaCI 58.44 g, AssumeNaCI undergoes complete dissociation)

Answer»

Moles of NaCl = 15/58.44

= 0.25 moles of NaCL

Kg of solvent = 250/1000 Kg

= 0.25 Kg of water

Therefore, Molality:

= 0.25/0.25

= 1 molal

For water change in BP:

ΔTb= Kb* m

= 0.52 * 1

= 0.52 K

Since water boils at 373.15 K at 1.013 bar pressure, therefore the boiling of solution will be 373.15+0.52 = 373.67 K

6941.

Name for group 2 elementsName for the group 17 elements

Answer»

Group 2 elements- alkaline earth metalsGroup 17 elements- halogens

6942.

induis 5) What is dry ice? What are the uses of dry ice?

Answer»

Ans :- Dry ice is the solid form of carbon dioxide. It is used primarily as a cooling agent. Its advantages include lower temperature than that of water ice and not leaving any residue. It is useful for preserving frozen foods where mechanical cooling is unavailable.

The most common use of dry ice is to preserve food, usingnon-cyclic refrigeration. It is frequently used to package items that must remain cold or frozen, such asice creamor biological samples, without the use of mechanical cooling.

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this question and answer is useful for me. thank you

6943.

Why should we wear cotton clothes in summer?

Answer»

because cotton clothes absorbs sweat we wear light colored cotton clothes because light colored clothes do not absorb more heat as compared to dark colored clothes

because they absorbes the wet and are Light

We wear cotton clothes in summer

Because cotton make sun ray decerease

we should wear a cotton clothes in summer because of mechanism of our body which keeps us cool and the heat energy equal to the lantern heat of vaporisation is absorbed from the body living the body cool

we wear cotton during summer because it doesn't absorb radiation of sun

6944.

Whatof clothes should we wear in summer?

Answer»

we should wear cotton clothes

In summer why should we wear cotton clothes

6945.

why should we wear cotton clotes in summer?

Answer»

in summer,we wear cotton clothes

6946.

Identify the type of vreaction:-2 Mg + O2 - 2090202 202 – 20202Pb (NO ), css heat 2PbO +4NO2 + O2In a cusoy unsog tevBackt Na 2504 - Bason I anade2 kalos cs) a akce +3022000 cs) hear 2018? Ozig2 KNO 3 , 2XN02est O2(g)

Answer»
6947.

23h at are the various ways in which a chemical equation can be made more informative? Give campto ustrate your answer.White balanced chemical equation from the following information:An aqueous calcium hydroxide solution (lime water) reacts with carbon diodde gas to produce a secalcium carbonate precipitate and water

Answer»
6948.

why frenkel defect occurs only in compounds with low coordination number and large difference between the sizes of ions

Answer»

Frenkel defects are exhibited in ionic solids with a large size difference between the anion and cation (with the cation usually smaller due to an increasedeffective nuclear charge)

but why is that so

6949.

"To pour water on calcium oxide." Which is another way to classify this reaction? Explairn.

Answer»

This is an example of combination reaction which is exothermicAs when water is added to calcium oxide it forms calcium hydroxide

6950.

What do you mean by Schottky defect ?Schottky defectIT?

Answer»

ASchottky defectis a type of pointdefectin a crystal lattice named after Walter H.Schottky. In non-ionic crystals itmeansa lattice vacancydefect. ... The surrounding atoms then move to fill these vacancies, causing new vacancies to form. Normally thesedefects willlead to a decrease in the density of the crystal.