

InterviewSolution
This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
401. |
In electrophilic substitution reaction nitrobenzene isA. Meta-directingB. Ortho-directingC. Para-directingD. Not reactive and does not undergo any substitution |
Answer» Correct Answer - C | |
402. |
The IUPAC name of the compoundA. 3,3-dimethyl -1- hydroxycyclohexaneB. 1,1 - dimethyl-3-cyclohexanolC. 3,3-dimethyl-1- cyclohexanolD. 1,1 - dimethyl -3- hydroxycyclohexane |
Answer» Correct Answer - C |
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403. |
The functional group present in anisole isA. ketoneB. aldehydeC. amineD. ether |
Answer» Correct Answer - D |
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404. |
Which of the following exhibit electromeric effect ?A. AlkanesB. AldehydesC. Alkyl halidesD. Alkyl amines |
Answer» Correct Answer - B | |
405. |
The correct IUPAC name `CH_(3)-underset(CH_(3))underset(|)(C)=underset(C_(2)H_(5))underset(|)(C)-CH_(3)`A. 1,2 -diethyl buteneB. 2 - ethyl -3- methyl penteneC. 3 , 4 - dimethyl hex -3- eneD. 2 , 3 - dimethyl pent -2- ene |
Answer» Correct Answer - D |
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406. |
The structure of isoprene isA. `CH_(3)-CH=C=CH_(2)`B. `CH_(2)=overset(CH_(3))overset(|)(C)-CH=CH_(2)`C. `HC-=C-overset(CH_(3))overset(|)(C)=CH_(2)`D. `CH_(2)=overset(CH_(3))overset(|)(C)-CH_(2)-CH=CH_(2)` |
Answer» Correct Answer - B |
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407. |
Which of the following species is not electrophilic in natureA. `overset(o+)(C)l`B. `BH_(3)`C. `H_(3)overset(o+)(O)`D. `overset(o+)(N)O_(2)` |
Answer» Correct Answer - C `Cl^(+)`, BH_(3), overset(o+)(N)O_(2)` are electron deficient. |
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408. |
Which will be MOST stable resonationg structure?(A) \(CH_2=CH-\overset\oplus CH-\overset\ominus CH-O-CH_3\)(B) \(\overset\ominus CH_2-\overset\oplus CH-CH=CH-OCH_3\)(C) \(\overset\ominus CH_2-CH=CH-CH=\overset\oplus O-CH_3\)(D) \(CH_2=CH-\overset\ominus CH-CH=\overset\oplus O-CH_3\) |
Answer» The structure having opposite charges on adjacent atoms are stable. structure having maximum number of covalent bonds is most stable. -OCH3 exerts -I and +M effect. +M effect of -OCH3 predominant over -I effect of -OCH3 and Also structure having complete octet are more state. In structure (iv) has complete octet and adjacent opposite charge. but in structure (i) has incomplete octet and -OCH3 group distablized adjacent anion. Therefore, structure (D) will be more stable resonating structure. Correct Answer - D |
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409. |
Point out the incorrect statement about resonance.A. Resonance structure should have equal energy.B. In resonance structures, the constituent atom should be in the same position.C. In resonance structure there should be the same number of electron pairs.D. Resonance structure should differ only in the location of electrons around the constituent atoms. |
Answer» Correct Answer - A | |
410. |
Which one of the following is most reactive towards electrophilic reagent ?A. B. C. D. |
Answer» Correct Answer - C `+R` effect of `OH gt OCH_(3)`. |
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411. |
Resonationg structures of molecules have :A. identical bondingB. different bondingC. identical arrangement of atoms and nearly same energiesD. the different number of paired and unpaired electrons |
Answer» Correct Answer - C | |
412. |
I.U.P.A.C name of ester isA. Alkoxy alkaneB. Alkyl alkanoateC. Alkanoyl halideD. Alkanoic anhydride |
Answer» Correct Answer - B |
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413. |
The only correct combination for benzyl cation is -A. (P) (ii), (II)B. (R) (iv) (IV)C. (S) (iv) (IV)D. Q (i) (II) |
Answer» Correct Answer - C | |
414. |
4 - methyl penta-1, 2- diene isA. `CH_(2)=CH(CH_(2))_(2)CH_(3)`B. `CH_(2)=CHCH(CH_(3))CH_(2)CH_(3)`C. `CH_(3)CH=C(CH_(3))CH=CH_(2)`D. `CH_(2)=C=CH-CH(CH_(3))_(2)` |
Answer» Correct Answer - D |
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415. |
Carbocations may be stabilised by :A. `pi`-bonds only at phenylic positionB. `pi`-bonds only at phenylic positionC. `pi`-bonds at allylic and benzylic position alsoD. `-I` effect |
Answer» Correct Answer - C Allylic and benzylic are stabuilised by resonance. |
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416. |
Consider the following benzyl alcohol : Correct order of their `K_(b)` value is :A. `IIIgtIVgtIIgtI`B. `IIIgtIgtIVgtII`C. `IltIIltIIIltIV`D. `IVgtIIgtIgtIII` |
Answer» Correct Answer - B | |
417. |
`3-`methyl pent`-1,3-`diene isA. `CH_(2) = CH(CH_(2))_(2)CH_(3)`B. `CH_(2)=CHCH(CH_(3))CH_(2)CH_(3)`C. `CH_(3)CH=C(CH_(3))CH=CH_(2)`D. `CH_(3)=C=CH(CH_(3))_(2)` |
Answer» Correct Answer - C |
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418. |
Among the following compounds, the strongest acid is :A. `CH-=CH`B. `C_(6)H_(6)`C. `C_(2)H_(6)`D. `CH_(3)OH` |
Answer» Correct Answer - D `CH_(3)OHhArrCH_(3)overset(Ɵ)O+H^(o+)` Since ,-ive charge is on electronegative oxygen. So, `CH_(3)OH` is most acidic. |
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419. |
Which of the following belongs to `+I` group ?A. `-OH`B. `-OCH_(3)`C. `-COOH`D. `-CH_(3)` |
Answer» Correct Answer - D `-CH_(3)` is electron donating group. |
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420. |
Give the correct order of increasing acidity of the following compounds. A. `IIltIltIVltIII`B. `IVltIIltIltIII`C. `IltIIltIVltIII`D. `IVltIltIIltIII` |
Answer» Correct Answer - B Carboxyllic acids are more acidic than phenol and alcohols. |
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421. |
The most stable diene is :A. B. C. D. |
Answer» Correct Answer - A All double bonds are trans to each other, no resonance in (d). |
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422. |
Which of following is the strongest `-I` group ?A. `-N^(+)(CH_(3))_(3)`B. `-^(+)NH_(3)`C. `-^(+)S(CH_(3))_(2)`D. `-F` |
Answer» Correct Answer - A | |
423. |
Which of the following is the strongest `-I` group :A. `-overset(+)N(CH_(3))_(3)`B. `-overset(+)NH_(3)`C. `-overset(+)S(CH_(3))_(2)`D. `-F` |
Answer» Correct Answer - A | |
424. |
Shifting of electron of a multiple bond under the influence of a reagent is called :A. I-effectB. M-effectC. E-effectD. T-effect |
Answer» Correct Answer - C | |
425. |
Acylium cation has two resonating sturctures (I) and (II), `R-underset(I)overset(o+)C=overset(* *)O:harrR-underset(II)C-=overset(o+)O:` Which statement is correct of (I) and (II)?A. (I) is more stable then (II)B. Stability of (II) is more than (I)C. Both have same stabilityD. None of these |
Answer» Correct Answer - B All atoms have complete octet structure in (II). |
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426. |
Which of the following is not correct ?A. A sigma bond is weaker than `pi` bondB. A sigma bond is stronger than `pi` bondC. A double bond is stronger than a single bondD. A double bond is shorter than a single bond |
Answer» Correct Answer - A | |
427. |
The length of the carbon-carbon single bond of the compounds (I)`CH_(2)=CH-C-=CH` (II) `CH-=C-C-=CH` (III) `CH_(3)-CH=CH_(2)` (IV) `CH_(2)=CH-CH=CH_(2)`A. `IIIgtIIgtIgtIV`B. `IgtIIIgtIIgtIV`C. `IIIgtIVgtIgtII`D. `IIgtIVgtIgtIII` |
Answer» Correct Answer - C | |
428. |
Which of the following is strongest `-m` groupA. `-SO_(3)H`B. `-COOH`C. `-NO_(2)`D. `-C-=N` |
Answer» Correct Answer - C | |
429. |
Which of the following involeves no displacement or shifting of electrons ?A. Zeeman effectB. Inductive effectC. ResonanceD. Electromeric effect |
Answer» Correct Answer - A | |
430. |
Consider the following three amines, (1) `CH_(3)CH_(2)-overset(* *)NH_(2)` (2)`CH_(2)=CH-overset(* *)NH_(2)` Arrange C-N bond length of these compounds in decreasing order :A. `1gt2gt3`B. `1gt3gt2`C. `3gt2gt1`D. `2gt3gt1` |
Answer» Correct Answer - A No resonance in (I). Due to resonance in (II) (-) bond get converted into (=) bond. More resonance in (III). |
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431. |
Which of the following pairs of structure are resonance structure? A. 1 and 4B. 2 and 3C. 1 and 2D. all of these |
Answer» Correct Answer - C 3 and 4 are tautomeric in sturcture. |
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432. |
Select the correct statement about the following reaction A. it can proceed via `S_(N)` 2 mechanismB. configuration about chiral carbon is retainedC. a racemic mixture is formedD. reaction is stereospecific |
Answer» Correct Answer - A The reaction can proceed through `S_(N)2` mechanism and it is stereospecific A reaction is stereospecific when a particular stereoissomeric form of the starting material reacts in such a way that it gives a stereoisomeric form of the product. |
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433. |
Arrange the following in increasing order of acidic strength I. `H_(2)SO_(4)` II. `(CH_(3))_(3)CH(SH)` III. `CH_(3)CH_(2)^(+)OH_(2)` IV. `CH_(3)CH_(2)CH_(3)`A. `IV lt II lt I lt III`B. `IV lt II lt III lt I`C. `IV lt I lt II lt III`D. `IV lt III lt II lt I` |
Answer» Correct Answer - A Acidic strength depends upon the tendency of a `molecule_(+)` to give a proton. Amond the given `CH_(3)CH_(2)OH_(2)` readily gives a proton so it is highly acidic `CH_(3)CH_(2)CH_(3)` has the least tendency to lose a proton, so its acidic strength is least among the given. thus the correct order of acidic strength is `IV lt II lt I lt III` |
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434. |
The major product obtained when `(Br_2)/(Fe)` is treated withA. B. C. D. |
Answer» Correct Answer - A The phenyl ring having `H-N lt` group is activated while another one is deactivated due to `-underset(O)underset(||)(C)-`, so electrophilic aromatic bromination will occur at para position with respect to `H - N lt` group inactivated ring. |
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435. |
The number of `pi` electrons present in phenanthreceneA. 10B. 14C. 12D. 16 |
Answer» Correct Answer - B |
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436. |
The IUPAC name of isA. but - 2 - ene - 2,3- diolB. pent - 2 - ene -2, 3- diolC. 2 - methyl but - 2 ene - 2,3 -diolD. hex - 2- ene -2, 3 -diol |
Answer» Correct Answer - B |
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437. |
The IUPAC name of the given structure A. 3 - cyano - 2 - carboxy benzaldehydeB. 2 - cyano - 6 - formyl benzoic acidC. 6 - cyano - 2 formyl benzoic acidD. 2 - formyl - 6 - cyano benzoic acid |
Answer» Correct Answer - B |
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438. |
The structure of spiro [3.3] heptane isA. B. C. D. |
Answer» Correct Answer - D |
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439. |
IUPAC name of the compound is `{:(CH_(3)-CH=C-CH_(3)),(" |"),(" "CH_(2)-CH_(3)):}`A. 2-ethyl-2-buteneB. 3-ethyl-2-buteneC. 3-methyl-3-penteneD. 3-methyl-2-pentene |
Answer» Correct Answer - D | |
440. |
IUPAC name of the following compound is A. 3-methyl cyclohex-1-eneB. 1- methyl cyclohex-2-eneC. 6-methyl cyclohexeneD. 1-methyl cyclohex-5-ene |
Answer» Correct Answer - A | |
441. |
The systematic name of `CH_(3)-CHBr - CH_(2)OH` isA. 3-hydroxy - 2-bromopropaneB. 2-bromopropanol-1C. 2-bromo-3-propanolD. 3-hydroxy isopropyl bromide |
Answer» Correct Answer - B | |
442. |
What is the IUPAC name of the following A. 6 - hydroxy cyclohex - 2 - ene - 1 - alB. 4 - hydroxy cyclohex - 1 - ene - 3 - alC. 2 - hydroxy cyclohex - 5 - ene carbaldehydeD. 1 - formyl cyclohex - 5 - enal |
Answer» Correct Answer - C ANSWER -: C) 2 - hydroxy cyclohex - 5 - ene carbaldehyde PRIORITY ORDER-: CHO > R-OH > ALKENE |
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443. |
Which of the following compounds have electron deficiency at ortho and para positions?A. B. C. D. |
Answer» Correct Answer - B::C::D `-NO_(2),-overset(O)overset(||)C-NH_(2),SO_(3)H` are electron withdrawing group |
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444. |
In which of the following molecules both phenyl rings are coplanar?A. B. C. D. |
Answer» Correct Answer - A::B::D c is nonplanar because of stearic hindrance at ortho position. |
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445. |
Find out correct statement regarding resonance energy :A. It is equal energy of resonance hybridB. It is equal to the difference in enregies of the most stable canonical structure and resonance hybridC. It is enerhy released by the moleculeD. It is rqual to the energy of least stable canonical structure |
Answer» Correct Answer - B::C | |
446. |
Which of the following would produce effervesence with sodium bicarbonate ?A. B. C. D. All of these |
Answer» Correct Answer - D All acids which are stronger than carbonic acid will produces effervesence with sodium bicarbonate |
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447. |
Select correct statement from the following:A. B. C. `HC-=CH` is more acidic than `NH_(3)`D. |
Answer» Correct Answer - C Self explanatory. |
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448. |
Correct order of acidic strength : A. `(iv) gt (i) gt (ii) gt (iii)`B. `(iv) gt (iii) gt (ii) gt (i)`C. `(iv) gt(ii) gt (iii) gt (i)`D. `(ii) gt (iv) gt (i) gt (iii)` |
Answer» Correct Answer - C An acid with weaker conjugatr base in stronger. |
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449. |
Which of the following is incorrect about the given molecules A. The correct order of basic strength `(K_(b))` is `a gt b gt c`B. The correct order of C-N bond length is `:a gt b gt c`C. The correct C=C bond length order is `a gt b gt c`D. The correct `pK_(b)` order is : `c gt b gt a` |
Answer» Correct Answer - C The polarity of N-H bond will be maximum on the N-atom which is most electron deficient. |
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450. |
Arrange the following compounds in order of decreasing acidity : A. `(i) gt (ii) gt (iii) gt(iv)`B. `(iii) gt (i) gt (ii) gt (iv)`C. `(iv) gt (iii) gt (i) gt (ii)`D. `(ii) gt (iv) gt(i) gt(iii)` |
Answer» Correct Answer - B Electron withdrawing group increase acidic strength and electron relasing group decrease acidic strength. |
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