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751.

Consider the following reaction The reactive intermediate invovled in this reaction isA. cArbanionB. CarbocationC. Free radical anionD. Free radical cation.

Answer» Correct Answer - C
752.

Assertion `:` Cyclohexane floats over water. Reason`:` Cyclohexane always has boat`-` like structure.A. If both assertion and reason are true and the reason is the correct explanation of the assertion.B. If both assertion and reason are true but reason is not the correct explanation of the assertion.C. If assertion is true but reason is false.D. If assertion is false but reason is true.

Answer» Correct Answer - c
Cyclohexane is higher than water and has boat as well as chair structures.
753.

Assertion: The melting and boiling point of alkanes are less compared with the inorganic compounds.Reason: the attractive forces in their molecules are quite weak.(a) A is correct, R is correct and R is a correct explanation of A.(b) A is not correct,R is correct and R is not a explanation for A.(c) Both A and R are wrong.(d) R is correct reason but A is wrong.

Answer»

(a) A is correct, R is correct and R is a correct explanation of A.

754.

What type of structural isomerism is shown by alkanes?

Answer»

Chain Isomerism.

755.

Assertion `:`Alkeanes having more than three carbon atoms exhibit chain isomerism. Reason `:` All carbon atoms in alkanes are `sp-`hybridizedA. If both assertion and reason are true and the reason is the correct explanation of the assertion.B. If both assertion and reason are true but reason is not the correct explanation of the assertion.C. If assertion is true but reason is false.D. If assertion is false but reason is true.

Answer» Correct Answer - c
Alkyanes have `sp^(3)` hybridized carbon
756.

Why are alkanes insoluble in water and readily soluble in organic solvents like chloroform or ether?

Answer»
  • The solubility of any substance is governed by the principle of like dissolves like. This means polar compounds are soluble in polar solvents while nonpolar compounds are soluble in nonpolar solvents.
  • Alkanes consist of C – C and C – H nonpolar covalent bonds and thus, they are nonpolar in nature, whereas water is a polar solvent.
  • The dipole-dipole forces that exist between water molecules is much stronger than the forces of attraction between alkane and water molecules.

Hence,

Alkanes are insoluble in water and readily soluble in organic solvents like chloroform or ether.

757.

Assertion: Alkanesare saturated hydrocarbons.Reason: saturated hydrocarbons are only formed by C-C single bond.(a) A is correct, R is correct and R is a correct explanation of A.(b) A is not correct,R is correct and R is not a explanation for A.(c) Both A and R are wrong.(d) R is correct reason but A is wrong.

Answer»

(a) A is correct, R is correct and R is a correct explanation of A.

758.

Acetylene can be obtained by the reactionA. `HCOOK overset(el ectrolysis)rarr`B. `CHI_(3)+6 Ag+CHI_(3) overset(Delta)rarr`C. `CH_(3)CH_(2)OHoverset(Conc. H_(2)SO_(4))underset(443^(@)C)rarr`D. `Be_(2)C+H_(2)O rarr`

Answer» Correct Answer - b
Acetylene can be obtained by the reaction of silver and chloroform `(` or iodoform `)`
`2CHl_(3)+6aGoverset(Delta)rarrunderset(acetyl en e)(C_(2)H_(2)+6Agl)`
759.

Why benzene is reluctant to show addition reaction?

Answer» Due to resonance benzene loses it pure double bond character redering it partial single bond character to double bond and double bond character to single bond. This causes for the reluctance of `pi`-electrons to participate in addition reactions Moreover addition reaction destroys the aromaticity of the benzene molecule.
760.

The ragent(s) required to convert 1-butyl to 2-butanone is (are)A. dilute `H_(2)SO_(4)`B. `ZnCl_(4)+HCl`C. `Hg^(2+)+H_(2)SO_(4)("dilute")`D. Alk. `KMnO_(4)`

Answer» Correct Answer - C
761.

Which is the weakes acid among the following?A. HClB. AcetyleneC. PhenolD. Picric acid

Answer» Correct Answer - B
762.

Propyne on passing through red hot copper tybe formsA. BenzeneB. ToulenceC. MesityleneD. None

Answer» Correct Answer - C
763.

An organic compound on treatment with `Br_(2)//C Cl_(4)`, gives a bromoderivative alkene. The compound will beA. `CH_(3)-CH=CH_(2)`B. `CH_(3)CH=CHCH_(3)`C. `HC=CH`D. `H_(2)C=CH_(2)`

Answer» Correct Answer - C
On adding `Br_(2)` acetylene gives 1,2-dibromoethaen-a bromoderivative of an alkene
`HC-=CH underset(C Cl_(4))overset(Br_(2))to BrCH=CHBr`
764.

Colouration of `Br_(2)//C Cl_(4)` will be discharged byA. B. C. D.

Answer» Correct Answer - A
765.

An organic compound on treatment with `Br_(2)//C Cl_(4)`, gives a bromoderivative alkene. The compound will beA. `CH_(3)CH=CH_(2)`B. `CH_(3)CH=CHCH_(3)`C. `HC-=CH`D. `CH_(2)=CH_(2)`

Answer» Correct Answer - C
`CH-=CH+Br_(2) overset(C Cl_(4))rarrunderset("Dibromoethylene")(BrCH=CHBr)`
766.

the ozonolysis product(s) of the following reaction is(are) `CH_(3)CH_(2)-C-=CH underset("(ii) "H_(2)O)overset((i)" "O_(3))to`product(s)A. `CH_(3)COCH_(3)`B. `CH_(3)COCH_(3)+HCHO`C. `CH_(3)COOH+HCOOH`D. `CH_(3)CH_(2)COOH+HCOOH`

Answer» Correct Answer - D
767.

Which of the following compounds are aromatic according to Huckel’s rule?

Answer»

A = Has 8π electrons, does not follow Huckel rule. Orbitals of one carbon atom are not in conjugation. It is not aromatic.

B = Has 6π delocalised electrons. Hence, is aromatic.

C = Has 6π electrons in conjugation but not in the ring. Non aromatic.

D = 10π electrons in planar rings, aromatic.

E = Out of 8π electrons it has delocalised 6π electrons in one six membered planar ring, which follows Huckel’s rule due to which it will be aromatic.

F = 14 π electrons are in conjugation and are present in a ring. Huckel’s rule is being followed. Compound will be aromatic if ring is planar.

768.

Markovnikov’s rule is applicable for ………….. (A) CH2 = CH2(B) CH3CH = CHCH3(C) CH3CH2CH = CHCH2CH3(D) (CH3)2C = CH2

Answer»

Correct option is: (D) \((CH_3 )_2 C = CH_2\)

Markovnikov’s rule is applicable for un symmetrical alkenes. 

Therefore, \((CH_3 )_2 C = CH_2\) can follow Markovnikov’s rule.

(D) (CH3)2C = CH2

769.

Wurtz reaction on a mixture of ethyl halide and isobutyl halide gives:A. Butane and isobutaneB. Butane and 2,5-dimethyl hexaneC. Butane,2,5-dimethylhexane and isohxaneD. Butane and isohexane

Answer» Correct Answer - C
`CH_(3)-CH_(2)-X+CH_(3)-underset(CH_(3))underset(|)(C)H-CH_(3)-Xunderset("Ether")overset(Na//dry)toCH_(3)-CH_(2)-CH_(2)-CH_(3)+CH_(3)-overset(CH_(3))overset(|)(C)H-CH_(2)-CH_(2)-overset(CH_(3))overset(|)(C)H-CH_(3)+CH_(3)-underset(CH_(3))underset(|)(C)H-CH_(2)-CH_(2)-CH_(3)`
770.

The products expected to be formed in the Wurtz reaction of a mixture of neopentyl bromide and isobutyl bromide are (i)2,2,4-trimethylpentane (ii)2,2,5,5-tetramethylhexane (iii)2,2,4,4-tetramethylhexane (iv)2,5-dimethyl hexane (v)2,2,5-trimethylhexaneA. (ii),(iii) and (v)B. (ii), (iv) and (v)C. (i),(iv) and (v)D. (i) , (iii) and (v)

Answer» Correct Answer - B
`underset"Neopentyl bromide (A)"(CH_3-undersetunderset(CH_3)|oversetoverset(CH_3)|C-CH_2Br)+underset"Isobutyl bromide (B)"(BrCH_2-oversetoverset(CH_3)|CH-CH_3)underset"(Wurtz reaction)"overset("Na/dry ether,"Delta)to underset"(Dimerization product of A)"underset"2,2,5,5-Tetramethylhexane (ii)"(CH_3-undersetunderset(CH_3)|oversetoverset(CH_3)|(.^2 C)-CH_2-CH_2-undersetunderset(CH_3)|oversetoverset(CH_3)|(.^5C)-CH_3)+underset"(Dimerization product of B)"underset"2,5-Dimethylhexane (iv)"(CH_3-oversetoverset(CH_3)|(.^2CH)-CH_2-CH_2-oversetoverset(CH_3)|(.^5CH)-CH_3)+underset"(Cross product of A and B)"underset"2,2,5-Trimethylhexane (v)"(CH_3-undersetunderset(CH_3)|oversetoverset(CH_3)|(.^2C)-CH_2-CH_2-oversetoverset(CH_3)|(.^5CH)-CH_3)`
771.

The total number of `p-` bond electrons in the following structure is A. 8B. 12C. 16D. 4

Answer» Correct Answer - a
No. of double bonds `=4` ltbr. No. of `p-` bond electrons `=2 xx `no. of double bond
`=2xx4=8.`
772.

In the reaction, `H-C-=C-H underset((ii)CH_3CH_2Br)overset((i)NaNH_2//liq. NH_3)to X underset((ii)CH_3CH_2Br) overset((i)NaNH_2//liq. NH_3)to Y` X and Y areA. X=2-butyne, Y=2-hexyneB. X=1-butyne, Y=2-hexyneC. X=1-butyne, Y=3-hexyneD. X=2-butyne, Y=3-hexyne

Answer» Correct Answer - C
`H-C-=C-H underset(-NH_3)overset(NaNH_3//liq. NH_3) to H-C-=C^(-)Na^+ underset(-NaBr)overset(CH_3CH_2Br)to underset"1-Butyne (X)"(H-C-=C-CH_2CH_3) underset(-NH_3)overset(NaNH_2 // liq. NH_3)to Na^+ .^-C-=C-CH_2CH_3 underset(-NaBr)overset(CH_3CH_2Br)to underset"3-Hexyne"(CH_3CH_2-C-=C-CH_2CH_3)`
773.

In the following questions a statement of assertion (A) followed by a statement of reason (R) is given. Choose the correct option out of the choices given below each question.Assertion (A) : Nitration of benzene with nitric acid requires the use of concentrated sulphuric acid.Reason (R) : The mixture of concentrated sulphuric acid and concentrated nitric acid produces the electrophile, NO2+ .(i) Both A and R are correct and R is the correct explanation of A.(ii) Both A and R are correct but R is not the correct explanation of A.(iii) Both A and R are not correct.(iv) A is not correct but R is correct.

Answer»

(i) Both A and R are correct and R is the correct explanation of A.

774.

Assertion (A): Nitration of benzene with nitric acid requires the use of concentrated sulphuric acid. Reason (R):The mixture of concentrated sulphuric acid and concentrated nitric acid produces the electrophile, `NO_2^+`.A. Both Assertion and Reason are correct and Reason is the correct explanation of Assertion.B. Both Assertion and Reason are correct but Reason is not the correct explanation of Assertion.C. Both Assertion and Reason are not correctD. Assertion is not correct but Reason is correct.

Answer» Both Assertion and Reason are correct and Reason is the correct explanation of Assertion.
775.

Statement-1: Ethyne is stronger acid than ethene. and Statement-2 Introduction of alkyl group activates benzene ring

Answer» Correct Answer - C
776.

Ethene can be separated from ethyne by passing the mixture throughA. concentrated `H_(2)SO_(4)`B. ammonical `Cu_(2)Cl_(2)`C. pyrogallolD. charcoal powder

Answer» Correct Answer - B
Ethene is less acidic than ethyne so it not react with `CH_(2)Cl_(2)` while ethyne reacts.
777.

Assertion `:` When double and triple bonds are in conjugation, addition takes place at triple bond. Reason`:` When double and triple bond are not in the conjugation, addition takes place at double bond.A. If both assertion and reason are true and the reason is the correct explanation of the assertion.B. If both assertion and reason are true but reason is not the correct explanation of the assertion.C. If assertion is true but reason is false.D. If assertion is false but reason is true.

Answer» Correct Answer - b
Conceptual `(` Stability of intermediate `)`
778.

Which of the following reagents cannot be used to locate the position of triple bond in `CH_(3)-C-=C-CH_(3)` ?A. `Br_(2)`B. `O_(3)`C. `Cu_(2)^(2+)`D. `KMnO_(4)`

Answer» Correct Answer - c
`CH_(3).C-=C.CH_(3)overset(Cu_(2)^(2+))rarr`No reaction
779.

In its reaction with silver nitrate acetylene showsA. Acidic propertyB. Reducting propertyC. Basic propertyD. Oxidisting property

Answer» Correct Answer - a
Acidic property because `H` atoms are replaced by silver metal atoms.
780.

Water can be added across a triple bond in the presence ofA. acidic mediumB. alkaline mediumC. neutral mediumD. acid and `HgSO_(4)`

Answer» Correct Answer - D
`H^(+)` ion forms cation because `H_(2)O` is too acidic.
781.

The compounds 1-butyne and 2-butyne can be distinguished by usingA. bromine waterB. `KMnO_(4)` solutionC. Tollens reagentD. chlorine gas

Answer» Correct Answer - C
`CH_(3)-CH_(2)-C-=CH`(I-butyne) have acidic hydrogen while 2-butyne not acidic.
782.

Acetylene reacts with `HCN` in the presence of `Ba(CN)_(2)` to yield `:`A. Viyny cyanideB. `1,1-`dicyanoethaneC. `1,2-`dicyanoetheneD. None

Answer» Correct Answer - a
`CH-=CH+HCNoverset(Ba(CN)_(2))rarrunderset("Vinyl cyanide")(CH_(2)=CH(CN))`
783.

Acetylene reacts with `HCN` in the presence of `Ba(CN)_(2)` to yield `:`A. `1,1-`dicyano ethaneB. Viny cyanideC. Ethyl cynideD. Divnyl cyanide

Answer» Correct Answer - b
`CH-= CH+HCN overset(Ba(CN)_(2))rarrunderset(Vi nyl cyan i d e )(CH_(2)=CH-C-=N`
784.

product formed by the oxidation of acetylene in the presence of alkaline `KMnO_(4)`.A. GlyoxalB. OxyraneC. `CO_(2)+H_(2)O`D. Oxalic acid

Answer» Correct Answer - D
785.

What is formed when calcium carbide reacts with heavy water?A. `C_(2)D_(2)`B. `CaD_(2)`C. `CaD_(2)O`D. `CD_(2)`

Answer» Correct Answer - A
`CaC_(2)+D_(2)O to CD-=CD+Ca(OD)_(2)`
786.

Acetylene on treating with HI gives-A. 1,1-DiiodoethaneB. EthyleneC. IodoethaneD. Ethane

Answer» Correct Answer - A
787.

Acetylene and ethylene react with alk `KMnO_(4)` to give-A. Oxalic acid and formic acidB. Acetic acid and ethylene glycolC. Ethyl alcohol and ethylene glycolD. None

Answer» Correct Answer - A
788.

Give one hydrocarbon which delcolourises alk KMnO4.

Answer»

Ethene (CH2 = CH2)

789.

What would be the product when ethene is oxidised with ozone and forms ozonide which is hydrolysed in the presence of Zn and acetic acid?A. `H-underset(O)underset(||)(C)-H`B. `CH_(3)OH`C. `H-underset(O)underset(||)(C)-OH`D. `H-underset(O)underset(||)(C)-underset(O)underset(||)(C)-H`

Answer» Correct Answer - A
790.

The unsaturation factor of

Answer» Correct Answer - 6
791.

How will you detect the presence of unsaturation in an organic compound?

Answer»

Either by Baeyer’s reagent or by Br2 in CCl4

792.

How will you detect the presence of unsaturation in an organic compound?

Answer»

Generally Unsaturated organic compound decolorize Bayer‘s reagent and Bromine water.

793.

How will you detect the presence of unsaturation in an organiccompound?

Answer»

Unsaturated organic compound decolorize the Brominewater.

794.

Give two chemical tests to detect unsaturation in organic compounds.

Answer»
  • Bromine test: When 5% solution of bromine in carbon tetrachloride is added to an alkene, it gets decolourized. This Indicate the presence of unsaturation in organic compound.
  • Bayer’s test: When alkene is oxidised with cold,. alkaline KMnO4, diol is formed. The KMnO4 gets decolourized. This indicates the presence of unsaturation of organic compound.
795.

In the reaction given below, `X` is `C_(6)H_(5)MgBr+CH_(3)OHrarrX`A. `C_(6)H_(6)`B. `C_(6)H_(5)OH`C. `C_(2)H_(5)OCH_(3)`D. `CH_(3)COOH`

Answer» Correct Answer - A
`C_(6)H_(5)MgBr+CH_(3)OH to C_(6)H_(6)+Mg-Br-OH`
796.

`CH_(3)-CH=CH_(2)overset((1) THF:BD_(3))underset((2) CH_(3)CO_(2)T)(to)(A)`, Product (A) of the above reaction is:A. `CH_(3)-CHD-CH_(2)D`B. `CH_(3)-CHT-CH_(2)T`C. `CH_(3)-CHD-CH_(2)T`D. `CH_(3)-CHT-CH_(2)D`

Answer» Correct Answer - c
Hydroboration -reduction take place.
`CH_(3)-CH=CH_(2)overset(THE BD_(3))to (CH_(3)-overset(D)overset(|)CH-CH_(2)-)_(3)Boverset(CH_(3)-CO_(2)T)toCH_(3)-overset(D)overset(|)CH-CH_(2)T`
797.

An organic compound `C_(4)H_(6)` on ozonolysis give `HCHO, CO_(2), CH_(3)CHO`. Compound will be:A. `H_(2)C=CH-CH=CH_(2)`B. `CH_(3)-CH=C=CH_(2)`C. `CH_(3)-C-=C-CH_(3)`D.

Answer» Correct Answer - b
Cumulative dienes.
798.

cis-2-butene`overset(HBr)underset("Peroxide")(to)`product, Product of the reaction is:A. RacemicB. DiastereomersC. MesoD. Pure enantiomers

Answer» Correct Answer - a
`CH_(3)-CH_(2)-underset(Br)underset(|)overset(**)CH-CH_(3)`
(racemic mixture)
799.

Addition of `BH_(3)` followed by `H_(2)O_(2)` to trans-2-butene would give a product which is:A. achiralB. racemicC. mesoD. Optically active

Answer» Correct Answer - b
Hydroboration -oxidation reaction is a syn- additon.
800.

Which of the following best describes the flow of electrons in the acid-catalyed dimerizantion of `(CH_(3))_(2)C=CH_(2)`?A. B. C. D.

Answer» Correct Answer - a
Carbocation formed will attcked by alkene.