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651.

An alekene X is obtained by dehydration of ann alcohol Y. X on ozonolysis gives two molecules of ethanal for every molecule of alkene. X and Y areA. X=3-hexene,Y=3-hexanolB. X=2-butene, Y=2-butanolC. X=1-butene, Y=1-butanolD. X=1-hexane, Y=1-hexanol

Answer» Correct Answer - B
Products of ozonolysis:
`CH_(3)-overset(H)overset(|)(C)=O+O=overset(H)overset(|)(C)-CH_(3) to underset("2-Butene")(CH_(3)CH=CHCH_(3))`
2-butene is obtained by dehydration of 2-butanol.
`CH_(3)-CH_(2)-underset(OH)underset(|)(C)H-CH_(3)overset(H^(+))to CH_(3)-CH=CH-CH_(3)+H_(2)O`
652.

Correct order of reactivity towards electrophilic additon reactions is :A. `CH_(2)=CH_(2)gtCH_(3)-CH=CH_(2)gt(CH_(3))_(2)C=CH_(2)`B. `CH_(2)=CH_(2)gtCH_(3)-CH=CH_(2)lt(CH_(3))_(2)C=CH_(2)`C. `CH_(2)=CH_(2)lt(CH_(3))-_(2)C=CH_(2)lt(CH_(3))-CH=CH_(2)`D. `CH_(3)-CH=(CH_(2))ltC=CH_(2)=(CH_(2))-lt(CH_(3))_(2)C=CH_(2)`

Answer» Correct Answer - B
As stability of cation increases rate of electrophilic additon reaction increases
653.

Acidic hydrogen is present in :a. acetylene b. ethane c. ethylene d. dimethyl acetylene

Answer»

Option : a. acetylene

654.

Among the following , the compound which has highest boiling point is:A. B. C. D.

Answer» Correct Answer - C
Compound contain 6 carbon
655.

Which has least carbon bond length-A. EthaneB. EthyneC. EtheneD. Ethanol

Answer» Correct Answer - B
If S-Character increases bond length decreases.
656.

Which of the following compound has the highest boiling point? a. n-pentane b. iso-butane c. butane d. neopentane

Answer»

Option : a. n-pentane

657.

When an alkyne `RC-=CH` is treated with cuprous ion in an ammoniacal medium one of the products isA. `RC-=C Cu`B. `CuC-=CH`C. `CuC-=C Cu`D. `RC-=CR`

Answer» Correct Answer - A
`RC -= CH overset(Cu^(+)//NH_(4)OH)rarrRC-=C Cu`
658.

Alkanes are readily attacked by-A. ElectrophilesB. NucleophilesC. Free RadicalsD. Bases

Answer» Correct Answer - C
In alkane non-polarize bond is present so it can usually cleaved by free radical.
659.

The compound with the highest boiling point is:A. n-hexaneB. n-pentaneC. 2,2-dimethyl propaneD. 2-methyl butane

Answer» Correct Answer - A
B.P. `prop` molecular weight
660.

A mixture of `CH_(4),C_(2)H_(4)` and `C_(2)H_(2)` gases are passed through a Wolf bottle containing ammoniacla cuprous chloride. The ga coming out isA. MethaneB. AcetyleneC. Mixture of methane and ethyleneD. Original mixture

Answer» Correct Answer - c
`C_(2)H_(2)` reacts with ammoniacla cuprous chloride due to acidic nature of acetylene.
So the gas coming out is mixture of methane and ethylene.
661.

Isopropyl bromide undergoes wurtz reaction to form-A. HexaneB. 2,3-Dimethyl butaneC. Propane+Ethane+Butane+Ethene+`CH_(4)`D. n-butane

Answer» Correct Answer - B
`CHMe_(2)-Br+2Na+Br-CHMe_(2)+Br-CHMe_(2)("dry")/("Ether")Me_(2)CH-CHMe_(2)+2NaBr`
662.

Which of the following will have least hindered rotation about carbon-carbon bond?A. EthaneB. EthyleneC. AcetyleneD. Hexachloroethane

Answer» Correct Answer - A
single bond can easily be rotated
663.

The highest boiling point is expected for:A. isooctaneB. n-octaneC. 2,2,3,3-tetramethylbutaneD. n-butane

Answer» Correct Answer - B
`B.P.prop"surface area"prop(1)/("Branching")`
664.

Highest boiling point is expected forA. 2,2-dimethyl butaneB. 3-methyl pentaneC. 2-methyl pentaneD.

Answer» Correct Answer - D
665.

Conversion of cyclohexene to cyclohexanol can be conveniently achieved by:A. `NaOH + H_(2)O`B. `Br_(2) - H_(2)O`C. hydroboration, oxidationD. hydroboration hydrolysis

Answer» Correct Answer - c
Hydroboration -oxidation reaction.
666.

Cyclohexene is best prepared from cyclohexanol by which of the followingA. conc. `H_3PO_4`B. conc. HCl/`ZnCl_2`C. conc. HClD. conc. HBr

Answer» Correct Answer - A
The acid used must have a non-nucleophilic anion. Since `Cl^-` and `Br^-`ions are good nucleophiles, therefore, HCl and HBr will give their corresponding halides , therefore, `H_3PO_4` is the correct option.
667.

Many organic compounds obtained from natural sources such as resins, balsams, oil of wintergreen, etc. have pleasant fragrance or aroma. Such compounds are named as aromatic compounds. i. Name the simplest aromatic compound. ii. Write the names of any two aromatic compounds.

Answer»

i. Benzene is the simplest aromatic hydrocarbon. 

ii. Toluene and naphthalene

668.

Identify the product in the reaction `PhC -=Cme overset(H_3O^(+), Hg^(2+)) to ` ?A. `PhCH_2CH_2CHO`B. `PhCOCH_2CH_3`C. `PhCH_2COCH_3`D. PhCOCOMe

Answer» Correct Answer - B
669.

How many e-s are here in Benzene Ring?

Answer»

Benzene Ring is 6 e-s

670.

Which one is more stable structure of benzene among Kekule and Dewar’s structures?

Answer» Kekule’s structure.
671.

Give two limitations of Kekule structure.

Answer»

1. Fails to explain unusual stability of benzene

2. Fails to explain preference to substitution reactions than addition reactions. 

672.

, Product (Q) is:A. B. C. `CH_(3)-overset(O)overset(||)(C)-O Me`D.

Answer» Correct Answer - b
`Br-CH_(2)-overset(O)overset(||)C-Cl(P)overset(CH_(3)OH)toBr -CH_(2)-overset(O)overset(||)C-O-CH_(3)`
673.

The boiling point of alkanes shows a steady increase with increase in molecular mass. Why?

Answer»

This is due to the fact that the intermolecular van der walls forces increase with increase of the molecular size or the surface area of the molecule.

674.

A concentrated solution of sodium butyrate is electrolysed in suitable apparatus. The product at the anode isA. ButaneB. PropaneC. HexaneD. Pentane

Answer» Correct Answer - C
`2CH_(3)CH_(2)CH_(2)-COO^(-) overset("Anode")`
`2CH_(3)CH_(2)CH_(2)COO to 2CO_(2)+2CH_(2)CH_(2)CH_(3) to CH_(3)CH_(2)-CH_(2)CH_(2)CH_(3)`
675.

Which of the following is an example of nucleophilic addition reactionA. `CH-=CH+H_(2) overset(Pd//BaSO_(4).S)to CH_(2)=CH_(2)`B. `CH-=CH+H_(2)O overset(Hg^(2+)//H_(+))to CH_(3)CHO`C. `CH-=CH+H_(2)O to CH_(2)-CHBr_(2)`D. `CH-=CH+CH_(3)COOH overset((CH_(3)COO)_(2)Mg)to CH_(3)-CH(OOC CH_(3))_(2)`

Answer» Correct Answer - B,D
Addition of water and acetic acid to acetylene are examples of nucleophilic addition reactions. Addition of `H_(2)(Pd//BaSO_(2)-S)` and HBr to acetylene are example of electolphilic addition reactions.
676.

All the four C-H bonds in methane are identical. Give reasons.

Answer»

The four C-H bonds of methane are identical because all of these are formed by the overlapping of the same type of orbital’s i.e; hybrid orbital’s of carbon and s-orbital of hydrogen.

677.

Explain the physical properties of benzene and its homologues.

Answer»

i. Benzene and its homologous upto eight carbon atoms are colourless liquids with characteristic smell.

ii. Aromatic hydrocarbons are immiscible with water but soluble in organic solvents.

iii. They are inflammable and burn with sooty flame.

iv. The melting and boiling points of aromatic compounds increases with increase in molecular mass due to increase in van der waals forces.

678.

Enlist physical properties of benzene.

Answer»

Physical properties of benzene:

  • Benzene is a colourless liquid. 
  • Its boiling point is 353 K and melting point is 278.5 K. 
  • It is insoluble in water. It forms upper layer when mixed with water. 
  • It is soluble in alcohol, ether and chloroform. 
  • Its vapours are highly toxic which on inhalation lead to unconsciousness.
679.

Which of the following is most acidic?A. MethaneB. EthaneC. EthyleneD. Acetylene

Answer» Correct Answer - D
Acidic strength `prop` stability of conjugate base.
`CH-=underset(SP-C)underset(darr)overset(ɵ)(CH)gt CH_(2)=underset(SP^(2)-C)underset(darr)overset(ɵ)(CH_(2))gtoverset(ɵ)(CH_(3))gtCH_(3)-overset(ɵ)(CH_(2))` (stability order)
680.

Ethylene reacts with 1% cold alkaline `KMnO_(4)` to formA. Oxalic acidB. Ethylene glycolC. Ethyl alcoholD. HCHO

Answer» Correct Answer - B
681.

Which of the following reactions takes place when a mixture of concentrated `HNO_(3)` and `H_(2)SO_(4)` reacts on benzene at `350K` ?A. SulphonationB. NitrationC. HydrohalogenationD. Dehydration

Answer» Correct Answer - b
b
682.

1-Butyne reacts with cold alkaline `KMnO_(4)` to produceA. `CH_(3)CH_(2)COOH`B. `CH_(3)CH_(2)CH_(2)COOH`C. `CH_(3)CH_(2)COOH+CO_(2)`D. `CH_(3)CH_(2)COOH+HCOOH`

Answer» Correct Answer - C
`CH_(3)-CH_(2)-C-=Choverset(KMnO_(4))toCH_(3)-CH_(2)-C-COOH+underset(H_(2)O+CO_(2))underset(darr)(HCOOH)("ustable")`
683.

Which of the following reactions can be used to prepare an alkane from an alkyl halide ?A. Wurtz reactionB. Kobe electrolysisC. Hoffmann reactionD. Fitting reaction

Answer» Correct Answer - a
a
684.

1-Butyne reacts with hot alkaline `KMnO_4` to produceA. `CH_3CH_2CH_2COOH`B. `CH_3CH_2COOH`C. `CH_3CH_2COOH+CO_2`D. `CH_3CH_2COOH + HCOOH`

Answer» Correct Answer - C
Terminal alkynes on oxidation give a mixture of `CO_2` and a carboxylic acid with one C-atom less than that of the starting alkyne.
685.

For an electrophilic substitution reaction , the presence of a halogen atom in the benzene ring …..A. deactivates the ring by inductive effectB. deactivates the ring by resonanceC. increases the charge density at ortho and para position relative to meta position by resonanceD. directs the incoming electrophile to meta position by increasing the charge density relative to ortho and para position.

Answer» Correct Answer - A::C
Statements (a) , (c ) are correct but (b ) and (d) are incorrect .
686.

Ozonolysis of an organic compound gives formaldehyde as one of the products. This confirms the presence ofA. a vinyl groupB. an isopropyl groupC. an acetylenic triple bondD. two ethylenic double bonds.

Answer» Correct Answer - A
Presence of vinyl group is alkene is indicated when it gives formaldehyde on ozonolysis
687.

Why is cyclopropane more reactive than propane?

Answer»

In cyclopropane, bond angle is 60° which is much less compared to the normal tetrahedral bond angle of 109.5° for sp3 hybridsed carbon. Therefore, the molecule is very much strained and hence reactive.

688.

The compound which produces propane on heating with HI in presence of phosphorys isA. `CH_(3)CH_(2)CHI`B. `CH_(3)CH_(2)CHO`C. `CH_(3)CH_(2)CH_(2)OH`D. All of these

Answer» Correct Answer - D
`CH_(3)CH_(2)CH_(2)I+HI overset("Red P")to CH_(3)CH_(2)CH_(3)+I_(2)`
`CH_(3)CH_(2)CH_(3)OH+2HI overset("red P")to CH_(3)CH_(2)CH_(3)+I_(2)+H_(2)O`
`CH_(3)CH_(2)CHO+4HI underset(423K)overset("red P")to CH_(3)CH_(2)CH_(3)+2I_(2)+H_(2)O`
689.

Which of the following on treatment with Zn/Cu couple produces propane?A. PropanalB. Isopropyl bromineC. Isopropyl amineD. Isopropyl alcohol

Answer» Correct Answer - B
`CH_(3)overset(Br)overset(|)(CHCH_(3)) underset(C_(2)H_(5)OH -HBr)overset(Zn-Cu)toH_(3)C-CH_(2)-CH_(3)`
690.

propene `+HOCltoAto` Final product. In the above reaction A will be:A. `CH_(3)-underset(OH)underset(|)overset(H)overset(|)(C)-overline(C)-H`B. `CH_(3)-overset(H)overset(|)(underline(C))-underset(Cl)underset(|)overset(H)overset(|)(C)-H`C. `CH_(3)-overset(H)overset(|)(underline(C))-underset(OH)underset(|)overset(H)overset(|)(C)-H`D. `CH_(3)-underset(OH)underset(|)overset(H)overset(|)(C)-overlineunderset(H)underset(|)(C)-H`

Answer» Correct Answer - D
691.

Propene on reaction with methylene iodide in presence of Zn-Cu couple gives:A. CyclopropaneB. CyclopropaneC. Methyl CyclopropaneD. Cyclobutene

Answer» Correct Answer - C
692.

When water vapours are passsedover aluminium carbide , we get `:`A. (a) acetaldehydeB. (b) ethyleneC. (c) methaneD. (d) methyl alcohol

Answer» Correct Answer - c
c
693.

Give the IUPAC name of an isomer of hexane which has only two different sets of structurally equivalent hydrogen atoms.

Answer» `underset"2,3-Dimethylbutane"(CH_3-undersetunderset(CH_3)|CH-undersetunderset(CH_3)|CH-CH_3)`
It has 12 equivalent `1^@` hydrogens and 2 equivalent `3^@` hydrogens.
694.

Which among the following is expected to have the hightest boiling point?A. 2-MethylpropaneB. n-HexaneC. 2-MethylpentaneD. 2,2-Dimethylbutane

Answer» Correct Answer - B
695.

How many σ C-C, σ C-H, & π bonds are present in benzene? 

Answer»

3C-Cσ , 6C-Hσ & 3π bonds. 

696.

Assertion: Among the isomeric alkanes, the branched chain isomers have lower boiling point than the straight chain isomers.Reason: With branching of chain surface area decreases and the vander waal forces of attraction which depend upon surface area also tend to decreases.(a) A is correct, R is correct and R is a correct explanation of A.(b) A is not correct,R is correct and R is not a explanation for A.(c) Both A and R are wrong.(d) R is correct reason but A is wrong.

Answer»

(a) A is correct, R is correct and R is a correct explanation of A.

697.

Give reason for the following:Straight chain alkanes possess higher boiling points than the corresponding branched chain isomers.

Answer»

Due to lower surface area, therefore strong vander waal’s forces of attraction.

698.

A is:A. B. C. D.

Answer» Correct Answer - C
Addition of `H_(2)O` according to Markovnikov Rule.
699.

Match the followingList - IList -II(No. of carbon atoms)(Major uses)A. 1-4(1) Paraffin waxB. 5-7(2) Gasoline onlyC. 6-12(3) SolventsD. 50+(4) Cooking fuelCode :ABCD(a)1234(b)2341(c)4321(d)3214

Answer»
ABCD
(c)4321

700.

Statement – I : Boiling point of methane is lower than that of butane. Statement – II : The boiling point of continuous chain alkanes increases with increase in length of carbon chain. (a) Statement – I and II are correct and statement – II is correct explanation of statement – I (b) Statement – I and II are correct but statement – II is not correct explanation of statement -I (c) Statement – I is correct but statement – II is wrong. (d) Statement – I is wrong but statement – I is correct.

Answer»

(a) Statement – I and II are correct and statement – II is correct explanation of statement -I