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51.

Arrange the following elements as per the guidelines in brackets. (1) Na,Cl; Mg, P [in decreasing order of atomic size] (2) C,Li,F,N [in increasing order of electronegativity] [in increasing order of ionisation potential] (3) Cl,Al.Na,S [in increasing order of electron affinity] (4) Ar,He,Ne [in increasing order of number of electron shells]

Answer»

1. Na, Mg, P, Cl 

2. Li, C, N, F 

3. Na, Al, S, Cl 

4. F, O, C, Li 

5. He, Ne, Ar

52.

Arrange the following as per the instructions given in the brackets: (1) Cs, Na, Li, K, Rb (increasing order of metallic character). (2) Mg, Cl, Na, S, Si (decreasing order of atomic size). (3) Na, K, Cl, S, Si (increasing order ionization energy) (4) Cl, F, Br, I (increasing order of electron affinity)

Answer»

1. Li < Na < K < Rb < Cs 

2. Na > Mg > Si > S > Cl 

3. K < Na < Si < S < Cl . 

4. I < Br < F < Cl

53.

Arrange the following as per the instruction in-the brackets – (1) He, Ar, Ne [Increasing order of the number of electron shells]. (2) Na, Li, K [Increasing ionisation energy]. (3) F, Cl, Br [Increasing electronegativity]. (4) Na, K, Li [Increasing atomic size].

Answer»

1. He, ne, Ar (increasing number of electron shells) 

2. K, Na, Li (increasing ionisation energy) 

3. Br, Cl, F (increasing electronegativity) 

4. Li, Na, K (increasing atomic size)

54.

State the group and the period of the element having three shells with three electrons in valence shell.

Answer»

If three shells → element belongs to third period. 

If three valence electrons → element belongs to 13 group.

55.

Identify the term in each of the following: (1) The tendency of an atom to attract electrons to itself when combined in a compound. (2) The electrons present in the outermost shell of an atom. 

Answer»

(1) Electro negativity 

(2) Valence electrons

56.

Complete the table   Element Atomic number Electronic  configuration Group  number Period  number Lithium 3 2,1 1 2 Oxygen 8 2,3 ..... 2 Argon 18  ..... ..... 3 Calcium ..... 2,8,8,2 2 4

Answer»
   Element Atomic number Electronic  configuration Group  number Period  number
 Lithium 3 2,1 1 2
 Oxygen 8 2,3 16 2
 Argon 18  2,8,8 16 3
 Calcium 20 2,8,8,2 2 4
57.

An element X belong to 3rd periods and group II of the periodic table state:(a) the number of valence electrons,(b) the valency,(c) name of the element,(d) whether it is a metal or a non-metal.

Answer»

(a) Since it belongs to period 3 it has 3 shells, K, L and M. The outermost M shell will have 2 valence electrons as it is placed in group II

(b) With 2 valence electrons, its valency will be 2.

(c) Since it has electronic configuration of 2, 8, 2, its atomic number is 12 and hence X is Magnesium

(d) It is a metal.

58.

How does the electronic configuration in atoms change.(i) in a period from left to right?(ii) in a group top to bottom?

Answer»

(i) Though the number of shells remain the same, number of valence electrons increases by one, as we move across any given period  from left to right.

(ii) While going from top to bottom in a group, the number of shells increases successively i.e. one by one but the number of valence electrons remains the same.

59.

Correct the statements.(i) Elements in the same periods have equal valency.(ii) Valency depends upon the number of shells in an atom.(iii) Copper and zinc are representative elements.(iv) Transition elements are placed at extreme right of the periodic table.

Answer»

(i) Elements in the same group have equal valency.

(ii) Valency depends upon the number of valence electrons in an atom.

(iii) Copper and zinc are transition elements.

(iv) Noble gases are placed at the extreme right of the periodic table.

60.

Why are noble gases placed in a separate group?

Answer»

Noble gases are unreactive since they have their outermost orbit complete. Due to stable electronic configuration they hardly react with other elements. So these elements are placed in a separate group i.e.18

61.

Explain why are the following statements not correct:(a) All groups contain metals and non metals.(b) Atoms of elements in the same group have the same number of electron(s)(c) Non- metallic character decreases across a period with increase in atomic number(d) Reactivity increases with atomic number in a group as well as in a period.

Answer»

(a) Since the elements in a group have same number of valence electrons, they can either contain metals or non-metals like alkali and alkaline metals have only metals whereas halogens are non-metals.

(b) No two elements have the same number of electrons instead atoms of the same elements in the same group have the same number of valence electrons.

(c) Non-metals have the tendency to gain electrons to attain stable configuration and therefore are said to be electronegative. As we move from left to right the increase in atomic number and decrease in size results in a greater nuclear pull. As a result the non-metallic character increases across a period.

(d) On moving from left to right in a period, the reactivity first decreases and then increases since the tendency to lose electrons first decreases on going from left to right and then from P to Cl, tendency to gain electrons increases, so reactivity increases then. In case of a group, reactivity increases on going down since the tendency to lose electrons increases but for non-metals, reactivity decreases on going down the group as the tendency to gain electrons decreases down the group.

62.

What is the name given to elements of 17th group?

Answer»

The name of 17th group’s elements is halogens.

63.

What is the IUPAC name and symbol of elements with atomic number 120?

Answer»

The IUPAC name for atomic number 120 is Unbinilium and symbol is Ubn.

64.

Why there are 14 elements in 4f series?

Answer»

The lanthanides are f-block elements which contain seven f-orbitals. The maximum electrons can be filled in f-orbitals are 14. Hence, lanthanides have total 14 elements.

65.

Give three examples of lanthanide elements. 

Answer»

Lanthanum, cerium, lutetium.

66.

As there elements existing in solid, liquid and gaseous state find examples?

Answer»
  • In solid-state - sodium, aluminum, carbon 
  • In liquid state – Bromine 
  • In gaseous state – oxygen, neon, argon
67.

Give one words or phrase for: The amount of energy released when an atom in the gaseous state accepts an electron to form an anion.

Answer»

The amount of energy released when an atom in the gaseous state accepts an electron to form an anion → Electron Affinity. 

68.

In the activity series of metals-M is a metal above hydrogen in the in the activity series and its oxide has the formula Mz M2O when dissolved in water forms the corresponding hydroxide which is a good conductor of electricity. In the above context answer the following: (1) What kind of combination exists between M and O? (2) State the number of electrons in the outermost shell of M? (3) Name the group to which M belongs.

Answer»

1. M and O combine with electrovalent bond. 

2. One 

3. Group I

69.

The elements of one short period of the periodic table are given below in order from left to rightLi Be B C O F Ne(a) To which period do these elements belong?(b) One element of this period is missing. Which is the missing element and where should it be placed?(c) Which one of the elements in this period shows the property of catenation?(d) Place the three elements fluorine, beryllium and nitrogen in the order of increasing electronegativity.(e) Which one of the above elements belongs to the halogen series?

Answer»

(b) Nitrogen (N), between carbon and oxygen

(c) Carbon

(d) Be< N< F

(e) Fluorine

70.

Define the term ‘Electronegativity’ state its unit.

Answer»

Electronegativity measures an atom's tendency to attract shared pair of electrons towards itself.

Its S.I unit is Pauling unit.

71.

Then what is the change in ionization energy?

Answer»

As the size of atom increases ionization energy decreases.

72.

Match the options A to B with the statements (1) to (2): A metal (1) The metal that forms two types of ions B iron (2) An element with electronic configuration 2, 8, 8,3

Answer»

A metal (2) An element with electronic configuration 2, 8, 8,3 

B iron (1) The metal that forms two types of ions 

73.

You have understood how sodium chloride is formed by combining sodium and chlorine atoms. The Bohr model of sodium and chlorine are given below(i) Which among these atoms lose electrons?(ii) Which one gains electrons

Answer»

i. Sodium atom

ii. Chlorine atom

74.

State with example the limitations of Newland’s law of octaves. 

Answer»

Newland arranged the element only upto calcium. After calcium every eighth element did not possess properties similar to that of the first. In order to fit the existing elements Newland placed two elements in the same position which differed in the properties. 

75.

The atomic numbers of five elements A, B, C and D are given below. Element Atomic number A3B5C7D9E10i. Which element belongs to group 18?  ii. Which element belongs to group 15?  iii. Which element belongs to halogen group?  iv. Which element belongs to alkali metals? 

Answer»

i. E 

ii. C 

iii. D 

iv. A 

76.

Why fluorine has higher E.N. than chorine?

Answer»

Since size of chlorine is bigger than fluorine hence the electrons being farther away from the nucleus experience a lesser force of attraction, hence electron negativity of chlorine is less than fluorine

77.

Are you familiar with the Bohr model of an atom? See the Bohr model of atoms of certain elements, in group I.(i) Which among them is the biggest?(ii) Which one is the smallest?(iii) What happens to the size of an atom when we move down the group?(iv) What is the reason for this?

Answer»

i. Potassium (K)

ii. Hydrogen [H]

iii. Increases

iv. Number of shells increases. 

As we move from top to bottom of a group in the periodic table the size of the atom increases as there is an increase in the number of shells.

78.

Chorine in the periodic table is surrounded by the elements with atomic number 9, 16, 18 and 35.(a) Which of these have physical and chemical properties resembling chlorine.(b) Which is more electronegative than chlorine

Answer»

(a) Element with atomic number 9 and 35

(b) Element with atomic number 9.

79.

See (Fig) the representation of Bohr model of elements with atomic numbers 3 to 9 in the second period of the periodic table.1. Is there are in the number of shells with the increase in atomic number?2. What happens to the nuclear charge with increase in atomic number?

Answer»

1. No.

2. On moving from left to right in a period, as nuclear charge increases, the force of attraction on the outer-most electrons increases and consequently the size of atom decreases.

80.

Which element is next to lanthanum with atomic number 57 of group 6 in the periodic table?

Answer»

Cerium with atomic No. 58

81.

The given table shows elements with the same number of electrons in its valence shell.  Elements  A B  C   m.p63.0180.0 97.0 State:(i) Whether these elements belong to same group or period.(ii) Arrange them in order of increasing metallic character.

Answer»

(i) Yes, these elements belong to the same group but are not from the same period.

(ii) We know that m.p. decreases on going down the group. Hence, from the above table, the elements can be ordered according to their period as follows:

  Elements  B  C  A
   m.p 180.0  97.0   63.0
 

The metallic character increases as one moves down the group. Hence, the order of the given elements with increasing metallic character is as follows: B

82.

Name(a) An alkali metal in period 3 and halogen in period 2.(b) The noble gas with 3 shells.(c) The non-metals present in period 2 and metals in period 3.(d) The element of period 3 with valency 4(e) The element in period 3 which does not form oxide(f) The element of lower nuclear charge out of Be and Mg.(g) Which has higher E.A. fluorine or Neon.(h) Which has maximum metallic character Na, Li or K.

Answer»

(a) SOL: Na and F

(b) SOL: Argon

(c) SOL: C, N, O and F are non-metals present in period 2 while Na, Mg and Al are metals in period 3.

(d) SOL: Silicon

(e) SOL: Argon

(f) SOL: Mg

(g) SOL: Fluorine

(h) SOL: K

83.

Periodicity is observed due to the similar …………………. (Number of valence electrons / atomic number / electronic configuration).

Answer»

Periodicity is observed due to the similar electronic configuration.

(Number of valence electrons / atomic number / electronic configuration).

84.

What is the Valency?

Answer»

Combining capacity of an element is known as Valency.

85.

Explain metalloids?

Answer»

Elements exhibiting the properties of both metal as well as nonmetal are called metalloids, eg. Silicon [Si], germanium [Ge] Arsenic [As], Antimony [Sb] and Tellurium [Te] belongs to this category.

86.

State the trends in ionization energy:(a) across the period:(b) down the group.

Answer»

(a) Ionization energy increases as we move from left to right across a period as the atomic size decreases.

(b) Ionization energy decreases down a group as the atomic size increases.

87.

Electronic configurations of elements P, Q, R, and S are given below. (These are not actual symbols).P – 2, 2 Q -2, 8, 2 R – 2, 8, 5 S – 2, 8 a) Which among these elements are included in the same period? b) Which are those included in the same group? c) Which among them is a noble gas? d) To which group and period does the element R belong?

Answer»

a) P and S, Q and R – belongs to same period 

b) P and Q, belongs to same group 

c) S 

d) R belongs to 3rd period and 15th group

88.

In a periodic table, the penultimate shell of which of the elements is incomplete?

Answer»

Transition elements because last two shells of these elements namely outermost and penultimate shells are incomplete.

89.

Table given below lists the contributions and names of scientists who made earlier attempts in the classification of elements. Make them in the correct order.     Contribution/Findings   Name of scientist Octet Rule John Dalton Triads New Lands Modern periodic table Lavoisier Classify into metals Henry Moseley Non-metals  Atomic theory Dobereiner

Answer»
 Contribution/Findings   Name of scientist
 Triads Dobereiner
 Law of octaves Newlands
 Classification of elements into metals and nonmetalsAntonie Lavoisier
 Modern periodic law Henry Moseley
90.

A, B, C, D are four elements. The electronic configuration is given below and find the answers in the following (Hint. The symbols are not real) A – 2, 2 B – 2, 8, 5 C – 2, 7 D – 2, 8, 2 a) Find the elements belongs to same period?b) Find the elements belongs to same group. c) ‘C’ belongs to which period and group?

Answer»

a) B, D, and A, C because the number of shells are same. 

b) A, D because the number of electrons in the outermost shell is same. 

c) ‘C’ belongs to second period and 17th group

91.

Out of the following which element has strongest metallic character? Al, P, S, Cl

Answer»

Al has strongest metallic character. 

92.

1. Write the electronic configuration of elements with atomic number 1-102. List the elements in group 183. Now try to write their electronic configuration4. How many electrons are there in the outermost shell of each element?5. The elements do not normally take part in chemical reactions. Find the reason?6. Which group of elements belong to transition elements?7. Find out whether elements familiar to you are present in these groups?8. Aren’t transition elements metals?

Answer»

1.

 Element Atomic number  Electronic configuration
Hydrogen 1 1
Helium 2 2 
Lithium 3 2,1
Beryllium 4 2,2
Boron 5 2,3
Carbon 6 2,4
Nitrogen 7 2,5
oxygen 8 2,6
Fluorine 9 2,7
Neon 10  2,8

The atom of the elements of these group show the periodically in electron filling they contain 1 -8 electron in their outermost shell. The elements of these groups are called representative elements.

2. Helium, Neon, Argon, Krypton, Xenon, Radon

3. 2He – 2 

10Ne – 2, 8 

18Ar – 2, 8, 8 

36Kr – 2, 8, 18, 8 

54Xe – 2, 8, 18, 18, 8 

86Rn – 2, 8, 18, 32, 18, 8

4. 8

5. They have a stable configuration in the outermost shell.

6. Elements of group 3-12 in the periodic table are transition elements

7. Copper, silver, gold, iron

8. Yes

93.

An element A has atomic number 14. To which period does this element belong and how many elements are there in this period.

Answer»

An element A with atomic number 14 belongs to period three and there are eight elements in this period.

94.

Answer the following in respect of element / (i) Give its electronic configuration(ii) To which group and period does it belong?(iii)What is its valency?(iv)Is it a metal or non - metal(v) Is it a reducing agent or oxidizing agent?(vi)Give its formula with chlorine.

Answer»

(i) Electronic configuration of P: 2, 8, 5

(ii) 15th Group and 3rd Period.

(iii)Valency of P = 8 - 5 = 3

(iv)Phosphorus is a non-metal.

(v) It is an oxidizing agent.

(vi)Formula with chlorine = PCl3

95.

How do the metallic character and nonmetallic character vary while moving from left to right in a period? Arriving at a conclusion by assessing the size of atom?

Answer»

In the periodic table, while moving from to top to bottom in groups metallic character generally increases while non-metallic character decreases. In a period as we move form left to right metallic character generally decreases while non-metallic character increases.

96.

Metallic character and non-metallic character are periodic properties discuss.

Answer»

The periodic variation in electronic configuration as one move sequentially in increasing order of atomic number produces a periodic variation in properties.

As the elements are arranged in increasing order of atomic number, the metals with tendency to lose electrons are placed on the left and the metallic character decreases from left to right and increases down a group and non-metals with tendency to gain electrons are placed automatically on the right and the non-metallic character increase across a period and decreases down a group.

97.

What is the basis for the chemical properties of metals and non-metals?

Answer»

Metals are the elements which give away the electrons and those that accept electrons are generally non-metals. Metals are electropositive elements because they lose electrons to form positive ions. Non-metals are called electronegative elements because they gain electrons in chemical reactions to form negative ions.

98.

How does the chemical reactivity of:(a) alkali metals vary?(b) halogens vary?

Answer»

(a) Since, the distance of the valence electrons from the nucleus keeps on increasing down the group, therefore, the ionization energy keeps on decreasing. Hence the reactivity of alkali metals increases from lithium to francium.

(b) As we move down a group, the size keeps on increasing, so it becomes more difficult for atoms to attract electrons. Thus reactivity of halogens decreases from Fluorine to Astatine.

99.

Arrange the following in order of increasing radii:(a) CI- , CI(b) Mg2+, Mg, Mg+(c) N, O, P

Answer»

(a) Cl < Cl¯

(b) Mg2+ < Mg+ < Mg

(c) O < N < P

100.

A group of elements in the periodic table are given below (boron is the first member of the group and thallium is the last).Boron, Aluminium, Gallium, Indium, Thallium.Answer the following questions in relation to the above group of elements:(a) Which element has the most metallic character?(b) Which element would be expected to have the highest electronegativity?(c) If the electronic configuration of aluminium is 2, 8, 3, how many electrons are there in the outer shell of thallium(d) The atomic number of boron is 5. Write chemical formula of the compound formed when boron reacts with chlorine.(e) Will the elements in the group to the right of this boron group be more metallic or less metallic in character? Justify your answer.

Answer»

(a) Thallium has the most metallic character since metallic character increases down the group

(b) Boron has the highest electronegativity since it has the smallest size in the group.

(c) 3. Since all the elements in a group have same number of valence electrons.

(d) BCl3

(e) The elements in the group to the right of boron group would be less metallic as with the decrease in size and increase in atomic number, it will be more difficult for them to lose electrons