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151.

Evaluate the Mendeleev’s periodic table and find the following. (a) Total number of periods (b) Total number of Groups (c) Are the same elements showing similar properties arranged in the same group or same period?

Answer»

a) 6 

b) 8 

c) Same group

152.

Define Mendeleev’s periodic law?

Answer»

In 1869 Mendeleev arranged the known 63 elements in horizontal and vertical columns and gave shape to the periodic table. He found that the chemical and physical properties of elements repeat at a regular intervals when they were arranged in the increasing order of atomic masses. Based on this Mendeleev proposed the periodic law of elements. The law states that physical and chemical properties of elements are periodic function of their atomic masses.

153.

(a) State the number of elements in periods 1, Periods 2, and Period 3, of the periodic table.(b) name the elements in period 1.(c) What is the common feature of the electronic configuration of the elements at the end of period 2, and period 3?(d) if an element is in group 17, it is likely to be ………….. (Metallic / non-metallic) in character while with one electron in its outermost energy level (shell), then it is likely to be ……………(Metallic / Non-metallic)

Answer»

(a) Period 1 has 2 elements while period 2 and period 3 have 8 elements each.

(b) Hydrogen and helium

(c) The elements at the end of period 2 and Period 3 have 8 electrons in its outermost shell.

(d) if an element is in group 17, it is likely to be Non metallic (Metallic / non-metallic) in character while with one electron in its outermost energy level (shell), then it is likely to be metallic (Metallic / Non-metallic)

154.

Fill in the following table: Group Group IA Group IIA Group IIIAGroup IVAGroup VA Group VIA Group VIIAGroup 0Element Na Mg AlSi P S Cl Ar Atomic number Electronic configurationMetallic propertyValency 

Answer»
Group Group IA Group IIA Group IIIAGroup IVAGroup VA Group VIA Group VIIAGroup 0
Element Na Mg AlSi Cl Ar 
Atomic number 1112131415161718
Electronic configuration2, 8, 1 2, 8, 2 2, 8, 32, 8, 4 2, 8, 5 2, 8, 6 2, 8, 7 2, 8, 8 
Metallic propertyMetalMetalMetalMetalloidNon-MetalNon-Metal Non- MetalNoble gases 
Valency 12343210

155.

An element barium has atomic number 56. Look up its position in the periodic table and answer the following questions.(a) Is it a metal or a non – metal?(b) Is it more or less reactive than calcium?(c) What is its valency?(d) What will be the formula of its phosphate?(e) Is it larger or smaller than caesium (Cs)?

Answer»

(a) Since it belongs to group II, it has 2 valence electrons and hence it is a metal.

(b) Barium is placed below calcium in the group. Since, it has more number of shells; it is easier for it to lose its valence electrons to complete its octet configuration. Hence it is more reactive than calcium.

(c) It needs to lose its 2 valence electrons to complete its octet configuration; therefore its valency is also 2.

(d) The formula of its phosphate will be (Ba)3 (PO4)2

(e) As we move from left to right in a period, the size decreases, therefore, it will be smaller than Cesium

156.

What is meant by groups and periods in the periodic table?

Answer»

The vertical columns in the periodic table are known as groups and the horizontal rows are called periods.

157.

The electronic configuration of an element X is 2, 8, 1 and element Y is 2, 8, 18, 8, 1. i. Identify the group of X and Y. ii. What is the period number of Y? iii. How many valence electrons are there in the atoms of X and Y? iv. What is the valency of X and Y? v. State whether X and Y are metals or non-metals. 

Answer»

i. Group of X and Y is IA. 

ii. X belongs to 3rd period and Y belongs to 5th period. 

iii. Valence electrons of X and Y is 1. 

iv. Valency of X and Y is 1. 

v. X and Y are alkali metals. 

158.

Find out the position allotted to the elements with atomic number 58-71?

Answer»

Separate position at the bottom of the periodic table

159.

Is the same way aren’t the elements with atomic number 90 to 103 of period 7 give separate positions at the bottom of the periodic table?

Answer»

Yes. These elements are called inner transition elements.

160.

In the modern periodic table: How many periods and groups are present there? 

Answer»

The horizontal rows in the modern periodic table are called as periods and the vertical columns are called as groups. The modern periodic table consists of seven periods and eighteen groups

161.

The following table shows the position of nine elements in the periodic table. The elements are shown by the letters which are not their usual symbols. Using the following table answer the following questions: Groups→Periods↓12131415161718Period 1 HydrogenPeriod 2 A BoronX Nitrogen OxygenP Neon Period 3 B Y L Q Period 4 C CalciumZ M R Period 5 D SWith the help of the table, answer the following questions:  i. Give the letter which has maximum metallic character.  ii. Give the letter which has maximum non-metallic character.  iii. Name the family of elements represented by P, Q, R, and S.  iv. Name the elements A, X, Q and S.  v. Write the valency of letters (a) X, Y and Z (b) L and M (c) P, Q, R and S vi. Which element has a larger atomic radius out of (a) A and D (b) A and P?  vii. Give the common name of the group 1 and group 2. 

Answer»

i. D 

ii. P 

iii. Halogen 

iv. A - Lithium, X - Carbon, Q - Chlorine, S - Iodine 

v. a. Valency of X,Y and Z is 4. 

b. Valency of L and M is 2. 

c. Valency of P, Q, R and S is 1. 

vi. a. D has larger radius (out of A and D). 

 b. A has larger radius (out of A and P). 

vii. Group 1 is known as alkali metals. 

 Group 2 is known as alkaline earth metals. 

162.

Element A belongs to the 3rd period and group 15 of periodic table. State the following: i. Name of the element. ii. Atomic number iii. Number of valence electrons iv. Valency v. Nature of the element (Metal/ Non-metal) vi. Electronic configuration 

Answer»

i. Phosphorous 

ii. 15 

iii. 5 

iv. 3 

v. Non-metal 

vi. Electronic configuration (2, 8, 5) 

163.

The three elements predicted by Mendeleev from the gaps in his periodic table were known as eka-boron, eka-aluminium and eka-silicon. What names were given to these elements when they were discovered later? 

Answer»

Eka-boron was named as Scandium 

Eka-aluminium was named as Gallium 

Eka-silicon was named as Germanium 

164.

In the modern periodic table: Identify the shortest and longest period.

Answer»

The first period is the shortest period containing only 2 elements. The sixth period is the longest and it contains 32 elements in it. 

165.

In Period 2 of the modern periodic table, name the following:  i. an alkali metal  ii. a noble gas with 2 shells  iii. a non-metal with valency 4  iv. a halogen v. an alkaline earth metal  vi. a metalloid 

Answer»

i. Lithium 

ii. Neon 

iii. Carbon 

iv. Fluorine 

v. Beryllium 

vi. Boron 

166.

“The Physical and chemical properties of elements are a periodic function of their atomic masses”. i. Name the law. ii. What do you understand by this statement? iii. How does it differ from the modern periodic law?

Answer»

i. This law is known as Mendeleev’s periodic law. 

ii. Mendeleev’s periodic law means that if elements are arranged in the order of increasing atomic masses, then the properties of the elements are repeated after certain intervals or periods. 

iii. It differs in the following way - The Modern periodic law states that “The chemical and physical properties of elements are a periodic function of their atomic numbers”. 

167.

On moving from left to right in a period of the periodic table how does the following properties of elements change?  i. Atomic size  ii. Metallic character  iii. Non-metallic character  iv. No. of valence electrons 

Answer»

On moving from left to right in a period of the periodic table 

 i. Atomic size decreases 

 ii. Metallic character decreases 

 iii. Non-metallic character increases 

 iv. Number of valence electrons increases

168.

Why is group 18 of modern periodic table also known as group zero? 

Answer»

The outermost shells of the elements belonging to group 18 contain eight electrons (except helium), so they are already completely filled with electrons. They have no tendency to lose or gain electrons and hence have a stable electronic configuration with zero valency. Therefore, group 18 of modern periodic table is also known as group zero. 

169.

Parts (a) to (e) refer to changes In the properties of elements on moving from left to right across a period of the periodic table. For each property, choose the correct answer.(a) The non-metallic character of the elements:(i) decreases(ii) increases,(iii)remains the same,(iv)depends on the period(b) The electronegativity:(i) depends on the number of valence electrons,(ii) remains the same,(iii)decreases,(iv)increases.(c) The ionization potential:(i) goes up and down(ii) decreases(iii) increases(iv) remains the same(d) The atomic size:(i) decreases,(ii) increases,(iii)remains the same,(iv)sometimes increases and sometimes decreases.(e) The electron affinity of the elements in groups 1 to 7:(i) goes up and then down.(ii) decreases and then increases,(iii) increases,(iv) decreases.

Answer»

(a) Increases

(b) Increases

(c) Increases

(d) Decreases

(e) Increases

170.

How the ions are formed?

Answer»

Atom becomes charged when there is transfer of electrons [Lose or gain electrons] they are called ions.

171.

On moving from top to bottom in a group in the periodic table how does the following properties change?  i. Metallic character  ii. Non-metallic character  iii. Atomic size iv. No. of valence electrons 

Answer»

On moving from top to bottom in a group of the periodic table 

 i. Metallic character of elements increases. 

 ii. Non-metallic character decreases. 

 iii. Size of atoms increases 

 iv. All elements will have the same number of valence electrons. 

172.

When the size of an atom increases, does the attraction of the nucleus on the outermost electron increase or decrease?

Answer»

Answer is Decrease

173.

Define ionization energy?

Answer»

The amount of energy required to liberate the most loosely bound electrons from the outermost shell of an isolated gaseous atom of an element is called ionization energy.

174.

What happens to the atomic size of elements on moving from top to bottom of a group?

Answer»

Atomic size increases as we move from top to bottom.

175.

Write the formula for calculation of percentage ionic character.

Answer»

Every ionic compound have some percentage of covalent character according to Fajan’s rule. The percentage of ionic character in a compound having some covalent character can be calculated by the following equation.

Percentage ionic character \(=\frac{\textit { Obsereed dipole moment }}{\textit { Calculated dipole moment }} \times 100\)

176.

The electro negativities (according to pauling) of the elements in periodic table are as follows with the elements arranges in alphabetical order: AI        CI      Mg       Na    P       S       Si 1.5  3.0  1.2   0.9   2.1  2.5  1.8(a) Arrange the elements in the order in which they occur in the periodic table from left to right.(The group 1 element first, followed by the group 2 element and so on, up to group 7)(b) Choose the word or phrase from the brackets which correctly completes each of the following statements:-(i) The element below sodium in the same group would be expected to have a………. (lower/higher) electro-negativity than sodium and the element above chlorine would be expected to have a ……. (lower/ higher) ionization potential than chlorine.(ii) On moving from left to right in a given period, the number of shells (remains the same/ increases/ decreases).(iii) On moving down a group, the number of valence electrons (remains the same/ increases/ decreases).

Answer»

(a)  Na, Mg, Al, Si, P, S, Cl

(b)  (i) The element below sodium in the same group would be expected to have a Lower (lower/higher) electro-negativity than sodium and the element above chlorine would be expected to have a higher (lower/ higher) ionization potential than chlorine.

(ii)  remains the same

(iii)  remains the same

177.

What are the factors affecting the ionization energy? Nuclear charge

Answer»

Size of the atom

178.

What is the general trend in the variation of ionization energy on moving across a period from left to right?

Answer»

Ionization energy increases

179.

Can you find out how ionization energy changes as we move from top to bottom in a group?

Answer»

Ionization energy decreases.

180.

What is the relation between Mulliken and Pauling Scale for measurement electronegativity?

Answer»

According to Mullikan scale:

Electronegativity = Ionisation enthalpy + Electron gain enthalpy / 2
When IE and electron gain enthalpy are expressed in eV.
Electronegativity = Ionisation enthalpy + Electron gain enthalpy / 540 When ionization enthalpy and electron gain enthalpy are expressed in kJ/mol.
χpauling = χmullikan/2.8
χpauling = Ionisation enthalpy + Electron gain enthalpy /5.6

181.

Find how ionization energy changes with increase in nuclear charge?

Answer»

On moving from left to right in a period, as nuclear charge increases, the size of the atom decrease hence ionization energy increase.

182.

What is relationship between metallic character and the size of an atom?

Answer»

As the size of the atom increases metallic character also increases.

183.

Don’t you think that there is a relationship between ionization energy and metallic -non-metallic character? Is the element with highest ionization energy metallic or non-metallic?

Answer»

Non-metallic

184.

How size of an atom influence the electronegativity?

Answer»

As the size of an atom increases the distance between the nucleus and the outermost electron increases, hence the electronegativity decreases. As we move in the same period form left to right size of atom decrease hence electronegativity increases.

185.

Isn’t there a relationship between electronegativity and metallic, non-metallic character? Explain the relationship?

Answer»

Non-metals are more electronegative.

186.

Select the right answer – Electronegativity across the period –

Answer»

Electronegativity across the period is Increases.

187.

a) Name the elements with highest and lowest electronegativity,(b) State the character of the oxide of period 3.

Answer»

(a) The element fluorine has the highest electronegativity and Caesium has the lowest electronegativity.

(b) The nature of oxides changes from basic to acidic as we move from left to right in third period. Hence sodium forms most basic oxide while oxide of Aluminum is amphoteric and oxides of phosphorus, sulphur and chlorine are progressively acidic